Abstract: A process for the production of Li2MSiO4 where M is selected from the group Fe, Mn, Co, and Ni, is disclosed. The process uses an atmospheric-pressure solvothermal synthesis and a calcining step wherein the solvent is selected to be stable from decomposition over the solvothermal process conditions. The solvothermal solvent is recoverable and reusable. The process also relies on an excess of lithium in the starting materials mix to promote phase-purity of the Li2MSiO4 crystalline phase. The Li2MSiO4 material is used as a cathode material in a lithium ion battery cell.

Abstract: A method of making cerium-containing metal oxide nanoparticles in non-polar solvent eliminates the need for solvent shifting steps. The direct synthesis method involves: (a) forming a reaction mixture of a source of cerous ion and a carboxylic acid, and optionally, a hydrocarbon solvent; and optionally further comprises a non-cerous metal ion; (b) heating the reaction mixture to oxidize cerous ion to ceric ion; and (c) recovering a nanoparticle of either cerium oxide or a mixed metal oxide comprising cerium. The cerium-containing oxide nanoparticles thus obtained have cubic fluorite crystal structure and a geometric diameter in the range of about 1 nanometer to about 20 nanometers. Dispersions of cerium-containing oxide nanoparticles prepared by this method can be used as a component of a fuel or lubricant additive.

Abstract: A process for the production of Li2MSiO4, wherein M is Mn, Fe, or Co, is disclosed. The process uses an atmospheric-pressure solvo-thermal synthesis in a high boiling-point amine solvent selected to be stable with respect to decomposition over the solvothermal process conditions. A subsequent calcination results in a substantially single phase powder of crystalline Li2MSiO4. The solvothermal solvent is recoverable and reusable. The process also uses on an excess of lithium in the starting materials mix to promote phase-purity of the Li2MSiO4 crystalline phase. The Li2MSiO4 material is used as a cathode material in a lithium ion battery cell.

Abstract: A process for the production of Li2MSiO4 where M is selected from the group Fe, Mn, Co, and Ni, is disclosed. The process uses an atmospheric-pressure solvothermal synthesis and a calcining step wherein the solvent is selected to be stable from decomposition over the solvothermal process conditions. The solvothermal solvent is recoverable and reusable. The process also relies on an excess of lithium in the starting materials mix to promote phase-purity of the Li2MSiO4 crystalline phase. The Li2MSiO4 material is used as a cathode material in a lithium ion battery cell.

Abstract: A method of making cerium-containing metal oxide nanoparticles in non-polar solvent eliminates the need for solvent shifting steps. The direct synthesis method involves: (a) forming a reaction mixture of a source of cerous ion and a carboxylic acid, and optionally, a hydrocarbon solvent; and optionally further comprises a non-cerous metal ion; (b) heating the reaction mixture to oxidize cerous ion to ceric ion; and (c) recovering a nanoparticle of either cerium oxide or a mixed metal oxide comprising cerium. The cerium-containing oxide nanoparticles thus obtained have cubic fluorite crystal structure and a geometric diameter in the range of about 1 nanometer to about 20 nanometers. Dispersions of cerium-containing oxide nanoparticles prepared by this method can be used as a component of a fuel or lubricant additive.