Patents by Inventor Peter M. Lange
Peter M. Lange has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5152986Abstract: Known antibacterial quinolonecarboxylic acid derivatives such as ciprofloxacin are administered to animals in their food in the form of weak cation exchangers loaded therewith. The taste is much improved and the animals accept the material more readily.Type: GrantFiled: October 24, 1989Date of Patent: October 6, 1992Assignee: Bayer AktiengesellschaftInventors: Peter M. Lange, Alfred Mitschker, Arundev H. Naik, Hubert Rast, Martin Scheer, Herbert Voege
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Patent number: 5059306Abstract: In the removal of pure aromatics from aromatic-containing hydrocarbon mixtures by liquid-phase extraction or extractive distillation using a selective solvent, the specific cost of separation can be reduced at the same yield of aromatics or the yield of aromatics can be increased at the same specific cost of separation if the liquid-phase extraction or the extractive distillation is carried out in the presence of a reactive solid. At the same time, substantially aromatic-free raffinates are obtained.Type: GrantFiled: June 21, 1990Date of Patent: October 22, 1991Assignee: Bayer AktiengesellschaftInventors: Hans-Joachim Kramer, Bruno Schulwitz, Werner Horlitz, Peter M. Lange, Alfred Mitschker
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Patent number: 5012031Abstract: Tert.-olefins are obtained in high purity by cleavage of their alkyl ethers, when the catalysts used for this purpose are styrene/divinylbenzene resins which contain sulphonic acid groups and have a macroporous structure and the polymer matrix of which has an internal surface area of at least 400 m.sup.2 /g, a pore volume (porosity) of 0.6-2.5 ml/g and a mean pore diameter of 40-1000 .ANG.. These catalysts show long service lives.Type: GrantFiled: March 7, 1989Date of Patent: April 30, 1991Assignees: EC Erdoelchemie GmbH, Bayer AktiengesellschaftInventors: Bernhard Schleppinghoff, Hans-Ludwig Niederberger, Christian Gabel, Peter M. Lange, Alfred Mitschker
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Patent number: 4988738Abstract: A process for the preparation of a bifunctional anion exchange resin by partial quaternization of a weakly basic anion exchanger containing tertiary amino groups which process comprises (a) partially loading the weakly basic anion exchanger with a strong acid and (b) quaternizing the partially loaded anion exchanger by means of a customary alkylating agent.Type: GrantFiled: June 30, 1989Date of Patent: January 29, 1991Assignee: Bayer AktiengesellschaftInventors: Alfred Mitschker, Peter M. Lange, Harold Heller, Friedrich Werner, Hans-Karl Soest, Gunter Siegers
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Patent number: 4952608Abstract: The invention relates to a process for preparing anion exchangers based on crosslinked, water-insoluble organic polymers containing aromatic nuclei, in which, in the first step, N-hydroxymethylphthalimide is produced by reaction of phthalimide with aqueous formaldehyde solution in swelling agents in the presence of bases; if desired, this N-hydroxymethylphthalimide is converted in a 2nd step to the bis)phthalimidomethyl)ether or an ester of N-hydroxymethylphthalimide; said polymers are aminomethylated wtih N-hydroxy-methylphthalimide, bis)phthalimidomethyl) ether or an ester of N-hydroxymethylphthalimide in the presence of Friedel-Craft catalysts and swelling agents and the amidomethylated polymers are finally saponified to form the aminomethylated polymers, wherein, in the first reaction step, the base used for producing N-hy-droxymethylphthalimide is sodium hydroxide solution and this sodium hydroxide solution is added in such an amount and at such a rate that the reaction of phthalimide with formaldehyde tType: GrantFiled: September 14, 1988Date of Patent: August 28, 1990Assignee: Bayer AktiengesellschaftInventors: Reinhold M. Klipper, Peter M. Lange
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Patent number: 4943420Abstract: In the process for recovering gallium from aqueous, alkaline solutions by adsorption of the gallium on to bead-polymerized synthetic resins impregnated with 8-hydroxyquinolines and elution thereof with aqueous acids, the synthetic resins employed according to the invention are macroporous polydivinylbenzene or macroporous divinylbenzene copolymers which have been obtained by bead polymerization of divinylbenzene or mixtures of aromatic mono-, di- and/or trivinylbenzenes containing at least 50% by weight of divinylbenzene, in the presence of methyl isobutyl ketone, and which have been loaded with 160-190 g of Kelex 100 per liter of resin; in addition the resin is washed with sodium hydroxide solution after the elution step and before the commencement of each individual service cycle.Type: GrantFiled: April 13, 1989Date of Patent: July 24, 1990Assignees: Bayer Aktiengesellschaft, Ingal International Gallium GmbHInventors: Alfred Mitschker, Peter M. Lange, Heiko Hoffmann, Gunter Lossmann, Andries P. van der Meer, Cornelius J. Smit
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Patent number: 4772635Abstract: The invention relates to new bead-shaped crosslinked macroporous copolymers containing epoxide groups and basic amino groups, which are obtainable by reacting polymerizable glycidyl compounds, before or during free radical bead polymerization, which is carried out in the presence of agents which impart porosity and, if appropriate, with the addition of polyvinyl compounds which can be polymerized by free radical polymerization, with amines which are capable of reacting with at least two epoxide groups, a process for their preparation and their use, for example, for binding biologically active substances, for the preparation of strongly basic anion exchangers and hydrophilic chromatography resins for biomaterials.Type: GrantFiled: November 25, 1986Date of Patent: September 20, 1988Assignee: Bayer AktiengesellschaftInventors: Alfred Mitschker, Peter M. Lange, Wolfgang Kreiss
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Patent number: 4767850Abstract: In the purification of acarbose by contacting an acarbose-containing solution with a cation exchanger to adsorb the acarbose, eluting the ion exchanger and collecting an eluate fraction enriched in purified acarbose, the improvement wherein the cation exchanger is a polymer obtained by polymerizing an aromatic compound possessing at least one vinyl group and at least one hydrophilic monomer in the presence of a solvent for the monomer which is a precipitant for the crosslinked polymer formed, isolating the resistant polymer, and sulphonating the polymer in the presence of a swelling agent for the polymer. The invention gives sharp separation and other processing advantages.Type: GrantFiled: May 29, 1986Date of Patent: August 30, 1988Assignee: Bayer AktiengesellschaftInventors: Peter M. Lange, Erich Rauenbusch
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Patent number: 4754020Abstract: A new method of diazotization consists in using as the diazotizing agent in an aqueous, aqueous organic or organic medium the system comprising salt of nitrous acid+acid insoluble in the reaction medium, in particular organic or inorganic cation exchangers having acid groups. The diazonium salt solutions thus prepared are immediately reacted with coupling components to give azo dyestuffs, the insoluble acid and/or its salt being separated off before or after the coupling.Type: GrantFiled: March 7, 1986Date of Patent: June 28, 1988Assignee: Bayer AktiengesellschaftInventors: Joachim Wolff, Karlheinz Wolf, Reinhold M. Klipper, Peter M. Lange
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Patent number: 4745216Abstract: Polyisocyanates are produced by reacting a polyamide solution with a phosgene solution. After the product polyisocyanate has been recovered, the solvent or a portion of the solvent employed is treated with crosslinked polymers insoluble in the solvent which polymers contain primary and/or secondary alcoholic hydroxyl groups and/or primary and/or secondary amino groups. After treatment, the polymer and any reaction products are removed. The solvent may then be reused. Preferred solvents are chlorobenzene and o-dichlorobenzene. The preferred polymers are bead polymers or bead copolymers of (meth)acrylic acid or styrene/divinyl benzene copolymer.Type: GrantFiled: March 25, 1985Date of Patent: May 17, 1988Assignee: Bayer AktiengesellschaftInventors: Berthold Keggenhoff, Gunther Ellendt, Marcel Petinaux, Alfred Mitschker, Peter M. Lange
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Patent number: 4705637Abstract: The invention relate to a process for reducing the wash water required by weakly basic anion exchangers containing primary and/or secondary amino groups when fed with water containing carbon dioxide; in accordance with the process the exhausted, weakly basic anion exchangers are treated with dilute aqueous mineral acids before being regenerated.Type: GrantFiled: May 31, 1985Date of Patent: November 10, 1987Assignee: Bayer AktiengesellschaftInventors: Harold Heller, Peter M. Lange, Friedrich Martinola
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Patent number: 4702744Abstract: Stable, concentrated aqueous solutions of, in particular, anionic reactive dyestuffs are obtained in a comparatively simple manner by freeing from salts, preferably by means of membrane separation processes, solutions of these substances just as they are obtained in the course of synthesis, and by replacing, with the aid of ion exchangers, the cations which cause sparing solubility.Type: GrantFiled: May 27, 1986Date of Patent: October 27, 1987Assignee: Bayer AktiengesellschaftInventors: Joachim Wolff, Jochen Koll, Karlheinz Wolf, Reinhold M. Klipper, Peter M. Lange
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Patent number: 4695556Abstract: The invention relates to a new process for the preparation of strongly acid cation exchangers loaded with catalytically active metals by loading the cation exchangers with a solution of a salt of the catalytically active metal and reducing the cation exchangers loaded with metal ions, according to which the loading of the cation exchangers is carried out at temperatures from 50.degree. to 120.degree. C. and formic acid is used as the reducing agent; the invention also relates to the catalyst resins which can be obtained by the process.Type: GrantFiled: September 22, 1986Date of Patent: September 22, 1987Assignee: Bayer AktiengesellschaftInventors: Siegfried Oeckl, Alfred Mitschker, Peter M. Lange, Friedrich Martinola
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Patent number: 4666776Abstract: In the purification of acarbose by contacting an acarbose-containing solution with a cation exchanger to adsorb the acarbose, eluting the ion exchanger and collecting an eluate fraction enriched in purified acarbose, the improvement wherein the cation exchanger is a polymer obtained by polymerizing an aromatic compound possessing at least one vinyl group and at least one hydrophilic monomer in the presence of a solvent for the monomer which is a precipitant for the crosslinked polymer formed, isolating the resistant polymer, and sulphonating the polymer in the presence of a swelling agent for the polymer. The invention gives shapr separation and other processing advantages.Type: GrantFiled: October 10, 1985Date of Patent: May 19, 1987Assignee: Bayer AktiengesellschaftInventors: Peter M. Lange, Erich Rauenbusch
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Patent number: 4587347Abstract: Substituted ethyleneureas are prepared by reacting appropriate .beta.-hydroxyethylureas with alkyl carbonates in the presence of catalysts at an elevated temperature.Substituted ethyleneureas are used, inter alia, as polymerization and copolymerization components for the preparation of plastics, coatings, surface finishes and ion exchangers.Type: GrantFiled: July 6, 1984Date of Patent: May 6, 1986Assignee: Bayer AktiengesellschaftInventors: Hans-Josef Buysch, Reinhold Klipper, Peter M. Lange, Peter Mues
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Patent number: 4563371Abstract: The metallization of porous solid bodies, such as, for example, ion exchange materials, by loading the surfaces of the metal-free substrates with transition metal ions and subsequently treating them with reducing agents can be improved by activating the substrates, before or after the loading with metal ions, with elements of group 1 or 8 of the periodic table or compounds thereof and sensitizing any activating ions still present. The metallization products are useful hydrogenation catalysts.Type: GrantFiled: December 23, 1983Date of Patent: January 7, 1986Assignee: Bayer AktiengesellschaftInventors: Kirkor Sirinyan, Peter M. Lange, Rudolf Merten, Alfred Mitschker
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Patent number: 4552954Abstract: A process for concentrating nikkomicins (X) and (Z) from a dilute impure aqueous solution thereof, comprising contacting the solution with a weakly basic ion exchanger and eluting the adsorbed material with an acid thereby to obtain a concentrated mixture of nikkomicin (X) and nikkomicin (Z). The dilute solution being treated can directly be a filtered microbial cultivation liquor or such a liquor can be prepurified by contact with an acid ion exchanger followed by elution with a base. The recovered material is of relatively high purity.Type: GrantFiled: May 26, 1983Date of Patent: November 12, 1985Assignee: Bayer AktiengesellschaftInventors: Heinrich-Ferdinand Moeschler, Christian Golker, Peter M. Lange
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Patent number: 4511722Abstract: Cyclic N-vinylacylamines are prepared by heating carbonic acid esters of cyclic N-2-hydroxyethylacylamines in the presence of a catalytic amount of alkali or alkaline earth metal compound having an alkaline reaction and subsequently distilling the reaction mixture.Cyclic N-vinylacylamines are valuable precursors for preparing plant protection agents and medicaments and serve as polymerization and copolymerization components for preparing plastics, surface coatings, paints and ion exchange materials.Type: GrantFiled: February 16, 1983Date of Patent: April 16, 1985Assignee: Bayer AktiengesellschaftInventors: Heinrich Krimm, Hans-Josef Buysch, Peter M. Lange, Reinhold Klipper
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Patent number: 4504688Abstract: A process for the preparation of pure alkyl tertiary alkyl ethers and hydrocarbon raffinates which are substantially free from tertiary olefins and alkanols. An alkanol and a hydrocarbon mixture containing at least one tertiary olefin are contacted with the alkanol being present in a stoichiometric excess. The reaction product is removed from the reaction zone and excess alkanol in the reaction product or a partial stream thereof is absorbed on a synthetic ion exchanger containing groups which exchange cations or anions or mixtures of such ion exchangers. After absorption of at least a portion of the alkanol on the synthetic ion exchanger, the alkanol is desorbed by contacting the same with a hydrocarbon mixture containing at least one tertiary olefin.Type: GrantFiled: March 7, 1984Date of Patent: March 12, 1985Assignees: EC Erdolchemie GmbH, Bayer AktiengesellschaftInventors: Jens Herwig, Hans-Volker Scheef, Bernhard Schleppinghoff, Peter M. Lange
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Patent number: 4427794Abstract: Process for the production of bead polymers of improved uniform particle size and uniform quality comprising (a) producing droplets which have a uniform particle size from the monomer or polymerization mixture to be polymerized by spraying the monomer or polymerization mixture into a liquid (continuous phase) which is essentially immiscible with the monomer or polymerization mixture, (b) encapsulating these droplets of uniform size are by shells which are stable under the polymerization conditions to be used and (c) then polymerizing the encapsulated droplets, and with the provision to maintain in the process steps of droplet production and encapsulation of the droplets certain special conditions.Type: GrantFiled: August 7, 1981Date of Patent: January 24, 1984Assignee: Bayer AktiengesellschaftInventors: Peter M. Lange, Werner Struver