Patents by Inventor Nobuyuki Ishiwatari

Nobuyuki Ishiwatari has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11961996
    Abstract: Provided are: a negative electrode material for nonaqueous secondary batteries, which can yield a high-capacity nonaqueous secondary battery having excellent discharge rate characteristics; and a negative electrode for nonaqueous secondary batteries and a nonaqueous secondary battery. Also provided is a nonaqueous secondary battery having excellent charge-discharge efficiency. The negative electrode material for nonaqueous secondary batteries includes carbonaceous particles (A) and silicon oxide particles (B), and satisfies the followings: a) the average particle size (50% cumulative particle size from the smaller particle side; d50) is 3 ?m to 30 ?m, and the 10% cumulative particle size from the smaller particle side (d10) is 0.1 ?m to 10 ?m; b) the ratio (R1=d90/d10) between the 90% cumulative particle size from the smaller particle side (d90) and the d10 is 3 to 20; and c) the ratio (R2=d50/d10) between the d50 and the d10 is 1.7 to 5.
    Type: Grant
    Filed: May 22, 2019
    Date of Patent: April 16, 2024
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke Yamada, Nobuyuki Ishiwatari, Naoto Maru, Atsushi Watarai
  • Patent number: 11936044
    Abstract: A carbon material for a non-aqueous secondary battery containing a graphite capable of occluding and releasing lithium ions, and having a cumulative pore volume at pore diameters in a range of 0.01 ?m to 1 ?m of 0.08 mL/g or more, a roundness, as determined by flow-type particle image analysis, of 0.88 or greater, and a pore diameter to particle diameter ratio (PD/d50 (%)) of 1.8 or less, the ratio being given by equation (1A): PD/d50 (%)=mode pore diameter (PD) in a pore diameter range of 0.01 ?m to 1 ?m in a pore distribution determined by mercury intrusion/volume-based average particle diameter (d50)×100 is provided.
    Type: Grant
    Filed: January 5, 2017
    Date of Patent: March 19, 2024
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke Yamada, Nobuyuki Ishiwatari, Satoshi Akasaka, Daigo Nagayama, Shingo Morokuma, Koichi Nishio, Iwao Soga, Hideaki Tanaka, Takashi Kameda, Tooru Fuse, Hiromitsu Ikeda
  • Publication number: 20240055607
    Abstract: The present invention provides a carbon material composition containing a carbon material (A) and a carbon material (B), in which the carbon material (A) contains graphite containing an amorphous carbonaceous material or a graphite material, has two or more peaks in a pore size distribution measured by a mercury porosimetry, and satisfies y??0.0084x+0.13 wherein a cumulative pore volume in a range where a pore diameter is equal to or smaller than a pore diameter at a local minimum value between a peak of a smallest pore diameter and a peak of a second smallest pore diameter in the pore size distribution is defined as y (mL/g) and a coating rate of the amorphous carbonaceous material or the graphite material in the graphite is defined as x (%), and the carbon material (B) has a pellet density of 1.80/cm3 or more.
    Type: Application
    Filed: October 20, 2023
    Publication date: February 15, 2024
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Nobuyuki ISHIWATARI, Hisako KONDO, Masakazu YOKOMIZO
  • Publication number: 20230352686
    Abstract: A method for producing a carbon material may include: granulating a raw carbon material by applying mechanical energy comprising impact, compression, friction, and/or shear force. The granulating may be carried out in the presence of a granulating agent. The granulating agent may be liquid during the granulating of the raw carbon material. Alternatively or in addition, the granulating agent may include no organic solvent, an organic solvent having no flash point, or no organic solvent having a flash point of 5° C. or higher.
    Type: Application
    Filed: June 9, 2023
    Publication date: November 2, 2023
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Satoshi AKASAKA, Daigo NAGAYAMA, Shingo MOROKUMA, Koichi NISHIO, Iwao SOGA, Hideaki TANAKA, Takashi KAMEDA, Tooru FUSE, Hiromitsu IKEDA
  • Patent number: 11605810
    Abstract: The invention relates to composite graphite particles for a nonaqueous secondary battery negative electrode containing graphite (A) and metal particles (B) capable of alloying with Li, wherein the degree of dispersion of the metal particles (B) in the composite graphite particles is 0.78 or more and the internal void fraction of the composite graphite particles is 3% or more and 40% or less.
    Type: Grant
    Filed: December 8, 2021
    Date of Patent: March 14, 2023
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Akio Ueda, Satoshi Akasaka, Nobuyuki Ishiwatari, Junko Kagimoto, Shingo Morokuma
  • Publication number: 20220123311
    Abstract: A carbon material may include granulated particles made of a carbonaceous material and satisfying (2L), ? X 1 - X ? / X 1 ? 0.2 , ( 2 ? L ) wherein X is a volume-based average particle diameter determined by laser diffraction, and X1 is an equivalent circular diameter determined from a cross-sectional SEM image, which is a reflected electron image acquired at 10 kV, wherein the carbon material has an average inter-void distance Z of 30 granulated particles randomly selected from a cross-sectional SEM image of the carbon material, as Zave, and wherein the carbon material has volume-based average particle diameter X determined by laser diffraction in a Zave/X ratio of 0.060 or less.
    Type: Application
    Filed: December 30, 2021
    Publication date: April 21, 2022
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Satoshi AKASAKA, Daigo NAGAYAMA, Shingo MOROKUMA, Koichi NISHIO, Iwao SOGA, Hideaki TANAKA, Takashi KAMEDA, Tooru FUSE, Hiromitsu IKEDA
  • Publication number: 20220123309
    Abstract: A carbon material may include granulated particles satisfying (1L) and (2L): (1L) the granulated particles are made of a carbonaceous material; and (2L) the granulated particles satisfy the relationship |X1?X|/X1?0.2, wherein X is a volume-based average particle diameter determined by laser diffraction, and X1 is an equivalent circular diameter as determined from a cross-sectional SEM image, provided that the cross-sectional SEM image is a reflected electron image acquired at an acceleration voltage of 10 kV, wherein the carbon material has an average box-counting dimension relative to void regions of 30 particles of 1.55 or greater, as calculated from images obtained by randomly selecting 30 granulated particles from a cross-sectional SEM image of the carbon material, dividing the cross-sectional SEM image of each granulated particle into void regions and non-void regions, and binarizing the image. Such carbon material may be used in electrodes and batteries.
    Type: Application
    Filed: December 30, 2021
    Publication date: April 21, 2022
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Satoshi AKASAKA, Daigo NAGAYAMA, Shingo MOROKUMA, Koichi NISHIO, Iwao SOGA, Hideaki TANAKA, Takashi KAMEDA, Tooru FUSE, Hiromitsu IKEDA
  • Publication number: 20220123308
    Abstract: A carbon material may satisfying inequality (1K): 10.914 > 5 ? x k - y k - 0.0087 ? a , ( 1 ? K ) wherein a is a volume-based average particle diameter in um of the carbon material, xk is a true density in g/cm3 of the carbon material, and yk is a value determined by equation (2K): y k = D 100 - D T , ( 2 ? K ) wherein D100 is density in g/cm3 of carbon material under uniaxial load of 100 kgf/3.14 cm2, and DT is tap density of carbon material in g/cm3. Such carbon materials may be used in electrodes and batteries.
    Type: Application
    Filed: December 30, 2021
    Publication date: April 21, 2022
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Satoshi AKASAKA, Daigo NAGAYAMA, Shingo MOROKUMA, Koichi NISHIO, Iwao SOGA, Hideaki TANAKA, Takashi KAMEDA, Tooru FUSE, Hiromitsu IKEDA
  • Publication number: 20220123310
    Abstract: A carbon material may include granulated particles made of a carbonaceous material and satisfying (2L): ? X 1 - X ? / X 1 ? 0.2 , ( 2 ? L ) wherein X is a volume-based average particle diameter determined by laser diffraction, and X1 is an equivalent circular diameter determined from a cross-sectional SEM image, which is a reflected electron image acquired at an acceleration voltage of 10 kV, wherein X and X1 are determined from a cross-sectional SEM image, by drawing grid lines to split the minor axis and the major axis of a target granulated particle each into 20 parts to obtain a grid, and using cells in the grid, compartmentalizing the target granulated particle in a compartment.
    Type: Application
    Filed: December 30, 2021
    Publication date: April 21, 2022
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Satoshi AKASAKA, Daigo NAGAYAMA, Shingo MOROKUMA, Koichi NISHIO, Iwao SOGA, Hideaki TANAKA, Takashi KAMEDA, Tooru FUSE, Hiromitsu IKEDA
  • Publication number: 20220102707
    Abstract: The invention relates to composite graphite particles for a nonaqueous secondary battery negative electrode containing graphite (A) and metal particles (B) capable of alloying with Li, wherein the degree of dispersion of the metal particles (B) in the composite graphite particles is 0.78 or more and the internal void fraction of the composite graphite particles is 3% or more and 40% or less.
    Type: Application
    Filed: December 8, 2021
    Publication date: March 31, 2022
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Akio UEDA, Satoshi AKASAKA, Nobuyuki ISHIWATARI, Junko KAGIMOTO, Shingo MOROKUMA
  • Patent number: 11245108
    Abstract: The invention includes a method to provide composite graphite particles for a nonaqueous secondary battery negative electrode, wherein metal particles capable of alloying with Li can be internally present with favorable dispersibility. The present invention relates to composite graphite particles for a nonaqueous secondary battery negative electrode containing graphite (A) and metal particles (B) capable of alloying with Li, wherein the degree of dispersion of the metal particles (B) in the composite graphite particles is 0.78 or more.
    Type: Grant
    Filed: May 5, 2020
    Date of Patent: February 8, 2022
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Akio Ueda, Satoshi Akasaka, Nobuyuki Ishiwatari, Junko Kagimoto, Shingo Morokuma
  • Publication number: 20220013779
    Abstract: A negative electrode material for a nonaqueous secondary battery which contains a graphite that contains an amorphous carbonaceous material in at least a part of the surface; has a cumulative pore volume of 0.100 mL/g or less in a pore size range of 0.01 ?m to 1 ?m; and satisfies at least one of the following conditions (1) and (2) in a DTA curve obtained by differential thermal analysis (DTA) in an air stream: (1) the negative electrode material has no exothermic peak in a temperature range of 550° C. to 650° C.; and (2) the negative electrode material has an exothermic peak in a temperature range of 550° C. to 650° C., and the area of the exothermic peak is larger than 0 ?V·s/mg but 90 ?V·s/mg or smaller; a negative electrode for a nonaqueous secondary battery, which contains the same; and a nonaqueous secondary battery are provided.
    Type: Application
    Filed: September 28, 2021
    Publication date: January 13, 2022
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Tomohiro SATO, Hiroaki YOSHIDA, Akihiro KATO, Masakazu YOKOMIZO, Hiromitsu IKEDA, Hiroki SATO
  • Patent number: 11183679
    Abstract: Provided are: a negative electrode material for nonaqueous secondary batteries, which has a high capacity and exhibits excellent low-temperature input-output characteristics, charge-discharge rate characteristics, cycle characteristics, and the like; and a negative electrode for nonaqueous secondary batteries and a nonaqueous secondary battery, which include the negative electrode material. The negative electrode material for nonaqueous secondary batteries includes silicon oxide particles (A) and a carbon material (B), wherein the silicon oxide particles (A) contain zero-valent silicon atoms, and the carbon material (B) has a volume resistivity of less than 0.14 ?·cm at a powder density of 1.1 g/cm3.
    Type: Grant
    Filed: May 22, 2019
    Date of Patent: November 23, 2021
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Nobuyuki Ishiwatari, Shunsuke Yamada, Naoto Maru, Koji Fukamizu
  • Publication number: 20210184217
    Abstract: A negative electrode material for nonaqueous secondary batteries which includes graphite including amorphous carbon deposited on at least a part of the surface of the graphite. The negative electrode material has a density index (Dr-t) of 0.080 g/cm3 or less. The density index (Dr-t) is represented by Formula 1 below. Formula 1: Dr-t (g/cm3)=[Powder density (g/cm3) measured when volume resistivity is 0.
    Type: Application
    Filed: September 17, 2020
    Publication date: June 17, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Tomohiro SATO
  • Publication number: 20200287205
    Abstract: The invention includes a method to provide composite graphite particles for a nonaqueous secondary battery negative electrode, wherein metal particles capable of alloying with Li can be internally present with favorable dispersibility. The present invention relates to composite graphite particles for a nonaqueous secondary battery negative electrode containing graphite (A) and metal particles (B) capable of alloying with Li, wherein the degree of dispersion of the metal particles (B) in the composite graphite particles is 0.78 or more.
    Type: Application
    Filed: May 5, 2020
    Publication date: September 10, 2020
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Akio UEDA, Satoshi AKASAKA, Nobuyuki ISHIWATARI, Junko KAGIMOTO, Shingo MOROKUMA
  • Patent number: 10720645
    Abstract: An objet of the invention is to provide a non-aqueous electrolyte secondary battery superior in input-output characteristics even at a low temperature. To achieve the object, hybrid particles (carbon material) satisfying certain conditions, and composed of graphite particles and carbon particles with a primary particle size from 3 nm to 500 nm, preferably as well as amorphous carbon, are used as a negative electrode active material for a non-aqueous electrolyte secondary battery, so that the input-output characteristics of a non-aqueous electrolyte secondary battery at a low temperature can be improved remarkably.
    Type: Grant
    Filed: February 23, 2015
    Date of Patent: July 21, 2020
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke Yamada, Nobuyuki Ishiwatari, Akio Ueda, Tooru Fuse, Masakazu Yokomizo, Akihiro Katou
  • Publication number: 20200185721
    Abstract: Provided is a method to manufacture a composite carbon material capable of obtaining a non-aqueous secondary battery, which has high capacity, initial efficiency, and low charging resistance and is excellent in productivity. As a result thereof, a high-performance non-aqueous secondary battery is stably provided with efficiency. A composite carbon material for a non-aqueous secondary battery is provided, which contains at least a bulk mesophase artificial graphite particle (A) and graphite particle (B) having an aspect ratio of 5 or greater, and which is capable of absorbing and releasing lithium ions. A graphite crystal layered structure of the graphite particle (B) is arranged in the same direction as a direction of an outer peripheral surface of the bulk mesophase artificial graphite particle (A) at a part of a surface of the bulk mesophase artificial graphite particle (A), and an average circularity of the composite carbon material is 0.9 or greater.
    Type: Application
    Filed: February 14, 2020
    Publication date: June 11, 2020
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Satoshi AKASAKA, Iwao SOGA, Hideaki TANAKA, Tooru FUSE, Shingo MOROKUMA, Koichi NISHIO
  • Patent number: 10680238
    Abstract: The invention includes a method to provide composite graphite particles for a nonaqueous secondary battery negative electrode, wherein metal particles capable of alloying with Li can be internally present with favorable dispersibility. The present invention relates to composite graphite particles for a nonaqueous secondary battery negative electrode containing graphite (A) and metal particles (B) capable of alloying with Li, wherein the degree of dispersion of the metal particles (B) in the composite graphite particles is 0.78 or more.
    Type: Grant
    Filed: October 12, 2018
    Date of Patent: June 9, 2020
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Akio Ueda, Satoshi Akasaka, Nobuyuki Ishiwatari, Junko Kagimoto, Shingo Morokuma
  • Publication number: 20190312257
    Abstract: Provided are: a negative electrode material for nonaqueous secondary batteries, which has a high capacity and exhibits excellent low-temperature input-output characteristics, charge-discharge rate characteristics, cycle characteristics, and the like; and a negative electrode for nonaqueous secondary batteries and a nonaqueous secondary battery, which include the negative electrode material. The negative electrode material for nonaqueous secondary batteries includes silicon oxide particles (A) and a carbon material (B), wherein the silicon oxide particles (A) contain zero-valent silicon atoms, and the carbon material (B) has a volume resistivity of less than 0.14 ?·cm at a powder density of 1.1 g/cm3.
    Type: Application
    Filed: May 22, 2019
    Publication date: October 10, 2019
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Nobuyuki ISHIWATARI, Shunsuke Yamada, Naoto Maru, Koji Fukamizu
  • Publication number: 20190273248
    Abstract: Provided are: a negative electrode material for nonaqueous secondary batteries, which can yield a high-capacity nonaqueous secondary battery having excellent discharge rate characteristics; and a negative electrode for nonaqueous secondary batteries and a nonaqueous secondary battery. Also provided is a nonaqueous secondary battery having excellent charge-discharge efficiency. The negative electrode material for nonaqueous secondary batteries includes carbonaceous particles (A) and silicon oxide particles (B), and satisfies the followings: a) the average particle size (50% cumulative particle size from the smaller particle side; d50) is 3 ?m to 30 ?m, and the 10% cumulative particle size from the smaller particle side (d10) is 0.1 ?m to 10 ?m; b) the ratio (R1=d90/d10) between the 90% cumulative particle size from the smaller particle side (d90) and the d10 is 3 to 20; and c) the ratio (R2=d50/d10) between the d50 and the d10 is 1.7 to 5.
    Type: Application
    Filed: May 22, 2019
    Publication date: September 5, 2019
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Shunsuke YAMADA, Nobuyuki ISHIWATARI, Naoto MARU, Atsushi WATARAI