Abstract: A process for multilayer coating of substrates includes applying a base coat layer of a water-based color- and/or special effect-imparting base coat composition onto a substrate, applying a clear coat layer of a transparent clear coat composition onto the base coat layer, and curing the clear coat layer. The base coat composition contains a water-dilutable polyurethane hybrid binder, obtained by polymerization of a polyurethane macromonomer, containing a lateral and/or terminal vinyl group, in the presence of an unsaturated monomer copolymerizable with the polyurethane macromonomer, a curing agent, and a pigment. The polyurethane macromonomer is based on a polyhydroxyl compound. The polyhydroxyl compound comprises at least about 50% by weight of at least one polycarbonate polyol, which is liquid at 20° C., the % by weight based on the total amount of the polyhydroxyl compound.

Abstract: Water-based coating compositions comprise a water-dilutable polyurethane hybrid binder, obtained by polymerization of a polyurethane macromonomer, containing a lateral and/or terminal vinyl group, in the presence of an unsaturated monomer copolymerizable with the polyurethane macromonomer, optionally a curing agent, and a pigment. The polyurethane macromonomer is based on a polyhydroxyl compound. The polyhydroxyl compound comprises at least about 50% by weight of a polycarbonate polyol, which is liquid at 20° C., the % by weight based on the total amount of the polyhydroxyl compound.

Abstract: The present invention relates to multilayer coatings of an optionally pre-coated substrate and processes for the multilayer coating of substrates. The multilayer coatings comprise a base coat layer of a water-based colour- and/or special effect-imparting base coat composition disposed on the optionally pre-coated substrate. The multilayer coatings further comprise a clear coat layer of a transparent clear coat composition disposed on the base coat layer. The water-based colour- and/or special effect-imparting base coat composition is a water-based coating composition comprising A) at least one water-dilutable polyurethane binder, B) optionally at least one curing agent, and C) at least one pigment. The at least one water-dilutable polyurethane binder is based on at least one polyhydroxyl compound, said polyhydroxyl compound comprises at least 50% by weight of at least one polycarbonate polyol, which is liquid at 20° C., the % by weight are based on the total amount of the polyhydroxyl compound.

Abstract: The present invention relates to water-based coating composition comprising A) at least one water-dilutable polyurethane binder, B) optionally at least one curing agent, and C) at least one pigment, characterised in that the at least one water-dilutable polyurethane binder is based on at least one polyhydroxyl compound, said polyhydroxyl compound comprises at least 50% by weight of at least one polycarbonate polyol, which is liquid at 20° C., the % by weight are based on the total amount of the polyhydroxyl compound. The invention also relates to the use of the water-based coating composition as base coat composition in a multilayer coating comprising a layer of a base coat composition and a layer of clear coat composition thereon. The water-based coating composition can be used as colour- and/or special effect imparting base coat composition in a multilayer coating comprising a layer of a base coat composition and a layer of a clear coat composition thereon.

Abstract: The invention relates to aqueous pigment dispersions comprising at least one dispersed pigment, an aqueous carrier and a copolymer prepared by polymerization of at least one macromonomer (1) having a terminal olefinic unsaturation with a mixture of olefinically unsaturated monomers (2), wherein the macromonomer (1) comprises 1a) 5-100% by weight of at least one polymerized acid functional unsaturated monomer, 1b) optionally at least one polymerized hydroxy functional unsaturated monomer, and optionally 1c) at least one further polymerized olefinically unsaturated monomer, and wherein the mixture of olefinically unsaturated monomers (2) comprises 2a) 5-80% by weight of at least one unsaturated vinyl aromatic monomer, 2b) 5-50% by weight of at least one vinyl monomer with at least one polar heterocyclic group with a 5 or 6 membered ring containing at least one ring nitrogen atom which is not connected to a hydrogen atom, and optionally 2c) other olefinically unsaturated monomers.

Abstract: A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a mixture A of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture A of 10 to 100 mg of KOH/g and 0.5 to 5 wt.

Abstract: The invention relates to aqueous pigment dispersions comprising at least one dispersed pigment, an aqueous carrier and a copolymer prepared by polymerization of at least one macromonomer (1) having a terminal olefinic unsaturation with a mixture of olefinically unsaturated monomers (2), wherein the macromonomer (1) comprises 1a) 5-100% by weight of at least one polymerized acid functional unsaturated monomer, 1b) optionally at least one polymerized hydroxy functional unsaturated monomer, and optionally 1c) at least one further polymerized olefinically unsaturated monomer, and wherein the mixture of olefinically unsaturated monomers (2) comprises 2a) 5-80% by weight of at least one unsaturated vinyl aromatic monomer, 2b) 5-50% by weight of at least one vinyl monomer with at least one polar heterocyclic group with a 5 or 6 membered ring containing at least one ring nitrogen atom which is not connected to a hydrogen atom, and optionally 2c) other olefinically unsaturated monomers.

Abstract: A curable silane resin, and a process for making same, having at least one of two units selected from the group consisting of a prepolymer (C) and a prepolymer (F); the prepolymer (C) having the formula (I): ##STR1## and the prepolymer (F) having the formula (III): ##STR2##The curable resin of our invention has excellent flexibility, solvent resistance and adhesion to organic materials. Furthermore our process for preparing the resin is simpler, more easily reproducible, and results in less unwanted by-prodducts than earlier processes for preparing similar silane resins.