Patents by Inventor Randall H. Helland
Randall H. Helland has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7169831Abstract: The invention relates to a pavement marking composition comprising ceramic fibers. The ceramic fibers are preferably randomly dispersed within a polymeric material. The polymeric material preferably comprises a substantially non-crosslinked elastomer. The pavement marking composition is preferably formed into a sheet material such as a tape.Type: GrantFiled: February 18, 2002Date of Patent: January 30, 2007Assignee: 3M Innovative Properties CompanyInventors: Randall H. Helland, Eric E. Rice
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Publication number: 20030099512Abstract: The invention relates to a pavement marking composition comprising ceramic fibers. The ceramic fibers are preferably randomly dispersed within a polymeric material. The polymeric material preferably comprises a substantially non-crosslinked elastomer. The pavement marking composition is preferably formed into a sheet material such as a tape.Type: ApplicationFiled: February 18, 2002Publication date: May 29, 2003Applicant: 3M Innovative Properties CompanyInventors: Randall H. Helland, Eric E. Rice
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Publication number: 20030069358Abstract: The invention relates to thermoplastic pavement marking compositions comprising synthetic polymeric fibers.Type: ApplicationFiled: September 26, 2002Publication date: April 10, 2003Applicant: 3M Innovative Properties CompanyInventors: Randall H. Helland, Chin Yee Ng
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Patent number: 6329128Abstract: An infrared photosensitive element comprising: a support bearing an infrared radiation-sensitive silver halide material; and an antihalation layer comprising a basic antistatic agent, an acid having a pKa less than 4.2 in an amount equal to at least 1.0% mole equivalent of acid to 1 mole equivalent of amine in said antistatic agent, and sufficient antihalation dye to provide a transmission optical density at the wavelength of maximum absorbence of said dye of at least 0.2 after coating.Type: GrantFiled: May 1, 1995Date of Patent: December 11, 2001Assignee: Eastman Kodak CompanyInventors: Randall H. Helland, Charles W. Gomez, William D. Ramsden
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Patent number: 5395747Abstract: Certain poly(lactic acid) and poly(glycolic acid) polymers or copolymers, and certain carbonates, lactones, lactates, lactylates, lactides, glycolates, glycolylates, and glycolides have been found to stabilize thermal-dye-bleach constructions containing a dye in association with a thermally-generated-bleaching agent. Preferably, the thermally-generated-bleaching agent is a thermal-carbanion-generating agent such as a quaternary ammonium salt of a phenylsulfonylacetic acid or a thermal-nucleophile-generating agent such as an ammonium salt of a phenylsulfonylacetic acid. These materials have been found to be particularly effective when used in acutance and antihalation systems for photothermographic and photographic elements.Type: GrantFiled: December 20, 1993Date of Patent: March 7, 1995Assignee: Minnesota Mining & Manufacturing CompanyInventors: Randall H. Helland, William D. Ramsden, Roger A. Mader
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Patent number: 5384237Abstract: A thermal-dye-bleach construction comprising a dye in association with a thermal dye-bleaching agent of general formula I: ##STR1## wherein: each of R.sup.a and R.sup.b are individually selected from: hydrogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group, and a heterocyclic group, and preferably, both R.sup.a and R.sup.b represent hydrogen;p is one or two, and when p is one, Z is a monovalent group selected from: an akyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, and a heterocyclic group, and when p is two, Z is a divalent group selected from: an alkylene group, an arylene group, an alkenylene group, an alkynylene group, an aralkylene group, a cycloalkene group, and a heterocyclic group; and,M.sup.+ is a cation which will not react with a carbanion generated from the thermal-carbanion-generating agent in such manner as to render the carbanion ineffective as a bleaching agent for the dye.Type: GrantFiled: January 25, 1994Date of Patent: January 24, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dian E. Stevenson, Mark P. Kirk, Sylvia A. Farnum, William C. Frank, Randall H. Helland, Jonathan P., Kitchin, Roger A. Mader, Mark B. Mizen, Richard A. Newmark, William D. Ramsden, Kumars Sakizadeh, Terence D. Spawn, George V. Tiers
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Patent number: 5380635Abstract: Dihydroperimidine squarylium dyes have been found to be particularly effective when used in acutance and antihalation systems for photothermographic and photographic articles.Type: GrantFiled: February 28, 1994Date of Patent: January 10, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Charles W. Gomez, Lori S. Harring, Randall H. Helland, William D. Ramsden, Tran Van Thien
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Patent number: 5324627Abstract: A thermal-dye-bleach construction comprising a dye in association with a thermal dye-bleaching agent of general formula I: ##STR1## wherein: each of R.sup.a and R.sup.b are individually selected from: hydrogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group, and a heterocyclic group, and preferably, both R.sup.a and R.sup.b represent hydrogen;p is one or two, and when p is one, Z is a monovalent group selected from: an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, and a heterocyclic group, and when p is two, Z is a divalent group selected from: an alkylene group, an arylene group, an alkenylene group, an alkynylene group, an aralkylene group, a cycloalkene group, and a heterocyclic group; and,M.sup.+ is cation which will not react with acarbanion generated from the thermal-carbanion-generating agent in such manner as to render the carbanion ineffective as a bleaching agent for the dye.Type: GrantFiled: December 21, 1992Date of Patent: June 28, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dian E. Stevenson, Mark P. Kirk, Sylvia A. Farnum, William C. Frank, Randall H. Helland, Jonathan P. Kitchin, Roger A. Mader, Mark B. Mizen, Richard A. Newmark, William D. Ramsden, Kumars Sakizadeh, Terence D. Spawn, George V. Tiers
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Patent number: 5314795Abstract: A thermal-dye-bleach construction comprising a polymethine dye having a nucleus of general formula I: ##STR1## in association with a thermal-carbanion-generating agent having the general formula: ##STR2## wherein the substituents are as defined in the specification and claims.Type: GrantFiled: December 21, 1992Date of Patent: May 24, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Randall H. Helland, Sylvia A. Farnum, Mark P. Kirk, Jonathan P. Kitchin, Roger A. Mader, Mark B. Mizen, Richard A. Newmark, William D. Ramsden, Kumars Sakizadeh, Terence D. Spawn, Dian E. Stevenson, George V. Tiers
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Patent number: 5266452Abstract: A photographic element containing a thermal-dye-bleach construction includes a thermal nucleophile-generating agent in association with a polymethine dye having a nucleus of general formula (I): ##STR1##Type: GrantFiled: April 30, 1992Date of Patent: November 30, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Mark P. Kirk, Dian E. Stevenson, Randall H. Helland
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Patent number: 5258274Abstract: A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a styryl dye having a nucleus of general formula (I): ##STR1## representing the nucleus of a styryl dye in which R=methyl or ethyl groupY=alkoxy of 1 to 20 carbon atomsm=1 or 2,n=1, 2, or 3, andx.sup..crclbar. =an anionThe aromatic fused benzene portion of the indolenine ring may be further substituted with commonly acceptable dye substituents such as alkyl and substituted alkyl (of 1 to 10 carbon atoms) groups, alkoxy groups (preferably of 1 to 10 carbon atoms), fused aromatic rings (as to make the benzene ring a fused naphthalene ring), halogen (including fluoro), cyano, nitro, carboxamido, amido, etc. One or two substituents chosen variously from said group may also be present on the phenyl ring to which the alkoxy group is attached.Type: GrantFiled: May 22, 1992Date of Patent: November 2, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Randall H. Helland, George V. D. Tiers, Dian E. Stevenson
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Patent number: 5135842Abstract: A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a polymethine dye having a nucleus of general formula (I): ##STR1## in which: n is 0, 1, 2 or 3;R.sup.1 and R.sup.4 are independently selected from the group consisting of hydrogen atoms, optionally substituted alkyl groups of up to 30 carbon atoms, optionally substituted alkenyl groups of up to 30 carbon atoms and optionally substituted aryl groups of up to 14 carbon atoms; andR.sup.1 and R.sup.2 together and/or R.sup.3 and R.sup.4 together may represent the necessary atoms to complete a 5 or 6-membered optionally substituted heterocyclic ring; orone or more of R.sup.1 to R.sup.4 may represent the necessary atoms to complete an optionally substituted 5 or 6-membered heterocyclic ring fused to the phenyl ring on which the NR.sup.1 R.sup.2 or NR.sup.3 R.sup.4 group is attached;R.sup.5 and R.sup.Type: GrantFiled: May 29, 1990Date of Patent: August 4, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Jonathan P. Kitchin, Mark P. Kirk, Dian E. Stevenson, Randall H. Helland
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Patent number: 4752559Abstract: A photothermographic recording article comprises in sequence:(a) a substrate,(b) a prime coat/antihalation layer comprising a pigmented acrylic polymer binder system,(c) a photothermographic dispersion comprising a binder, a non-light sensitive silver source material, photographic silver halide in catalytic proximity to silver source material, and(d) optionally, a topcoat layer,said article further comprising a reducing agent for silver ion and at least one development accelerator in at least one of the layers of the substrate.Type: GrantFiled: March 24, 1987Date of Patent: June 21, 1988Inventors: Randall H. Helland, Gregory J. McCarney
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Patent number: 4681830Abstract: A flowable, dry powder of particles of a developing composition are provided. The compositions may be either heat- or pressure-fixable and utilize from about 0.4 to 10 parts by weight of fluorinated carbon per 100 parts by weight of a thermoplastic binder and a magnetically responsive material. The fluorinated carbon has a degree of fluorination in the range of 10% to 100% and an average diameter below about 2 microns. The developing powder compositions possess improved flow humidity resistance and provide dramatically improved copy quality.Type: GrantFiled: April 24, 1986Date of Patent: July 21, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Randall H. Helland, Craig A. Burton