Patents by Inventor Nobuyuki Kibino

Nobuyuki Kibino has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8835580
    Abstract: The invention relates to a catalyst for the polymerization of norbornene monomers comprising transition metal complex (A) represented by formula (1); and a method for producing a norbornene (co)polymer, especially a norbornene copolymer containing a monomer unit represented by formulae (2) and (3), wherein a norbornen monomer is homopolyzed or copolymerized in the presence of the polymerization catalyst. Preferable examples of the transition metal complex (A) include (?-allyl){4-(2,6-diisopropylphenylimino)-2-penten-2-olato-?2N,O}palladium and (?-allyl){4-(1-naphthylimino)-2-penten-2-olato-?2N,O}palladium. In the formulae, the symbols are as defined in the description. A norbornene (co)polymer which has excellent transparency, excellent heat resistance, excellently low water absorption and excellent electrical insulation characteristics can be efficiently produced by the present invention.
    Type: Grant
    Filed: October 25, 2011
    Date of Patent: September 16, 2014
    Assignee: Showa Denko K.K.
    Inventors: Satoshi Fujibe, Nobuyuki Kibino
  • Patent number: 8598288
    Abstract: A catalyst for a polymerization of norbornene monomers includes a transition metal complex represented by a formula (1). A method for producing a norbornene copolymer includes copolymerizing first norbornene monomers corresponding to a first monomer unit represented by a formula (2) and second norbornene monomers corresponding to a second monomer unit represented by a formula (3) in a presence of the catalyst. The transition metal complex is preferably (?-allyl) {2-[N-(2,6-diisopropylphenyl) iminomethyl]phenolate}palladium, (?-allyl) {2-[N-(2,6-diisopropylphenyl)iminomethyl]-4-fluorophenolate}palladium, (?-allyl)[2-(N-phenyliminomethyl) phenolate]palladium or (?-allyl){2-[N-(2,6-diisopropylphenyl) iminomethyl]-6-methylphenolate}palladium.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: December 3, 2013
    Assignee: Showa Denko K.K.
    Inventors: Satoshi Fujibe, Nobuyuki Kibino, Tsuneo Tajima
  • Publication number: 20130261271
    Abstract: The invention relates to a catalyst for the polymerization of norbornene monomers comprising transition metal complex (A) represented by formula (1); and a method for producing a norbornene (co)polymer, especially a norbornene copolymer containing a monomer unit represented by formulae (2) and (3), wherein a norbornen monomer is homopolyzed or copolymerized in the presence of the polymerization catalyst. Preferable examples of the transition metal complex (A) include (?-allyl){4-(2,6-diisopropylphenylimino)-2-penten-2-olato-?2N,O}palladium and (?-allyl){4-(1-naphthylimino)-2-penten-2-olato-?2N,O}palladium. In the formulae, the symbols are as defined in the description. A norbornene (co)polymer which has excellent transparency, excellent heat resistance, excellently low water absorption and excellent electrical insulation characteristics can be efficiently produced by the present invention.
    Type: Application
    Filed: October 25, 2011
    Publication date: October 3, 2013
    Applicant: SHOWA DENKO K.K.
    Inventors: Satoshi Fujibe, Nobuyuki Kibino
  • Patent number: 8163860
    Abstract: The invention relates to a norbornene copolymer having excellent properties such as transparency, heat resistance, low water absorption and electric insulating property, which copolymer comprises a monomer unit represented by formula (1) and formula (2) and having a number average molecular weight (Mn) of 300,000 to 2,000,000. (In the formulae, R1 represents an alkyl group having 1 to 10 carbon atoms; and R2, R3 and R4 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: April 24, 2012
    Assignees: Showa Denko K.K., Riken
    Inventors: Shojiro Kaita, Nobuyuki Kibino, Kazufumi Kai
  • Publication number: 20110282014
    Abstract: The invention relates to a norbornene copolymer having excellent properties such as transparency, heat resistance, low water absorption and electric insulating property, which copolymer comprises a monomer unit represented by formula (1) and formula (2) and having a number average molecular weight (Mn) of 300,000 to 2,000,000. (In the formulae, R1 represents an alkyl group having 1 to 10 carbon atoms; and R2, R3 and R4 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.
    Type: Application
    Filed: January 29, 2010
    Publication date: November 17, 2011
    Applicants: RIKEN, SHOWA DENKO K.K.
    Inventors: Shojiro Kaita, Nobuyuki Kibino, Kazufumi Kai
  • Publication number: 20110124815
    Abstract: The invention relates to polyurethane having s excellent electric insulating property and thermal stability, obtained by a polyaddition reaction between a polyol copolymer which is a copolymer comprising as monomer units the structures represented by formulae (1) and (2) and a polyisocyanate compound: wherein R represents aliphatic hydrocarbon group having 2 to 20 carbon atoms, which may be branched and may contain a cyclic structure; and a production method thereof.
    Type: Application
    Filed: August 4, 2009
    Publication date: May 26, 2011
    Applicant: SHOWA DENKO K.K.
    Inventors: Nobuyuki Kibino, Kazufumi Kai
  • Publication number: 20100286354
    Abstract: The invention relates to an allyl alcohol copolymer comprising structures represented by formula (1) and (2) as monomer units. (In the formula, R represents an aliphatic hydrocarbon group having 2 to 20 carbon atoms, which may be branched or include a cyclic structure). The copolymer of the invention is excellent in compatibility with various resins, adhesiveness, electric insulation, low water absorption, thermal stability and surface active effect.
    Type: Application
    Filed: December 22, 2008
    Publication date: November 11, 2010
    Applicant: SHOWA DENKO K.K.
    Inventors: Nobuyuki Kibino, Yukiharu Hetsugi, Kazufumi Kai
  • Patent number: 7754926
    Abstract: The present invention reacts an allyl alcohol with an alcohol compound in the presence of a catalyst containing at least one element selected from the group consisting of elements of the group III, lanthanoid elements and actinoid elements of the Periodic Table, as depicted in the following reaction and provides a method for efficiently producing 3-alkoxy-1-propanol in a single step using an alcohol as a starting material.
    Type: Grant
    Filed: February 4, 2005
    Date of Patent: July 13, 2010
    Assignee: Showa Denko K.K.
    Inventors: Nobuyuki Kibino, Yasushi Kadowaki, Masaaki Sakai, Yukiharu Hetsugi
  • Publication number: 20070161828
    Abstract: In the presence of a catalyst containing at least one element selected from the group consisting of elements of the group III, lanthanoid elements and actinoid elements of the Periodic Table, an allyl alcohol is reacted with an alcohol compound. A method for efficiently producing 3-alkoxy-1-propanol in a single step using an alcohol as a starting material is provided.
    Type: Application
    Filed: February 4, 2005
    Publication date: July 12, 2007
    Inventors: Nobuyuki Kibino, Yasushi Kadowaki, Masaaki Sakai, Yukiharu Hetsugi
  • Patent number: 6303714
    Abstract: The present invention provides an olefin polymerization catalyst component comprising a transition metal compound represented by general formula (1) LmCpnMX1X2  (1) an olefin polymerization catalyst containing the catalyst component as a transition metal component, and a method of producing a polyolefin using the catalyst. According to the present invention, polyolefins having a wide molecular weight distribution and excellent moldability and containing small amounts of low molecular weight components can be produced with high activity.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: October 16, 2001
    Assignee: Japan Polyolefins Co., Ltd.
    Inventors: Nobuyuki Kibino, Kiyotaka Ishida, Tsugihiko Hakozaki, Tsutomu Sakuragi, Shigenobu Miyake, Shintaro Inazawa
  • Patent number: 5770664
    Abstract: A catalyst component for producing polyolefin, a catalyst for producing polyolefin using the catalyst component, and a process for producing polyolefin in the presence of the catalyst. The catalyst component comprises a metallocene compound represented by formula (1): ##STR1## All the symbols in formula (1) are defined in the description.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: June 23, 1998
    Assignee: Japan Polyolefins Co., Ltd.
    Inventors: Yoshikuni Okumura, Nobuyuki Kibino, Tetsuya Maki, Akihiro Hori, Kiyotaka Ishida, Shigenobu Miyake, Shintaro Inazawa
  • Patent number: 5349032
    Abstract: A metallocene having an asymmetric ligand which is represented by the formula below and its enantiomer: ##STR1## and a process for producing a polyolefin using the same as a catalyst component. The metallocene and its enantiomer are particularly effective in the production of highly stereospecific polyolefins.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: September 20, 1994
    Assignee: Showa Denko K.K.
    Inventors: Shigenobu Miyake, Nobuyuki Kibino, Takashi Monoi, Hiroyuki Ohira, Shintaro Inazawa
  • Patent number: 5329031
    Abstract: A metallocene having an asymmetric ligand which is represented by the formula below and its enantiomer: ##STR1## and a process for producing a polyolefin using the same as a catalyst component. The metallocene and its enantiomer are particularly effective in the production of highly stereospecific polyolefins.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: July 12, 1994
    Assignee: Showa Denko K.K.
    Inventors: Shigenobu Miyake, Nobuyuki Kibino, Takashi Monoi, Hiroyuki Ohira, Shintaro Inazawa