Patents by Inventor Paul R. Van Rheenen

Paul R. Van Rheenen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11655319
    Abstract: A processing aid for foam molding comprising a copolymer obtained by the polymerization of from 50% to 100% by weight total of one or more monomers selected from the group consisting of ethyl methacrylate and propyl methacrylate, and 0 to 50% by weight of other copolymerizable monomers, the copolymer having the following properties: (a) a reduced viscosity measured according to ASTM D2857 at 1 mg/mL in chloroform at 25° C. of greater than 8 dL/g and (b) a Tg equal to or less than 77° C. is provided.
    Type: Grant
    Filed: August 31, 2016
    Date of Patent: May 23, 2023
    Assignee: Rohm and Haas Company
    Inventors: Michael T. Petr, Paul R. Van Rheenen
  • Patent number: 11584818
    Abstract: A processing aid for foam molding comprising a copolymer obtained by the polymerization of 30 to 90% by weight of methyl methacrylate, 10 to 70% by weight total of one or more monomers selected from the group consisting of butyl methacrylate (BMA), pentyl methacrylate (PMA) and hexyl methacrylate (HMA), and 0 to 20% by weight of other copolymerizable monomers, the copolymer having a reduced viscosity measured according to ASTM D2857 at 1 mg/mL in chloroform at 25° C. of greater than 8 dL/g is provided.
    Type: Grant
    Filed: August 31, 2016
    Date of Patent: February 21, 2023
    Assignee: Rohm and Haas Company
    Inventors: Michael T. Petr, Paul R. Van Rheenen
  • Patent number: 11214640
    Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: January 4, 2022
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Steven J. Broadwater
  • Patent number: 10611904
    Abstract: The present invention provides vinyl halide polymer thermoplastic polymer compositions comprising a multi-stage, or, preferably, two-stage acrylic copolymer polymeric additive having (A) a high Tg, high molecular weight first stage polymer that is free of, in copolymerized form, vinyl aromatic monomers, and having (B) a low Tg, low molecular weight second stage polymer of copolymerized vinyl aromatic containing monomers, wherein the multi-stage acrylic copolymer can be isolated by coagulation and drying and provides compositions having both melt strength and lubrication in thermoplastic processing.
    Type: Grant
    Filed: December 9, 2016
    Date of Patent: April 7, 2020
    Assignee: Rohm and Haas Company
    Inventors: Michael T. Petr, Paul R. Van Rheenen
  • Patent number: 10266687
    Abstract: A base resin including from 30 to 70 percent by weight impact modified acrylic resin having a Tg from 60 to 150° C.; from 70 to 30 percent by weight polyvinylchloride (PVC), wherein the weight percentages of the impact modified acrylic resin and the polyvinylchloride are based on the combined weight of the impact modified acrylic resin and the polyvinylchloride; from 0.25 to 4 weight percent of anti-melding additive based on the total base resin weight; and from 0.5 weight percent to 25 weight percent colorant based on total base resin weight is provided. Also provided are capstock compositions including one or more base resins, a process for making a capstock, and capstock produced thereby.
    Type: Grant
    Filed: April 28, 2015
    Date of Patent: April 23, 2019
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Scott W. Reading
  • Publication number: 20180362751
    Abstract: The present invention provides vinyl halide polymer thermoplastic polymer compositions comprising a multi-stage, or, preferably, two-stage acrylic copolymer polymeric additive having (A) a high Tg, high molecular weight first stage polymer that is free of, in copolymerized form, vinyl aromatic monomers, and having (B) a low Tg, low molecular weight second stage polymer of copolymerized vinyl aromatic containing monomers, wherein the multi-stage acrylic copolymer can be isolated by coagulation and drying and provides compositions having both melt strength and lubrication in thermoplastic processing.
    Type: Application
    Filed: December 9, 2016
    Publication date: December 20, 2018
    Inventors: Michael T. Petr, Paul R. Van Rheenen
  • Publication number: 20180258246
    Abstract: A processing aid for foam molding comprising a copolymer obtained by the polymerization of 30 to 90% by weight of methyl methacrylate, 10 to 70% by weight total of one or more monomers selected from the group consisting of butyl methacrylate (BMA), pentyl methacrylate (PMA) and hexyl methacrylate (HMA), and 0 to 20% by weight of other copolymerizable monomers, the copolymer having a reduced viscosity measured according to ASTM D2857 at 1 mg/mL in chloroform at 25° C. of greater than 8 dL/g is provided.
    Type: Application
    Filed: August 31, 2016
    Publication date: September 13, 2018
    Inventors: Michael T. Petr, Paul R. Van Rheenen
  • Publication number: 20180237606
    Abstract: A processing aid for foam molding comprising a copolymer obtained by the polymerization of from 50% to 100% by weight total of one or more monomers selected from the group consisting of ethyl methacrylate and propyl methacrylate, and 0 to 50% by weight of other copolymerizable monomers, the copolymer having the following properties: (a) a reduced viscosity measured according to ASTM D2857 at 1 mg/mL in chloroform at 25° C. of greater than 8 dL/g and (b) a Tg equal to or less than 77° C. is provided.
    Type: Application
    Filed: August 31, 2016
    Publication date: August 23, 2018
    Inventors: Michael T. Petr, Paul R. Van Rheenen
  • Patent number: 9908958
    Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.
    Type: Grant
    Filed: December 28, 2011
    Date of Patent: March 6, 2018
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Steven P. Broadwater
  • Publication number: 20170081510
    Abstract: A base resin including from 30 to 70 percent by weight impact modified acrylic resin having a Tg from 60 to 150° C.; from 70 to 30 percent by weight polyvinylchloride (PVC), wherein the weight percentages of the impact modified acrylic resin and the polyvinylchloride are based on the combined weight of the impact modified acrylic resin and the polyvinylchloride; from 0.25 to 4 weight percent of anti-melding additive based on the total base resin weight; and from 0.5 weight percent to 25 weight percent colorant based on total base resin weight is provided. Also provided are capstock compositions including one or more base resins, a process for making a capstock, and capstock produced thereby.
    Type: Application
    Filed: April 28, 2015
    Publication date: March 23, 2017
    Inventors: Paul R. Van Rheenen, Scott W. Reading
  • Patent number: 9399710
    Abstract: A thermoplastic composition comprising the melt blending product of one or more thermoplastic polymers; and from 2 to 20 PHR, of one or more gloss reducing additives wherein each gloss reducing additive comprises a (meth)acrylate copolymer having a glass transition temperature of greater than or equal to 40° C. and 0.001 to 0.04 PHM derived from one or more crosslinking monomers and/or graft-linking agents having two or more ethylenically unsaturated radicals capable of free-radical polymerization, wherein a test specimen produced from the thermoplastic composition has roughness according to DIN 4768 of Ra greater than or equal to 0.6 microns, Rz greater than or equal to 6 microns, Rmax greater than or equal to 7 microns, and a gloss less than 65, 75 degree angle, is provided. Methods for producing the thermoplastic compositions, methods for producing articles from the thermoplastic compositions and such articles are also provided.
    Type: Grant
    Filed: May 4, 2015
    Date of Patent: July 26, 2016
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Veera Nelliappan, Seth T. Stewart
  • Publication number: 20160152750
    Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.
    Type: Application
    Filed: February 3, 2016
    Publication date: June 2, 2016
    Inventors: Paul R. Van Rheenen, Steven J. Broadwater
  • Patent number: 9309397
    Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.
    Type: Grant
    Filed: December 29, 2011
    Date of Patent: April 12, 2016
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Steven J. Broadwater
  • Publication number: 20150232655
    Abstract: A thermoplastic composition comprising the melt blending product of one or more thermoplastic polymers; and from 2 to 20 PHR, of one or more gloss reducing additives wherein each gloss reducing additive comprises a (meth)acrylate copolymer having a glass transition temperature of greater than or equal to 40° C. and 0.001 to 0.04 PHM derived from one or more crosslinking monomers and/or graft-linking agents having two or more ethylenically unsaturated radicals capable of free-radical polymerization, wherein a test specimen produced from the thermoplastic composition has roughness according to DIN 4768 of Ra greater than or equal to 0.6 microns, Rz greater than or equal to 6 microns, Rmax greater than or equal to 7 microns, and a gloss less than 65, 75 degree angle, is provided. Methods for producing the thermoplastic compositions, methods for producing articles from the thermoplastic compositions and such articles are also provided.
    Type: Application
    Filed: May 4, 2015
    Publication date: August 20, 2015
    Inventors: Paul R. Van Rheenen, Veera Nelliappan, Seth T. Stewart
  • Patent number: 9051459
    Abstract: A thermoplastic composition comprising the melt blending product of one or more thermoplastic polymers; and from 2 to 20 PHR, of one or more gloss reducing additives wherein each gloss reducing additive comprises a (meth)acrylate copolymer having a glass transition temperature of greater than or equal to 40° C. and 0.001 to 0.04 PHM derived from one or more crosslinking monomers and/or graft-linking agents having two or more ethylenically unsaturated radicals capable of free-radical polymerization, wherein a test specimen produced from the thermoplastic composition has roughness according to DIN 4768 of Ra greater than or equal to 0.6 microns, Rz greater than or equal to 6 microns, Rmax greater than or equal to 7 microns, and a gloss less than 65, 75 degree angle, is provided. Methods for producing the thermoplastic compositions, methods for producing articles from the thermoplastic compositions and such articles are also provided.
    Type: Grant
    Filed: October 10, 2011
    Date of Patent: June 9, 2015
    Assignee: Rohm and Haas Company
    Inventors: Paul R. Van Rheenen, Veera Nelliappan, Seth T. Stewart
  • Publication number: 20140371396
    Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.
    Type: Application
    Filed: December 28, 2011
    Publication date: December 18, 2014
    Inventors: Paul R. Van Rheenen, Steven P. Broadwater
  • Publication number: 20120208963
    Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.
    Type: Application
    Filed: December 29, 2011
    Publication date: August 16, 2012
    Inventors: Paul R. Van Rheenen, Steven J. Broadwater
  • Publication number: 20120108751
    Abstract: A thermoplastic composition comprising the melt blending product of one or more thermoplastic polymers; and from 2 to 20 PHR, of one or more gloss reducing additives wherein each gloss reducing additive comprises a (meth)acrylate copolymer having a glass transition temperature of greater than or equal to 40° C. and 0.001 to 0.04 PHM derived from one or more crosslinking monomers and/or graft-linking agents having two or more ethylenically unsaturated radicals capable of free-radical polymerization, wherein a test specimen produced from the thermoplastic composition has roughness according to DIN 4768 of Ra greater than or equal to 0.6 microns, Rz greater than or equal to 6 microns, Rmax greater than or equal to 7 microns, and a gloss less than 65, 75 degree angle, is provided. Methods for producing the thermoplastic compositions, methods for producing articles from the thermoplastic compositions and such articles are also provided.
    Type: Application
    Filed: October 10, 2011
    Publication date: May 3, 2012
    Applicant: ROHM AND HAAS COMPANY
    Inventors: Paul R. Van Rheenen, Veera Nelliappan, Seth T. Stewart
  • Patent number: 7001949
    Abstract: An aqueous coating composition comprising a comb copolymer is disclosed. A method of forming a coating from the aqueous coating composition, and a coating formed by that method are also disclosed, as is a method of forming the comb copolymer. The comb copolymer is characterized in that aqueous dispersions of the comb copolymer have a Hard/Soft Balance Advantage value of at least 25%. The aqueous coating composition is capable of producing coatings having an excellent balance of hard and soft properties.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: February 21, 2006
    Assignee: Rohm and Haas Company
    Inventors: David M. Fasano, Karl A. Bromm, Willie Lau, Jack C. Thibeault, David A. Larson, Paul R. Van Rheenen
  • Patent number: 6809141
    Abstract: An aqueous dispersion of a segmental copolymer, wherein the aqueous dispersion has a Hard/Soft Balance Advantage value of at least 25% is disclosed. A method for preparing the aqueous dispersion of a segmental copolymer is also disclosed, as is a film produced thereby.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: October 26, 2004
    Assignee: Rohm and Haas Company
    Inventors: David M. Fasano, Karl A. Bromm, Willie Lau, Jack C. Thibeault, David A. Larson, Paul R. Van Rheenen