Abstract: The present invention relates to cationically curable compositions for curing on a surface comprising a cationically curable component, and an initiator component capable of initiating cure of the cationically curable component. The initiator comprises at least one metal salt, which is chosen so that it is reduced at the surface, and where the standard reduction potential of the initiator component is greater than the standard reduction potential of the surface, and where when the composition is placed in contact with the surface, the metal salt of the initiator component of the composition is reduced at the surface, thereby initiating cure of the cationically curable component of the composition. No catalytic component is required in the composition for efficient cure.

Abstract: The present invention relates to novel adducts useful for improving the toughness and curable compositions using such toughening adducts. In a particular aspect, the present invention relates to novel toughening adducts and curable compositions having improved fracture toughness using those toughening adducts.

Abstract: The invention relates to a binding agent composition, in particular an adhesive, containing at least one epoxy compound or at least one amino compound comprising at least two amino groups, or at least one hydroxy compound comprising at least two OH groups, or at least one mercapto compound comprising at least two mercapto groups, or at least one isocyanate comprising at least two NCO groups and a compound with chelating properties. The invention also relates to a method for producing binding agent compounds of this type and to the use of the same.

Abstract: A method of adhesively bonding a first component to a second component, which comprises a peripheral zone with which the first component is adhesively bonded in overlapping manner is provided.

Abstract: This invention relates to compositions useful as adhesives and more particularly to the preparation of heat-cured epoxy-based adhesive compositions with improved impact resistance and good adhesion to oily metal substrates.

Abstract: The present invention relates to novel adducts useful for improving the toughness and curable compositions using such toughening adducts. In a particular aspect, the present invention relates to novel toughening adducts and thermosetting resin formulations having improved fracture toughness using those toughening adducts.

Abstract: A method of washing a soiled textile comprising cotton, the method comprising contacting the textile with a wash liquor, the wash liquor containing a soil-release effective amount of one or more soil release polymers obtained by polymerizing one or more polyisocyanates with one or more polymeric polyols having an average molar mass of above 1000 D and a 20° C. water solubility of above 300 g of polymer per liter, one or more polyols having an average molar mass of below 12,000 D and a 20° C. water solubility of below 100 g per liter, and optionally one or more further polyols.

Abstract: Blocked polyurethane prepolymers obtained by reacting at least one polyol, a first polyisocyanate comprising diphenylmethane diisocyanate, a second polyisocyanate having a viscosity at 25° C. of less than about 250 mPa·s, a phenol blocking agent, and an oxime blocking agent, wherein the weight ratio of second polyisocyanate:first polyisocyanate is not more than 0.65:1. The blocked polyurethane prepolymers are especially useful in formulating coating compositions additionally comprising at least one acrylic resin, at least one plasticizer, at least one filler, and optionally other ingredients and additives. A cured coating is obtained by applying a layer of the coating composition to a substrate surface and heating the coating composition layer.

Abstract: In the preparation of an improved adhesive composition, an epoxy-based prepolymer is obtained by the reaction of one or more epoxy resins with amino-terminated polyethers and/or carboxyl-terminated butadiene-nitrile rubbers. In one embodiment of the invention, both a solid epoxy resin and a liquid epoxy resin, each of which is a diglycidyl ether of a polyphenol such as bisphenol A, are used. The epoxy-based prepolymer is mixed with an acrylate-terminated urethane resin (preferably, one based on a polyol having a number average molecular weight of at least about 400) and a heat-activated latent curing agent to make an adhesive composition which can be pumpable at room temperature. Curable adhesives capable of expansion to about 100% with high impact resistance after curing may be obtained by inclusion of expanding agents such as expandable microspheres.

Abstract: Blocked polyurethane prepolymers obtained by reacting at least one polyol, a first polyisocyanate comprising diphenylmethane diisocyanate, a second polyisocyanate having a viscosity at 25° C. of less than about 250 mPa.s, a phenol blocking agent, and an oxime blocking agent, wherein the weight ratio of second polyisocyanate:first polyisocyanate is not more than 0.65:1. The blocked polyurethane prepolymers are especially useful in formulating coating compositions additionally comprising at least one acrylic resin, at least one plasticizer, at least one filler, and optionally other ingredients and additives. A cured coating is obtained by applying a layer of the coating composition to a substrate surface and heating the coating composition layer.

Abstract: Products prepared from polycarboxylic anhydrides and active hydrogen-functionalized elastomeric polymers, in particular polyoxyalkyleneamines, are suitable as builder components (prepolymers) for epoxy resin compositions. The reaction products are distinguished by having a plurality of carboxyl groups, but no imide groups, in each molecule. The reaction products may optionally be further reacted with epoxy resins and may optionally be formulated together with polymers having at least one glass transition temperature of ?30° C. or lower and epoxy-reactive groups and/or reaction products of said polymers with epoxy resins to provide resin systems useful in adhesives. Such adhesive formulations may additionally contain liquid and/or solid epoxy resins and/or hardeners and/or accelerators and/or fillers and/or and/or other impact-modifying components and/or rheology auxiliaries.

Abstract: The invention relates to a binding agent composition, in particular an adhesive, containing at least one epoxy compound or at least one amino compound comprising at least two amino groups, or at least one hydroxy compound comprising at least two OH groups, or at least one mercapto compound comprising at least two mercapto groups, or at least one isocyanate comprising at least two NCO groups and a compound with chelating properties. The invention also relates to a method for producing binding agent compounds of this type and to the use of the same.

Abstract: Condensation products prepared from cyclic carboxylic anhydrides of dicarboxylic acids, tricarboxylic anhydrides or tetracarboxylic anhydrides and difunctional polyamines, in particular polyoxyalkyleneamines, are suitable as a builder component for epoxy resin compositions. The reaction products based on tricarboxylic anhydrides or tetracarboxylic anhydrides are distinguished by having on average more than one imide group and carboxyl group per molecule. The compositions may optionally also contain condensation products obtained from tri- or poly-functional polyols and/or tri- or poly-functional amino-terminated polymers and cyclic carboxylic anhydrides, wherein the latter reaction products contain on average more than one carboxyl group per molecule. These compositions additionally contain conventional rubber-modified epoxy resins together with liquid and/or solid polyepoxy resins and conventional hardeners and accelerators and optionally fillers and rheology auxiliaries.

Abstract: Hot-curing structural adhesives with multiphase polymer morphology, wherein the binder matrix of the cured chemically reactive adhesive displays (a) a continuous phase containing a polymer P1 having a glass transition temperature of over 100° C.; (b) a heterodisperse phase consisting of individual continuous domains of a thermoplastic or elastomeric polymer P2 having a glass transition temperature of below ?30° C. and an average particle size of between 0.5 and 50 ?m, which itself contains separate phases of another thermoplastic or elastomeric polymer P3 having a glass transition temperature of below ?30° C.

Abstract: A method of washing a soiled textile comprising cotton, the method comprising contacting the textile with a wash liquor, the wash liquor containing a soil-release effective amount of one or more soil release polymers obtained by polymerizing one or more polyisocyanates with one or more polymeric polyols having an average molar mass of above 1000 D and a 20° C. water solubility of above 300 g of polymer per liter, one or more polyols having an average molar mass of below 12,000 D and a 20° C. water solubility of below 100 g per liter, and optionally one or more further polyols.

Abstract: In the preparation of an improved adhesive composition, an epoxy-based prepolymer is obtained by the reaction of one or more epoxy resins with amino-terminated polyethers and/or carboxyl-terminated butadiene-nitrile rubbers. In one embodiment of the invention, both a solid epoxy resin and a liquid epoxy resin, each of which is a diglycidyl ether of a polyphenol such as bisphenol A, are used. The epoxy-based prepolymer is mixed with an acrylate-terminated urethane resin (preferably, one based on a polyol having a number average molecular weight of at least about 400) and a heat-activated latent curing agent to make an adhesive composition which can be pumpable at room temperature. Curable adhesives capable of expansion to about 100% with high impact resistance after curing may be obtained by inclusion of expanding agents such as expandable microspheres.

Abstract: In the preparation of an improved adhesive composition, a first reaction product is prepared by the reaction at an elevated temperature of a) 30 to 50 wt-% of an epoxy resin, solid at room temperature, which was prepared from bisphenol A and/or bisphenol F and epichlorohydrin with an epoxide equivalent weight of 400 to 700, b) 10 to 25 wt-% of an epoxy resin, liquid at room temperature, prepared from bisphenol A and/or bisphenol F and epichlorohydrin with an epoxide equivalent weight of 150 to 220, c) 35 to 50 wt-% amino-terminated polyethylene and/or polypropylene glycols and d) a carboxyl-terminated butadiene-nitrile rubber. The first reaction product is mixed with an acrylate terminated urethane resin, glass microspheres, expandable hollow plastic microspheres and a latent curing agent to make an adhesive composition which is pumpable at room temperature and capable of expansion to about 100% with high impact resistance after curing.

Abstract: Condensation products prepared from cyclic carboxylic anhydrides of dicarboxylic acids, tricarboxylic anhydrides or tetracarboxylic anhydrides and difunctional polyamines, in particular polyoxyalkyleneamines, are suitable as a builder component for epoxy resin compositions. The reaction products based on tricarboxylic anhydrides or tetracarboxylic anhydrides are distinguished by having on average more than one imide group and carboxyl group per molecule. The compositions may optionally also contain condensation products obtained from tri- or poly-functional polyols and/or tri- or poly-functional amino-terminated polymers and cyclic carboxylic anhydrides, wherein the latter reaction products contain on average more than one carboxyl group per molecule. These compositions additionally contain conventional rubber-modified epoxy resins together with liquid and/or solid polyepoxy resins and conventional hardeners and accelerators and optionally fillers and rheology auxiliaries.