Patents by Inventor Nobuharu Hisano
Nobuharu Hisano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10781288Abstract: A polyimide precursor including at least one repeating unit represented by the following chemical formula (1): in which A is an arylene group; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, and a polyimide obtained from the polyimide precursor has a coefficient of linear thermal expansion from 50° C. to 400° C. of 100 ppm/K or less.Type: GrantFiled: March 15, 2013Date of Patent: September 22, 2020Assignee: Ube Industries, Ltd.Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20200133048Abstract: A polyimide film having, when measured at a film thickness of 10 ?m, a weight residue ratio of 99.0% or more when held at 400° C. for 4 hours, a YI (yellow index) of 10 or less, and a coefficient of linear thermal expansion between 100 and 350° C. of 55 ppm/K or less. The polyimide film is excellent in transparency and heat resistance, has a low linear thermal expansion coefficient, and can be suitably used for a substrate for a display, a touch panel, or a solar cell.Type: ApplicationFiled: May 30, 2018Publication date: April 30, 2020Inventors: Takuya OKA, Miharu NAKAGAWA, Nobuharu HISANO
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Patent number: 10174166Abstract: A polyimide precursor comprising a repeating unit represented by the following chemical formula (1): in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least one type of repeating unit represented by the chemical formula (1) in which A is a group represented by chemical formula (2) or (3): in which m independently represents 0 to 3 and n independently represents 0 to 3; Y1, Y2 and Y3 each independently represent at least one selected from the group consisting of hydrogen atom, methyl group and trifluoromethyl group; and Q and R each independently represent direct bond, or at least one of —NHCO—, —CONH—, —COO— and —OCO—, in which Z and W each independently represent a divalent aromatic group having 6 to 18 carbon atoms; and Y4 repType: GrantFiled: September 10, 2013Date of Patent: January 8, 2019Assignee: UBE INDUSTRIES, LTD.Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20180171077Abstract: A polyimide precursor composition including a polyimide precursor, and a fine particle having an optical anisotropy; and a polyimide composition including a polyimide, and a fine particle having an optical anisotropy.Type: ApplicationFiled: June 10, 2016Publication date: June 21, 2018Inventors: Takuya OKA, Yukinori KOHAMA, Ryoichi TAKASAWA, Nobuharu HISANO, Ken KAWAGISHI
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Publication number: 20170342215Abstract: The present invention relates to a polyimide film consisting essentially of a polyimide comprising a repeating unit represented by the following chemical formula (1): wherein the film has a YI (yellowness index) of 4 or less, a tensile modulus of elasticity of 4 GPa or more, and a load at break of 10 N or more.Type: ApplicationFiled: October 23, 2015Publication date: November 30, 2017Inventors: Takuya OKA, Yukinori KOHAMA, Nobuharu HISANO
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Publication number: 20170313821Abstract: The present invention relates to a polyimide precursor comprising a repeating unit represented by the following chemical formula (1A) and a repeating unit represented by the following chemical formula (2A): wherein A1 is a divalent group having an aromatic ring; and R1 and R2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein A2 is a divalent group having an aromatic ring; and R3 and R4 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms.Type: ApplicationFiled: October 23, 2015Publication date: November 2, 2017Inventors: Takuya OKA, Yukinori KOHAMA, Nobuharu HISANO
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Patent number: 9783640Abstract: A polyimide precursor comprising at least one repeating unit represented by the following chemical formula (5): in which A3 is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X3 and Y3 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, and/or at least one repeating unit represented by the following chemical formula (6): in which A3 is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X4 and Y4 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms.Type: GrantFiled: September 13, 2013Date of Patent: October 10, 2017Assignee: UBE INDUSTRIES, LTD.Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Patent number: 9556312Abstract: A polyimide precursor, a polyimide using the polyimide precursor, and a polyimide film using the polyimide. The polyimide film has excellent adhesiveness to a metal layer or an adhesive, and has improved heat resistance. The polyimide solution may be used as a coating material.Type: GrantFiled: May 14, 2013Date of Patent: January 31, 2017Assignees: NATIONAL UNIVERSITY CORPORATION IWATE UNIVERSITY, UBE INDUSTRIES, LTD.Inventors: Yoshiyuki Oishi, Shin-ichiro Kohama, Nobuharu Hisano
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Patent number: 9511565Abstract: A polyimide precursor for obtaining a polyimide film having excellent adhesiveness to metals and improved transmittance in the UV-visible range, a polyimide in which the polyimide precursor is used, a polyimide film in which the polyimide is used, and a method for manufacturing a triazine compound used for manufacturing the polyimide precursor, polyimide film and polyimide.Type: GrantFiled: August 10, 2012Date of Patent: December 6, 2016Assignees: UBE INDUSTRIES, LTD., NATIONAL UNIVERSITY CORPORATION IWATE UNIVERSITYInventors: Yoshiyuki Oishi, Nobuharu Hisano, Shin-ichiro Kohama, Taizou Murakami, Hiroaki Yamaguchi
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Publication number: 20160297995Abstract: A polyimide precursor obtained from a tetracarboxylic acid component including norbornane-2-spiro-?-cyclopentanone-??-spiro-2?-norbornane-5,5?,6,6?-tetracarboxylic dianhydride, or a derivative thereof, and a diamine component including a diamine, or a derivative thereof, the norbornane-2-spiro-?-cyclopentanone-??-spiro-2?-norbornane-5,5?,6,6?-tetracarboxylic dianhydride characterized in that the ratio of the peak area of a certain peak is 60% or more in a gas chromatogram obtained by conducting gas chromatography analysis.Type: ApplicationFiled: October 8, 2014Publication date: October 13, 2016Inventors: Takuya OKA, Yukinori KOHAMA, Nobuharu HISANO
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Patent number: 9393720Abstract: A polyimide film, which is produced by the reaction of a tetracarboxylic acid component comprising 3,3?,4,4?-biphenyltetracarboxylic dianhydride as the main component and a diamine component comprising p-phenylenediamine as the main component, is heated at a temperature of from 460° C. to 550° C., and then water or an alkaline aqueous solution is sprayed on a surface of the polyimide film for surface treatment, thereby improving adhesiveness, while maintaining the excellent properties inherent in the polyimide film.Type: GrantFiled: August 18, 2010Date of Patent: July 19, 2016Assignee: UBE INDUSTRIES, LTD.Inventors: Nobuharu Hisano, Taizou Murakami, Masafumi Kohda, Hiroaki Yamaguchi
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Patent number: 9375877Abstract: A method for manufacturing a polyimide-metal laminate including forming a polyimide film, in which at least surfaces of both sides of the film are formed by thermally fusion-bondable polyimide layers (a), and thermal compression-bonding metal layers on both sides of the polyimide film; in which forming the polyimide film includes reacting a tetracarboxylic dianhydride component with a diamine component containing a diamine compound represented by general formula (1) to give a solution of a polyamic acid (a), forming a self-supporting film from the solution of the polyamic acid (a) and imidizing the self-supporting film by heating at a maximum heating temperature of 440° C. or lower to form the polyimide layer (a); in which R1 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms; and R2 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms.Type: GrantFiled: August 10, 2012Date of Patent: June 28, 2016Assignee: UBE INDUSTRIES, LTD.Inventors: Shin-ichiro Kohama, Nobuharu Hisano, Taizou Murakami, Kosuke Oishi, Hiroaki Yamaguchi
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Publication number: 20160137787Abstract: A polyimide precursor consisting of a repeating unit represented by the following chemical formula (1): and a repeating unit represented by the following chemical formula (2): in which A is a tetravalent group of a tetracarboxylic acid, from which carboxyl groups have been removed; B is a divalent group of a diamine, from which amino groups have been removed; with the proviso that the A group and the B group contained in each repeating unit may be the same as, or different from each other; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, the amount of the repeating unit represented by the chemical formula (2) is 30 mol % or more and 90 mol % or less relative to the total repeating units, 50 mol % or more of the total amount of the B group in the chemical formula (1) and the chemical formula (2) is p-phenylene group and/or a specific divalent group containing two or more benzene rings, the polyimide prType: ApplicationFiled: June 26, 2014Publication date: May 19, 2016Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20150361222Abstract: A polyimide precursor comprising a repeating unit represented by the following chemical formula (1): in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least one type of repeating unit represented by the chemical formula (1) in which A is a group represented by chemical formula (2) or (3): in which m independently represents 0 to 3 and n independently represents 0 to 3; Y1, Y2 and Y3 each independently represent at least one selected from the group consisting of hydrogen atom, methyl group and trifluoromethyl group; and Q and R each independently represent direct bond, or at least one of —NHCO—, —CONH—, —COO— and —OCO—, in which Z and W each independently represent a divalent aromatic group having 6 to 18 carbon atoms; and Y4 repreType: ApplicationFiled: September 9, 2013Publication date: December 17, 2015Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20150307662Abstract: A polyimide precursor comprising at least one repeating unit represented by the following chemical formula (5): in which A3 is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X3 and Y3 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, and/or at least one repeating unit represented by the following chemical formula (6): in which A3 is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X4 and Y4 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms.Type: ApplicationFiled: September 13, 2013Publication date: October 29, 2015Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20150284513Abstract: A polyimide comprising a repeating unit represented by the following chemical formula in which A is a divalent group of an aromatic diamine or an aliphatic diamine, from which amino groups have been removed; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, wherein the polyimide precursor comprises at least two types of repeating units represented by the chemical formula (1) in which A is a group represented by any one of the following chemical formulas (2-1), (2-2), (3) and (4): in which a polyimide obtained from the polyimide precursor has a coefficient of linear thermal expansion from 50° C. to 200° C. of 50 ppm/K or less and a transmittance at 400 nm of 75% or more in the form of a polyimide film having a thickness of 10 ?m.Type: ApplicationFiled: September 10, 2013Publication date: October 8, 2015Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20150158980Abstract: A polyimide precursor including at least one repeating unit represented by the following chemical formula (1): in which A is an arylene group; and X1 and X2 are each independently hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, and a polyimide obtained from the polyimide precursor has a coefficient of linear thermal expansion from 50° C. to 400° C. of 100 ppm/K or less.Type: ApplicationFiled: March 15, 2013Publication date: June 11, 2015Inventors: Takuya Oka, Yukinori Kohama, Yoshiyuki Watanabe, Nobuharu Hisano
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Publication number: 20150132591Abstract: A polyimide precursor, a polyimide using the polyimide precursor, and a polyimide film using the polyimide. The polyimide precursor comprises a structural unit represented by general formula (AI): in which A is tetravalent aromatic group or aliphatic group, B is divalent aromatic group, and each R2 independently represents hydrogen, an alkyl group having 1 to 6 carbon atoms, or an alkylsilyl group having 3 to 9 carbon atoms, in which B in general formula (AI) includes a triazine moiety represented by following formula (AB1): in which R1 represents hydrogen, an alkyl group having 1 to 6 carbon atoms or an aromatic group, and R3 represents hydrogen, methyl or ethyl.Type: ApplicationFiled: May 14, 2013Publication date: May 14, 2015Inventors: Yoshiyuki Oishi, Shin-ichiro Kohama, Nobuharu Hisano
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Patent number: 9005843Abstract: A polymer electrolyte composition of a sulfonated block copolymer (A) having a hydrophilic segment with a sulfonic acid group and a hydrophobic segment with no sulfonic acid group, each segment having an aromatic ring is its main chain, and an aromatic polymer (B) having no sulfonic acid group with a structural unit that is identical to the structural unit contained in the hydrophobic segment of the sulfonated block copolymer is provided. The ion-exchange capacity of the composition can be in a range of 0.5 mmol/g to 2.9 mmol/g. Electrolyte membranes, membrane/electrolyte assemblies, and electrolyte fuel cells utilizing the polymer electrolyte composition are also provide.Type: GrantFiled: March 2, 2012Date of Patent: April 14, 2015Assignee: Ube Industries, Ltd.Inventors: Tetsuji Hirano, Nobuharu Hisano, Tatsuya Arai, Masayuki Kinouchi
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Publication number: 20140290853Abstract: A method for manufacturing a polyimide-metal laminate including forming a polyimide film, in which at least surfaces of both sides of the film are formed by thermally fusion-bondable polyimide layers (a), and thermal compression-bonding metal layers on both sides of the polyimide film; in which forming the polyimide film includes reacting a tetracarboxylic dianhydride component with a diamine component containing a diamine compound represented by general formula (1) to give a solution of a polyamic acid (a), forming a self-supporting film from the solution of the polyamic acid (a) and imidizing the self-supporting film by heating at a maximum heating temperature of 440° C. or lower to form the polyimide layer (a); in which R1 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms; and R2 represents hydrogen or alkyl or aryl having 1 to 12 carbon atoms.Type: ApplicationFiled: August 10, 2012Publication date: October 2, 2014Applicant: UBE INDUSTRIES, LTD.Inventors: Shin-ichiro Kohama, Nobuharu Hisano, Taizou Murakami, Kosuke Oishi, Hiroaki Yamaguchi