Patents by Inventor Paul Schulz
Paul Schulz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20060025753Abstract: This document describes a urinary catheter assembly that can reduce the need for a user to handle the urinary catheter directly, thereby reducing the likelihood of a urinary tract infection and making the cathing process less messy. In one aspect, a urinary catheter apparatus and methods for voiding a human's bladder and enabling a human patient to void his or her bladder are provided.Type: ApplicationFiled: August 2, 2004Publication date: February 2, 2006Inventors: Thomas Kubalak, Teena Broumand, Paul Schulz, Robert Lutzke, Dennis Femrite
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Patent number: 5898070Abstract: The invention relates to an improved process for the production of alkyl and/or alkenyl oligoglycosides corresponding to formula (I):R.sup.1 O-?G!.sub.p (I)in which R.sup.1 is an alkyl and/or alkenyl radical containing 4 to 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1 to 10, by acid-catalyzed acetalization of primary alcohols with monomeric carbohydrates, in which the reaction is carried out in a stirred tank reactor surmounted by a vacuum falling-film evaporator through which the mixture is pumped under reaction conditions.Type: GrantFiled: March 17, 1997Date of Patent: April 27, 1999Assignee: Henkel CorporationInventors: Paul Schulz, deceased, Rainer Eskuchen, Michael Nitsche
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Patent number: 5792843Abstract: Alkyl and/or alkenyl oligoglucosides can be produced at high reaction rates by a process in which glucose having a particle size distribution of at least 80% in the 20 to 300 .mu.m range is subjected to acidic acetalization with fatty alcohols. Products having a high percentage content of mono-glucosides are obtained.Type: GrantFiled: January 22, 1996Date of Patent: August 11, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Schulz, Rainer Eskuchen
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Patent number: 5569752Abstract: Light-colored lower alkyl oligoglucosides having a low polyglucose content can be obtained in short reaction times by a process in whicha) aqueous glucose sirup is added to a mixture of a lower alcohol and an acidic catalyst at elevated temperatures via an inline mixer,b) the water present in the reaction mixture and the water released are azeotropically distilled off continuously andc) after the addition of glucose sirup, the reaction mixture is subjected to heating until at least 99% of the glucose is reacted.Type: GrantFiled: June 6, 1994Date of Patent: October 29, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Schulz, Herbert Esser, Rainer Eskuchen
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Patent number: 5554741Abstract: The aliphatic primary alcohols are reacted with a glycose, more especially glucose, in the presence of an acidic catalyst in certain process steps so that particularly light-colored and alkali-stable alkyl glucosides are obtained after a subsequent, compulsory bleaching step, which represents an improvement over known direct synthesis processes. The process may be carried out both on a laboratory scale and also on an industrial production scale.Type: GrantFiled: September 1, 1994Date of Patent: September 10, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Franz-Josef Carduck, Paul Schulz, Rainer Eskuchen
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Patent number: 5538669Abstract: Water-based surfactant pastes, more particularly those containing nonionic surfactants of the alkyl glycoside type, are effectively stabilized against microbial infestation if, after oxidative bleaching to eliminate alkali-sensitive color bodies, they are adjusted to a pH value of at least 11 by addition of alkaline substances.Type: GrantFiled: April 19, 1995Date of Patent: July 23, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Schulz, Rainer Eskuchen, Manfred Weuthen
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Patent number: 5536431Abstract: A process for the production of free-flowing detergent granules or partial granules comprising the steps of:(a) providing an interiorly baffled, rotatable drying apparatus capable of rotating at high speeds;(b) introducing water-containing alkyl or alkenyl oligoglycoside pastes into the rotatable, drying apparatus;(c) introducing into the drying apparatus detergent components selected from the group consisting of anionic surfactants, nonionic surfactants, detergent builders, and mixtures thereof; and(d) simultaneously drying and granulating the water-containing alkyl or alkenyl oligolycoside pastes and detergent components.Type: GrantFiled: September 23, 1994Date of Patent: July 16, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Franz-Josef Carduck, Paul Schulz, Rainer Eskuchen
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Patent number: 5510482Abstract: The crude reaction products from the synthesis of alkyl glycosides are bleached by kneading the material substantially freed from the excess fatty alcohol and containing at most limited quantities of water with an oxidizing agent at such elevated temperatures that the reaction mixture lends itself to plastic processing. Temperatures of from about 50.degree. to 150.degree. C. are particularly suitable, although it is best to apply temperatures in the range from about 80.degree. to 100.degree. C. using aqueous hydrogen peroxide as the oxidizing agent. Bleaching is carried out under basic conditions, optionally by addition of an alkaline compound, such as for example 50% sodium hydroxide solution. The bleached product accumulates in the form of a solid. It is preferably mixed with typical compatible solids, more particularly typical constituents of detergents and cleaning preparations, to form a solid and preferably free-flowing alkyl glycoside compound.Type: GrantFiled: October 17, 1994Date of Patent: April 23, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Willi Wuest, Rainer Eskuchen, Paul Schulz, Volker Bauer, Franz-Josef Carduck, Herbert Esser, Christiane Zeise, Manfred Weuthen, Josef Penninger
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Patent number: 5480979Abstract: Alkyl and/or alkenyl oligoglycosides can be obtained in short reaction times and high yields by a process in which glycose is reacted with fatty alcohols at elevated temperature in the presence of sulfomonocarboxylic acids containing 2 to 8 carbon atoms, carboxylic anhydrides thereof and/or mixed cyclic sulfonic/carboxylic anhydrides thereof as acidic catalysts, the water of reaction is removed and the reaction products are worked up.Type: GrantFiled: May 13, 1994Date of Patent: January 2, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Manfred Weuthen, Karlheinz Hill, Paul Schulz
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Patent number: 5478930Abstract: Light-colored alkyl or alkenyl oligoglucosides are obtained by a process in which glucose or aqueous starch degradation products are reacted with fatty alcohols in the presence of acidic catalysts which are obtained by partial sulfation of C.sub.4-22 fatty alcohols.Type: GrantFiled: August 10, 1994Date of Patent: December 26, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Patrick M. McCurry, Jr., Rainer Eskuchen, Paul Schulz
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Patent number: 5463114Abstract: Ether carboxylic acids of the formula (I):R--(OC.sub.m H.sub.2m).sub.n --O--CH.sub.2 COOM (I)wherein R is an alkyl group having from 1 to about 22 carbon atoms, an aryl group or an aralkyl group; m is 2 or 3; n is a number from 1 to about 200; M is an alkali metal are made by oxidation of an ether alcohol wherein the ether alcohol, oxygen, and an alkali metal hydroxide are continuously added to an aqueous dispersion of a noble metal catalyst under reduced pressure.Type: GrantFiled: April 13, 1994Date of Patent: October 31, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolf-Eckart Noack, Paul Schulz, F. Norman Tuller
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Patent number: 5456850Abstract: The invention relates to a fluid to pasty, phosphate-free washing agent, containing, based on the washing agent, (A) a tenside component of 20 to 35% w/w which comprises (A1) 1 to 4% w/w of anionic tensides of the class of sulphonates and soaps, (A2) 16 to 34% w/w non-ionic tensides with a setting point of, at the highest, 10.degree. C., (B) 10 to 35% w/w builder salts which are either complexing or which bind alkaline earth metal ions, (C) 15 to 40% w/w sodium metasilicate, (D) 8 to 25% w/w bleaching per-salts, (E) up to 15% w/w other washing agent ingredients, (F) less than 3% w/w water, with the proviso that the sum of components B+C=30 to 60% w/w.Type: GrantFiled: August 14, 1991Date of Patent: October 10, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Uwe Trabitzsch, Guenther Amberg, Paul Schulz, Jean-Marie Paillau
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Patent number: 5278327Abstract: The use of a fatty oil ex Helianthus annuus containing 78 to 92% by weight oleic acid and 2 to 10% by weight linoleic acid for the production of diperazelaic acid, with elimination of enrichment steps with respect to the oleic acid content, by fat splitting, distillation, oxidative ozonolysis of the fatty acid mixture obtained, and reaction of the azelaic acid thus obtained with hydrogen peroxide to form diperazelaic acid. The resulting diperazelaic acid has improved stability in storage and is obtained in high yields and in highly pure form.Type: GrantFiled: May 6, 1988Date of Patent: January 11, 1994Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Eierdanz, Paul Schulz, Beatrix Kottwitz
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Patent number: 5008031Abstract: A liquid detergent based on nonionic and anionic surfactants, and optionally particulate builder materials, contains a non-surfactant component which increases the wash efficiency, comprising the combination of low-polarity and mid- to high-polarity organic liquids. The low-polarity liquids are hydrocarbons, while the mid- to high-polarity liquids are esters, ethers, ketones or alcohols. The detergents have a satisfactory viscosity behavior, good miscibility with water and good wash efficiency.Type: GrantFiled: March 15, 1989Date of Patent: April 16, 1991Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Schulz, Karl Schwadtke
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Patent number: 5002695Abstract: A foam regulator consisting essentially of a mixture, applied to a particulate support material, of (a) 5 to 60% of a paraffin wax, (b) 20 to 90% of a microcrystalline paraffin wax which shows defined melting behavior as a function of temperature and (c) 5% to 20% of a diamide derived from C.sub.2 -C.sub.7 diamines and C.sub.12 -C.sub.22 fatty acids which is present in the paraffin mixture in very finely divided form. The mixture is preferably prepared by reaction of the diamines with the fatty acids in a molten mixture of components (a) and (b) in the presence of an acidic catalyst.Type: GrantFiled: September 30, 1988Date of Patent: March 26, 1991Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Schulz, Juergen Haerer, Claus-Peter Kurzendoerfer, Franz-Josef Carduck, Friedrich W. Diekoetter, Ulrich Jahnke, Edmund Schmadel
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Patent number: 4956124Abstract: Bicyclic decanedioic acids corresponding to the following general formula ##STR1## in which R represents a C.sub.1 -C.sub.22 alkyl radical, a C.sub.2 -C.sub.34 alkylcarbonyl radical, or a residue of a polyalkoxylated C.sub.2 -C.sub.22 fatty alcohol, represent a new class of dicarboxylic acids which are useful as flotation aids in the flotation of non-sulfidic ores.Type: GrantFiled: May 11, 1988Date of Patent: September 11, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Eierdanz, Paul Schulz, Wolfgang von Rybinski, Rita Koester
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Patent number: 4940808Abstract: A process for the ozonization of unsaturated organic compounds in a reaction column through which the unsaturated compounds--in solution in a protic solvent--and an ozone-containing carrier gas and an inert coolant are passed downward in co-current flow to provide for an improved coolant effect and an increased ozonization yield where the coolant comprises a compound gaseous or liquid at ambient temperature with a boiling point preferably in the range from +20.degree. C. to -200.degree. C. The boiling point of the coolant is preferably at least 5.degree. C. below the ozonization temperature.Type: GrantFiled: July 7, 1988Date of Patent: July 10, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Paul Schulz, Michael J. Virnig, Franz J. Carduck
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Patent number: 4929380Abstract: The invention provides a substantially anhydrous gas-free liquid detergent based on non-ionic surfactants containing a liquid surfactant component comprising adducts of from 2 to 8 moles ethylene oxide with 1 mole C.sub.10-20 - fatty alcohol, anionic surfactant, and low molecular weight polyethylene glycol. The liquid surfactant component makes up at least 20% by weight of the detergent as a whole; the ratio of fatty alcohol ethoxylate to anionic surfactant is from 1:1 to 2:1; and the detergent has a density of from 1.4 to 1.8. Typically, the detergent includes a particulate solids component which is incorporated with the liquid components as separate component fractions of differing particle size.Type: GrantFiled: October 19, 1988Date of Patent: May 29, 1990Assignee: Henkel Kommanditgesellschaft aug AktienInventors: Paul Schulz, Karl Schwadtke, Eduard Smulders
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Patent number: 4889644Abstract: A machine washing process with process-controlled dosing of water and detergent using a paste-form, phosphate-reduced or phosphate-free detergent which is substantially free from water, organic solvents and hydrotropic compounds. The paste comprises a phase liquid at a temperature below 10.degree. C. and contains a nonionic surfactant selected from the group of polyglycolether compounds and of a solid phase dispersed therein in which the particles have a mean particle size of from 5 to 40 .mu.m and less than 5% of the particles have a particle size larger than 80 .mu.m, the solid phase comprising washing alkalis, sequestering compounds and other detergent constituents and, optionally, anionic surfactants. Under the control of a process-control computer, the paste is taken from a storage container, delivered to a mixer and diluted therein with water to at least such an extent that the formation of a gel phase is avoided.Type: GrantFiled: June 15, 1988Date of Patent: December 26, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Guenther Amberg, Wolfgang Bechstedt, Paul Schulz, Uwe Trabitzsch
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Patent number: RE36549Abstract: The use of a fatty oil ex Helianthus annuus containing 78 to 92% by weight oleic acid and 2 to 10% by weight linoleic acid for the production of .Iadd.azelaic acid or for the production of .Iaddend.diperazelaic acid .Iadd.from the azelaic acid thus produced.Iaddend., with elimination of enrichment steps with respect to the oleic acid content, by fat splitting, distillation, oxidative ozonolysis of the fatty acid mixture obtained, and .Iadd.in the case of production of diperazelaic acid by .Iaddend.reaction of the azelaic acid thus obtained with hydrogen peroxide to form diperazelaic acid. The resulting diperazelaic acid has improved stability in storage and is obtained in high yields and in highly pure form.Type: GrantFiled: December 21, 1994Date of Patent: February 1, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Eierdanz, Paul Schulz, Beatrix Kottwitz