Abstract: Aqueous compositions contain hydrochloric acid at a concentration between 8 wt % and 28 wt % inclusive. The amino acid; hydrochloric acid mole ratio may be between 0.2 and 1.5. Sufficient water is present to dissolve the hydrochloric acid and the amino acid. Such compositions have utility as retarders for acid compositions employed in the stimulation of subterranean formations. Slowing the reaction between the acid and formation helps maximize formation permeability and productivity.

Abstract: A method of treating a subterranean formation, the method including placing a well treatment fluid comprised of at least an enzyme and a breaker additive in the subterranean formation. Initially, the pH of the well treatment fluid is about 11.5. The breaker additive reduces the pH of the well treatment fluid by at least 1.5 to increase the activity of enzyme and accelerate hydrolysis of a crosslinkable component.

Abstract: Aqueous compositions contain hydrochloric acid at a concentration between 8 wt % and 28 wt % inclusive. The amino acid; hydrochloric acid mole ratio may be between 0.2 and 1.5. Sufficient water is present to dissolve the hydrochloric acid and the amino acid. Such compositions have utility as retarders for acid compositions employed in the stimulation of subterranean formations. Slowing the reaction between the acid and formation helps maximize formation permeability and productivity.

Abstract: A composition for treating a subterranean formation is formed from water, a water-soluble polymer and a crosslinking system. The crosslinking system utilizes 1) primary crosslinking agent of at least one of a dialdehyde benzene source, a dioxane, and a trioxane, 2) a secondary low temperature organic crosslinking agent that generates aldehyde, and 3) a phenol source. The crosslinking system provides the composition a delayed gel time of about 2 to about 20 hours at temperatures of about 250° F. (121° C.) or higher. A method of treating a subterranean formation penetrated by a wellbore is also accomplished by forming a treatment fluid from the composition and introducing the treatment fluid into the formation through the wellbore.

Abstract: Apparatus, systems, and methods in which a fracturing fluid source is in fluid communication with a wellbore extending into a subterranean formation. A compressor has an input in fluid communication with a natural gas source, and has an output in fluid communication with the wellbore. The compressor is operable to compress natural gas received at the input for delivery at the output. A liquefied gas source is also in fluid communication with the wellbore.

Abstract: A method is given for fracturing a formation, in particular far-field in a tight formation, in which at least a portion of the proppant is crushable in situ at some point during pumping, during fracture closure, or at higher stresses experienced later during fracture closure. The closure stress or hydrostatic stress is estimated, then a proppant is selected that is at least partially crushable at that closure stress, and then the fracturing treatment is performed with at least a portion of the total proppant being the selected crushable proppant.

Abstract: A method for treating a subterranean formation penetrated by a wellbore, the method including the introduction of a well treatment fluid containing at least an encapsulated biocide. Once the encapsulated biocide is introduced and after a predetermined period of time, a biocide is released from an encapsulation material and treats the wellbore and the subterranean formation.

Abstract: A method of treating a subterranean formation penetrated by a wellbore is accomplished by introducing a fluid into the wellbore containing a combined fluid loss additive and breaker. The combined fluid loss additive and breaker is formed from particles of an organic peroxide provided on a substrate. The particles are sized to facilitate fluid loss control. A treatment operation is carried out wherein a treatment fluid viscosified with a polymer is introduced into the formation through the wellbore.

Abstract: A method of forming a wellbore fluid, the method including introducing a hydratable polymer and introducing a crosslinker comprised of at least a silica material, the crosslinker having a dimension of from about 5 nm to about 100 nm.

Abstract: A method of forming a wellbore fluid, the method including introducing a hydratable polymer and introducing a crosslinker comprised of at least a silica material, the crosslinker having a dimension of from about 5 nm to about 100 nm.

Abstract: Disclosed herein is a gel comprising, polyacrylamide crosslinked with a non-metallic crosslinker, the non-metallic crosslinker comprising a polyamine. A method of making the gel and a method of using the gel are also disclosed.

Abstract: Aqueous compositions contain hydrochloric acid at a concentration between 8 wt % and 28 wt % inclusive. The amino acid; hydrochloric acid mole ratio may be between 0.2 and 1.5. Sufficient water is present to dissolve the hydrochloric acid and the amino acid. Such compositions have utility as retarders for acid compositions employed in the stimulation of subterranean formations. Slowing the reaction between the acid and formation helps maximize formation permeability and productivity.

Abstract: Apparatus, systems, and methods in which a fracturing fluid source is in fluid communication with a wellbore extending into a subterranean formation. A compressor has an input in fluid communication with a natural gas source, and has an output in fluid communication with the wellbore. The compressor is operable to compress natural gas received at the input for delivery at the output. A liquefied gas source is also in fluid communication with the wellbore.

Abstract: Various methods for performing treatment operations at a wellsite having a subterranean formation with a reservoir therein are provided. The method involves introducing a treatment fluid comprised of at least a gas hydrate slurry to the subterranean formation.

Abstract: A method of treating a subterranean formation, the method including placing a well treatment fluid comprised of at least an enzyme and a breaker additive in the subterranean formation. Initially, the pH of the well treatment fluid is about 11.5. The breaker additive reduces the pH of the well treatment fluid by at least 1.5 to increase the activity of enzyme and accelerate hydrolysis of a crosslinkable component.

Abstract: Process fluids comprising more than 1 wt % polyacrylamide and a non-metallic crosslinker may be used to control lost circulation in subterranean wells. The process fluid is placed into a subterranean lost-circulation zone and allowed to crosslink, thereby forming a gel barrier that limits further flow of process fluid into the zone. The non-metallic crosslinker may preferably comprise one or more polylactams. A pH-adjusting agent may also be incorporated into the process fluid.

Abstract: A technique utilizes micro-tubing to facilitate performance of a well treatment in which the micro-tubing is deployed for cooperation with a larger tubing, such as a coiled tubing positioned in wellbore. The micro-tubing is used to deliver a separated chemical downhole to modify a property of a treatment fluid used in performing a desired well treatment operation at a desired treatment region along the wellbore. A variety of additional components may be combined with the micro-tubing to further facilitate the treatment application.

Abstract: Methods for reducing a viscosity of a viscosified fluid include reacting, such as by depolymerizing and/or decomposing, a polymeric material of the viscosified fluid with a breaking agent including one or more organic peroxide breakers having a structural feature selected from a cyclic peroxide segment and/or multiple linear peroxide moieties per molecule. The methods of treating the subterranean are provided that include reacting, such as by depolymerizing and/or decomposing, a polymeric material of a viscosified treatment fluid with one or more organic peroxide breakers having a structural feature selected from cyclic peroxide segment and/or multiple linear peroxide moieties per molecule to facilitate breaking of the viscosified treatment fluid after the fracturing or treatment is finished.

Abstract: A treatment fluid composition for treating a subterranean formation penetrated by a wellbore is formed from an aqueous fluid, a hydratable polymer and a water-soluble, non-symmetrical, inorganic peroxide breaking agent, which is capable of undergoing heterolytical cleavage. A method of treating a subterranean formation penetrated by a wellbore may also be performed by forming a treatment fluid from an aqueous hydrated polymer solution. This is combined with a water-soluble, non-symmetrical, heterolytically cleavable inorganic peroxide breaking agent. The treating fluid is introduced into the formation. An optional crosslinking agent capable of crosslinking the polymer may also be included.

Abstract: A method is given for fracturing a formation, in particular far-field in a tight formation, in which at least a portion of the proppant is crushable in situ at some point during pumping, during fracture closure, or at higher Fluid flow stresses experienced later during fracture closure. The closure stress or hydrostatic stress is estimated, then a proppant is selected that is at least partially crushable at that closure stress, and then the fracturing treatment is performed with at least a portion of the total proppant being the selected crushable proppant.