Abstract: Thermoformed articles comprising a film thermoformed to be in the form of a pouch defining an interior pouch volume, the film comprising a mixture of a polyvinyl alcohol resin and a plasticizer, wherein the plasticizer is provided in an amount in a range of about 5 to about 30 weight parts, based on 100 weight parts of total polyvinyl alcohol resin; wherein the thermoformed film in the form of a pouch defining an interior pouch volume is characterized by a draw ratio in a range of about 2.3 to about 2.9; the article is characterized by a release time of at least 30 seconds when formed into a sealed packet and tested in accordance with the Liquid Release Test; and the article is characterized by a residue value of at most 9%, as determined by the Residue Test.

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a first copolymer including a first anionic monomer unit and a second PVOH copolymer including a second anionic monomer unit. When the PVOH copolymers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits maintained film stiffness, and pouch tautness when in contact with liquid pouch contents, maintain acceptable clarity properties, and/or demonstrate acceptable band release without impairing the ultimate solubility of the water-soluble film.

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a first copolymer including a first anionic monomer unit and a second PVOH copolymer including a second anionic monomer unit. When the PVOH copolymers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits maintained film stiffness, and pouch tautness when in contact with liquid pouch contents, and/or maintain acceptable clarity properties, without impairing the ultimate solubility of the water-soluble film.

Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. The PVOH resin blend includes a first copolymer including a first anionic monomer unit and a second PVOH copolymer including a second anionic monomer unit. When the PVOH copolymers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits maintained film stiffness, and pouch tautness when in contact with liquid pouch contents, and/or maintain acceptable clarity properties, without impairing the ultimate solubility of the water-soluble film.

Abstract: The disclosure provides a water-soluble film, including a mixture of a water-soluble polyvinyl alcohol, a plasticizer, and a starch, wherein (a) the starch includes a hydroxypropylated starch in an amount of about 5 phr to about 30 phr; (b) the starch includes a modified starch having a degree of modification greater than about 2%, in an amount of about 2.5 phr to about 30 phr; (c) the starch is an unmodified starch having an amylose content of about 20% to about 80%; or (d) the starch includes a hydroxypropylated starch having an amylose content of about 23% to about 95% and the polyvinyl alcohol includes unmodified polyvinyl alcohol or anionic modified polyvinyl alcohol with the proviso that the anionic modifier is not acrylate. The disclosure further provides a sealed article including a water-soluble film in the form of a pouch defining an interior pouch volume.

Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.

Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.

Abstract: Disclosed herein are capsules for delayed release of an active ingredient contained therein, in particular water-soluble capsules for delayed release of water-sensitive, gas-generating compositions into an aqueous liquid medium. The delayed release capsules incorporate one or more gas-relief pinholes for gas-generating water-sensitive compositions contained in the capsules, such as inorganic bleach or other alkaline compositions intended for delayed release into a wash medium during a laundry cycle. The pinholes permit gas generated within the capsule due to exposure to environmental water vapor to escape from the capsule interior, preventing pressure build-up and capsule deformation during storage. The pinholes are sized to prevent or otherwise substantially limit the passage of liquids when submerged in a liquid medium (e.g., liquid water in an aqueous liquid medium). Related articles and methods for delivering the capsules in combination with a detergent or other laundry composition are also disclosed.

Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.

Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.

Abstract: Disclosed herein are capsules for delayed release of an active ingredient contained therein, in particular water-soluble capsules for delayed release of water-sensitive, gas-generating compositions into an aqueous liquid medium. The delayed release capsules incorporate one or more gas-relief pinholes for gas-generating water-sensitive compositions contained in the capsules, such as inorganic bleach or other alkaline compositions intended for delayed release into a wash medium during a laundry cycle. The pinholes permit gas generated within the capsule due to exposure to environmental water vapor to escape from the capsule interior, preventing pressure build-up and capsule deformation during storage. The pinholes are sized to prevent or otherwise substantially limit the passage of liquids when submerged in a liquid medium (e.g., liquid water in an aqueous liquid medium). Related articles and methods for delivering the capsules in combination with a detergent or other laundry composition are also disclosed.

Abstract: Disclosed herein are sealing solutions for sealing water-soluble films, in particular aqueous mixtures including one or more polymeric solvents such as polyols. Aqueous sealing solutions including a relatively dilute solvent for one or more polymeric components of the water-soluble film (e.g., water-soluble polymeric components thereof, such as polyvinyl alcohol (PVOH)) can exhibit one or more benefits, including a reduction in dissolution of the film by the sealing solution and an increase in seal strength. Also disclosed are sealed articles formed with the sealing solutions, for example water-soluble packets containing various liquid or solid compositions.