Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.

Abstract: The present invention provides a process is presented for preparing a positive electrode active material for rechargeable lithium ion batteries. The process comprises a sintering step having a short sintering time. This improves the production throughput. More particularly, the process applies to positive electrode active material powders having a general formula Li(1+a)(NixMnyCozMec)(1?a)O2, wherein Me comprises at least one element of the group consisting of Al, Mg, Ti, Zr, W, Nb, B, and Sr, with ?0.1?a?0.1, 0.33?x?0.95, 0?y?0.35, 0<z?0.35, 0?c?0.05, and x+y+z+c=1. The sintering step is performed for a predefined sintering time ts, expressed in hours, and at a predefined temperature Ts, expressed in ° C., such that 0.3?ts?6.0, and 1140+50 Log10 (6/t)?580 x?Ts?1245+50 Log10(6/ts)?580 x.

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1-a((Niz(Ni0.5Mn0.5)yCox)1-kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.

Abstract: This invention relates to an industrial process of manufacturing hydroxide precursor for lithium transition metal oxide used in secondary lithium ion batteries. More particularly, this process utilizes highly concentrated nitrate salts and is designed to mitigate waste production.

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.

Abstract: This invention relates to a process for manufacturing lithium nickel cobalt oxide-based cathode compounds for lithium ion secondary batteries. As part of this process, nickel, cobalt, and optionally manganese-bearing precursor compounds are lithiated and sintered at a high temperature. When cooled down, a high cooling rate will benefit the throughput of the process and the economics. It has however been found that the cooling rate should not exceed 10° C./min in what has been determined to be a critical temperature domain, ranging from 700° C. to 550° C.

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni1/2 Mn1/2)yCox)1?k Ak)1+aO2, wherein x+y+z=1, 0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.03?a?0.35, wherein the precursor has a crystalline size L expressed in nm, with 15?L?36. Also a method is described for manufacturing a positive electrode material having a general formula Li1+a?M?1?a?O2, with M?=(Niz(Ni1/2 Mn1/2)yCOx)1?k Ak, wherein x+y+z=1.0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.01?a??0.10, by sintering the lithium deficient precursor powder mixed with either one of LiOH, LiOH.H2O, in an oxidizing atmosphere at a temperature between 800 and 1000° C., for a time between 6 and 36 hrs.

Abstract: This invention relates to an industrial process of manufacturing hydroxide precursor for lithium transition metal oxide used in secondary lithium ion batteries. More particularly, this process utilizes highly concentrated nitrate salts and is designed to mitigate waste production.

Abstract: A particulate precursor compound for manufacturing a lithium transition metal (M)-oxide powder for use as an active positive electrode material in lithium-ion batteries, wherein (M) is NixMnyCozAv, A being a dopant, wherein 0.33?x?0.60, 0.20?y?0.33, and 0.20?z?0.33, v?0.05, and x+y+z+v=1, the precursor comprising Ni, Mn and Co in a molar ratio x:y:z and having a specific surface area BET in m2/g and a sulfur content S expressed in wt %, wherein formula (I).

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni1/2 Mn1/2)yCox)1?k Ak)1+aO2, wherein x+y+z=1, 0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.03?a?0.35, wherein the precursor has a crystalline size L expressed in nm, with 15?L?36. Also a method is described for manufacturing a positive electrode material having a general formula Li1+a?M?1?a?O2, with M?=(Niz(Ni1/2 Mn1/2)yCOx)1?k Ak, wherein x+y+z=1. 0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.01?a??0.10, by sintering the lithium deficient precursor powder mixed with either one of LiOH, LiOH.H2O, in an oxidizing atmosphere at a temperature between 800 and 1000° C., for a time between 6 and 36 hrs.

Abstract: A particulate precursor compound for manufacturing a lithium transition metal (M)-oxide powder for use as an active positive electrode material in lithium-ion batteries, wherein (M) is NixMnyCozAv, A being a dopant, wherein 0.33?x?0.60, 0.20?y?0.33, and 0.20?z?0.33, v?0.05, and x+y+z+v=1, the precursor comprising Ni, Mn and Co in a molar ratio x:y:z and having a specific surface area BET in m2/g and a sulfur content S expressed in wt %, wherein formula (I).

Abstract: The invention provides a cathode active material for use in a rechargeable battery, comprising a coated lithium nickel oxide powder or a coated lithium nickel manganese oxide powder, the powder being composed of primary particles provided with a glassy lithium silicate surface coating. A method for preparing the cathode active material comprises the steps of: providing a lithium transition metal based oxide powder, providing an alkali mineral compound comprising a Li2?xSiO3?0.5x compound, wherein 0<x<2, mixing the lithium transition metal based oxide powder and the alkali mineral compound to form a powder-mineral compound mixture, and heat treating the mixture at a temperature T whereby lithium is extracted from the surface of the metal based oxide powder to react with the alkali mineral compound, and a glassy surface coating is formed comprising a Li2?x?SiO3?0.5x? compound, wherein x<x?<2.

Abstract: A carbonate precursor compound of a lithium manganese based oxide powder for a positive electrode of a rechargeable battery, the oxide having the general formula Li1+vM1?vO2, wherein ?0.03?v?0.25, wherein M is a composition comprising at least 50 mol % of manganese, and wherein the carbonate precursor compound has a secondary particle size D50 expressed in ?m, and a tap density TD expressed in g/cm3, with either 1?TD?(2.78*D50)/(D50+7.23) and the compound having a particle size distribution having a span S?1.8 with S=(D90?D10)/D50; or 1?TD?(2.78*D50)/(D50+7.50).

Abstract: The invention relates to cathode materials for Li-ion batteries having a size dependent compositions. The lithium metal oxide powder has a general formula LiaNixCoyMnzM?mO2±eAf, with 0.9<a<1.1, 0.2?x?0.9, 0<y?0.4, 0<z?0.7, 0?m?0.35, e<0.02, 0?f?0.05 and 0.9<(x+y+z+m+f)<1.1; M? consisting of either one or more elements from the group Al, Mg, Ti, Cr, V, Fe and Ga; A consisting of either one or more elements from the group F, C, Cl, S, Zr, Ba, Y, Ca, B, Sn, Sb, Na and Zn. The powder has a particle size distribution defining a D10 and a D90; wherein either x1?x2?0.005; or z2?z1?0.005; or both x1?x2?0.005 and z2?z1?0.005; x1 and z1 being the values of x and z of particles having a particle size D90; and x2 and z2 being the values of x and z of particles having a particle size D10.

Abstract: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a first inner and a second outer layer, the second outer layer comprising a fluorine-containing polymer, and the first inner layer consisting of a reaction product of the fluorine-containing polymer and the primary particle surface. An example of this reaction product is LiF, where the lithium originates from the primary particles surface. Also as an example, the fluorine-containing polymer is either one of PVDF, PVDF-HFP or PTFE.

Abstract: A carbonate precursor compound of a lithium manganese based oxide powder for a positive electrode of a rechargeable battery, the oxide having the general formula Li1+vM1?vO2, wherein ?0.03?v?0.25, wherein M is a composition comprising at least 50 mol % of manganese, and wherein the carbonate precursor compound has a secondary particle size D50 expressed in ?m, and a tap density TD expressed in g/cm3, with either ?TD?(2.78*D50)/(D50+7.23) and the compound having a particle size distribution having a span S?1.8 with S=(D90?D10)/D50; or 1?TD?(2.78*D50)/(D50+7.50).

Abstract: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a LiF layer, where this layer consists of a reaction product of a fluorine-containing polymer and the primary particle surface. The lithium of the LiF originates from the primary particles surface. Examples of the fluorine-containing polymer are either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCodMeO2, wherein M is either one of both of Mg and Ti, with e<0.02 and d+e=1; —Li1+aM?1?aO2±bM1kSm with ?0.03<a<0.06, b<0.02, M? being a transition metal compound, consisting of at least 95% of either one or more elements of the group Ni, Mn, Co and Ti; M1 consisting of either one or more elements of the group Ca, Sr, Y, La, Ce and Zr, with 0?k?0.1 in wt %; and 0<m<0.6, m being expressed in mol %; and —LiaNixCOyM?zO2±eAf, with 0.9<a?<1.1, 0.5?x?0.9, 0<y?0.4, 0<z?0.35, e<0.

Abstract: The invention relates to cathode materials for Li-ion batteries having a size dependent compositions. The lithium metal oxide powder has a general formula LiaNixCoyMnzM?mO2±eAf, with 0.9<a<1.1, 0.2?x?0.9, 0<y?0.4, 0<z?0.7, 0?m?0.35, e<0.02, 0?f?0.05 and 0.9<(x+y+z+m+f)<1.1; M? consisting of either one or more elements from the group Al, Mg, Ti, Cr, V, Fe and Ga; A consisting of either one or more elements from the group F, C, Cl, S, Zr, Ba, Y, Ca, B, Sn, Sb, Na and Zn. The powder has a particle size distribution defining a D10 and a D90; wherein either x1?x2?0.005; or z2?z1?0.005; or both x1?x2?0.005 and z2?z1?0.005; x1 and z1 being the values of x and z of particles having a particle size D90; and x2 and z2 being the values of x and z of particles having a particle size D10.

Abstract: The invention provides a cathode active material for use in a rechargeable battery, comprising a coated lithium nickel oxide powder or a coated lithium nickel manganese oxide powder, the powder being composed of primary particles provided with a glassy lithium silicate surface coating. A method for preparing the cathode active material comprises the steps of: providing a lithium transition metal based oxide powder, providing an alkali mineral compound comprising a Li2?xSiO3?0.5x compound, wherein 0<x<2, mixing the lithium transition metal based oxide powder and the alkali mineral compound to form a powder-mineral compound mixture, and heat treating the mixture at a temperature T whereby lithium is extracted from the surface of the metal based oxide powder to react with the alkali mineral compound, and a glassy surface coating is formed comprising a Li2?x?SiO3?0.5x? compound, wherein x<x?<2.