Abstract: Crude chlorosilane streams containing lower-boiling chlorosilanes and higher-boiling chlorosilanes are separated by contacting them with a distillation aid. The lower-boiling chlorosilanes are separated from the crude chlorosilane stream, and then the distillation aid and the higher-boiling chlorosilanes are separated from one another. The distillation aid is a mono-cyano-substituted organic compound, a nitro-substituted organic compound, a mono-cyano-substituted organosilicon compound, a nitro-substituted organosilicon compound, or a mixture thereof. These distillation aids increase the relative volatility of crude chlorosilane streams such as methyltrichlorosilane and dimethyldichlorosilane resulting in improved separation at lower capital and/or fixed costs.

Abstract: New binary azeotropes of octamethyltrisiloxane (MDM) with n-propoxypropanol, and the use of the binary azeotropes as environmentally friendly cleaning agents are disclosed. New azeotrope-like compositions of octamethyltrisiloxane and n-propoxypropanol are also disclosed.

Abstract: Binary azeotropic and azeotrope-like compositions contain 1-heptanol, cyclohexanol, or 4-methylcyclohexanol, with octamethyltrisiloxane, and the compositions are useful for cleaning, rinsing, or drying.

Abstract: Binary azeotropic and azeotrope-like compositions contain 1-heptanol, cyclohexanol, or 4-methylcyclohexanol, with octamethyltrisiloxane, and the compositions are useful for cleaning, rinsing, or drying.

Abstract: Binary azeotropes and azeotrope-like compositions contain n-butyl lactate, n-propoxypropanol, 1-butoxy-2-propanol, 1-butoxy-2-ethanol, or 4-methylcyclohexanol, with octamethylcyclotetrasiloxane, and are useful for cleaning, rinsing, or drying.

Abstract: New binary azeotropes of hexamethyldisiloxane with certain alcohols, and the use of the binary azeotropes as environmentally friendly cleaning agents are disclosed. The alcohol component of the binary azeotrope is 3-methyl-3-pentanol C.sub.2 H.sub.5 C(CH.sub.3)(OH) C.sub.2 H.sub.5 ; 2-pentanol CH.sub.3 CH.sub.2 CH.sub.2 CH(OH) CH.sub.3, or 1-methoxy-2-propanol CH.sub.3 OCH.sub.2 CH(CH.sub.3)OH.

Abstract: New binary azeotropes and azeotrope-like compositions are mixtures containing octamethyltrisiloxane and 2-butoxyethanol, 2-methylcyclohexanol, or isopropyl lactate. The mixtures are useful as environmentally friendly cleaning, rinsing, and drying agents.

Abstract: New binary azeotropes of octamethyltrisiloxane (MDM) with n-propoxypropanol, and the use of the binary azeotropes as environmentally friendly cleaning agents are disclosed. New azeotrope-like compositions of octamethyltrisiloxane and n-propoxypropanol are also disclosed.

Abstract: New binary azeotropes of octamethyltrisiloxane (MDM) with certain alcohols and an ester, and the use of the binary azeotropes as environmentally friendly cleaning agents are disclosed. The alcohol and ester components of the binary azeotrope are 2-methyl-1-pentanol, 1-hexanol, 1-butoxy-2-propanol, and ethyl lactate.

Abstract: A method for separating close-boiling chlorosilanes by the procedures of extractive distillation using sulfolane as the extractive solvent is described. An example of close-boiling chlorosilanes which can be separated by this method include dimethyldichlorosilane and methyltrichlorosilane containing mixtures. The invention comprises heating a mixture of the close-boiling chlorosilanes with sulfolane to distill the lower-boiling chlorosilane from the mixture and thereafter separating the sulfolane and the high-boiling chlorosilane.