Abstract: An electrochemical device is provided having a functionalized carboranyl magnesium electrolyte. Specifically the disclosure relates to an electrochemical device having a magnesium anode, a cathode, a current collector made of non-noble metal, and a functionalized carboranyl magnesium electrolyte. The functionalized carboranyl electrolyte includes a carboranyl anion functionalized with at least one halide, or one alkyl, aryl, alkoxy, aryloxy groups, or their partially or completely fluorinated analogues. In contact with the electrolyte, the non-noble metal cathodic current collector has unusually high oxidative stability >3.0V vs. a magnesium reference. Processes for making the electrochemical device are additionally provided.

Abstract: Electrochemical devices and processes for forming them employ a functionalized carboranyl magnesium electrolyte. The functionalized carboranyl electrolyte includes a carboranyl anion functionalized with at least one halide, or one alkyl, aryl, alkoxy, and/or aryloxy groups, or their partially or completely fluorinated analogues. In contact with the electrolyte, a non-noble metal cathodic current collector has unusually high oxidative stability >3.0V vs. a magnesium reference.

Abstract: A method for forming a solvo-ionic liquid suitable for use as an electrolyte in an electrochemical cell is provided. The solvo-ionic liquid, a mixture including a multidentate ethereal solvent and magnesium borohydride, can be a liquid, a gel or a solid at room temperature and generally has high thermal stability including virtually no volatility at a typical cell operating temperature. An electrochemical cell having a solvo-ionic liquid as electrolyte is also disclosed. The electrochemical cell will typically be a rechargeable magnesium battery, having an anode suitable to accommodate magnesium oxidation during battery discharge.

Abstract: A method for forming a solvo-ionic liquid suitable for use as an electrolyte in an electrochemical cell is provided. The solvo-ionic liquid, a mixture including a multidentate ethereal solvent and magnesium borohydride, can be a liquid, a gel or a solid at room temperature and generally has high thermal stability including virtually no volatility at a typical cell operating temperature. An electrochemical cell having a solvo-ionic liquid as electrolyte is also disclosed. The electrochemical cell will typically be a rechargeable magnesium battery, having an anode suitable to accommodate magnesium oxidation during battery discharge.

Abstract: A method for production of a magnesium battery with low impedance is provided. A cell is constructed comprising an uncoated current collector anode, an electrolyte system comprising a non-aqueous solvent and a magnesium salt soluble in the non-aqueous solvent, and a cathode. The cell is charged to electrodeposit magnesium metal unto the uncoated current collector to obtain an anode having magnesium metal as the active material. Also provided are rechargeable magnesium batteries obtained by the method.

Abstract: An electrochemical device is provided having a carboranyl magnesium electrolyte. Specifically the disclosure relates to an electrochemical device having a magnesium anode, a cathode, and a current collector made of non-noble metal, and a carboranyl magnesium electrolyte. In contact with the electrolyte, the non-noble metal cathode current collector has unusually high oxidative stability>3.0V vs. a magnesium reference. Processes for making the electrochemical device are additionally provided.

Abstract: An electrochemical device is provided having a carboranyl magnesium electrolyte. Specifically the disclosure relates to an electrochemical device having a carboranyl magnesium electrolyte which is compatible with a magnesium anode and a cathode, and on non-noble metal still having oxidative stability >3.0V vs. a magnesium reference.

Abstract: A method for forming a solvo-ionic liquid suitable for use as an electrolyte in an electrochemical cell is provided. The solvo-ionic liquid, a mixture including a multidentate ethereal solvent and magnesium borohydride, can be a liquid, a gel or a solid at room temperature and generally has high thermal stability including virtually no volatility at a typical cell operating temperature. An electrochemical cell having a solvo-ionic liquid as electrolyte is also disclosed. The electrochemical cell will typically be a rechargeable magnesium battery, having an anode suitable to accommodate magnesium oxidation during battery discharge.

Abstract: Electrodes employing as active material magnesium nanoparticles synthesized by a novel route are provided. The nanoparticle synthesis is facile and reproducible, and provides magnesium nanoparticles of very small dimension and high purity for a wide range of metals. The electrodes utilizing these nanoparticles thus may have superior capability. Magnesium ion electrochemical cells employing said electrodes are also provided.

Abstract: Electrodes employing as active material magnesium nanoparticles synthesized by a novel route are provided. The nanoparticle synthesis is facile and reproducible, and provides magnesium nanoparticles of very small dimension and high purity for a wide range of metals. The electrodes utilizing these nanoparticles thus may have superior capability. Magnesium ion electrochemical cells employing said electrodes are also provided.

Abstract: A composition and its method of production are provided. The composition includes at least one zero-valent metal atom in complex with at least one hydride molecule. The method of production includes ball-milling an elemental metal in a high-surface area form, with a hydride. The composition can be useful as a reagent for the synthesis of zero-valent metallic nanoparticles.

Abstract: A composition and its method of production are provided. The composition includes at least one zero-valent metal atom in complex with at least one hydride molecule. The method of production includes ball-milling an elemental metal in a high-surface area form, with a hydride. The composition can be useful as a reagent for the synthesis of zero-valent metallic nanoparticles.

Abstract: A method for forming a solvo-ionic liquid suitable for use as an electrolyte in an electrochemical cell is provided. The solvo-ionic liquid, a mixture including a multidentate ethereal solvent and magnesium borohydride, can be a liquid, a gel or a solid at room temperature and generally has high thermal stability including virtually no volatility at a typical cell operating temperature. An electrochemical cell having a solvo-ionic liquid as electrolyte is also disclosed. The electrochemical cell will typically be a rechargeable magnesium battery, having an anode suitable to accommodate magnesium oxidation during battery discharge.

Abstract: An electrochemical device is provided having a carboranyl magnesium electrolyte. Specifically the disclosure relates to an electrochemical device having a carboranyl magnesium electrolyte which is compatible with a magnesium anode and a cathode, and on non-noble metal still having oxidative stability >3.0V vs. a magnesium reference.

Abstract: An electrochemical device is provided having a carboranyl magnesium electrolyte. Specifically the disclosure relates to an electrochemical device having a magnesium anode, a cathode, and a current collector made of non-noble metal, and a carboranyl magnesium electrolyte. In contact with the electrolyte, the non-noble metal cathode current collector has unusually high oxidative stability >3.0V vs. a magnesium reference. Processes for making the electrochemical device are additionally provided.