Abstract: The invention relates to inert gas production processes and can be used for producing a krypton/xenon mixture from a stream of oxygen recovered from air separation plants and containing 0.05-0.5% krypton and xenon. The method for producing a krypton/xenon mixture involves purifying a stream of gaseous primary concentrate by the catalytic combustion thereof and subsequently cooling same, purifying the primary concentrate of catalytic combustion products, carrying out cooling upon completion of purification, fractionating the primary concentrate in a rectification column to form a stream of krypton/xenon mixture and a stream of stripped oxygen and removing the stream of krypton/xenon mixture from the rectification column in the form of a target product, as well as purifying the krypton/xenon mixture of radon. The invention makes it possible to extend the scope of use of the krypton/xenon mixture.