Patents by Inventor Richard L. Kao

Richard L. Kao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10240098
    Abstract: Modular, portable processes and apparatus for the production of tight gas (including shale gas) and tight oil (including shale oil) and for the conversion of tight oil into a plurality of marketable fuels are described which enable easy deployment and start-up and are specifically useful in remote areas. Furthermore, these modular processes and apparatus are configured to use co-produced tight gas as a source of processing energy. Another feature of the modular processes is to substantially reduce the use of fracking water and process water.
    Type: Grant
    Filed: August 19, 2016
    Date of Patent: March 26, 2019
    Assignee: ACID TECHNOLOGIES, LLC
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Edward H. Stribling, III, Kenneth J. Schmitt
  • Publication number: 20170051214
    Abstract: Modular, portable processes and apparatus for the production of tight gas (including shale gas) and tight oil (including shale oil) and for the conversion of tight oil into a plurality of marketable fuels are described which enable easy deployment and start-up and are specifically useful in remote areas. Furthermore, these modular processes and apparatus are configured to use co-produced tight gas as a source of processing energy. Another feature of the modular processes is to substantially reduce the use of fracking water and process water.
    Type: Application
    Filed: August 19, 2016
    Publication date: February 23, 2017
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Edward H. Stribling, III, Kenneth J. Schmitt
  • Publication number: 20140364654
    Abstract: Disclosed herein is a process for monetization of natural gas by producing fuel grade dimethyl ether (DME). The process includes three reactive stages with the first reactive stage being the conversion of natural gas into syngas, the second reactive stage being the conversion of syngas into crude methanol and the third reactive stage being the production of fuel grade dimethyl ether. The management and optimization of the water and steam circuits is important to maintain net overall system efficiency and mitigation of any liquid effluents.
    Type: Application
    Filed: June 10, 2013
    Publication date: December 11, 2014
    Applicant: Unitel Technologies, Inc.
    Inventors: SARABJIT S. RANDHAVA, Richard L. Kao, Todd L. Harvey, Bradley S. Novak, Jorge Romero Zabaleta
  • Patent number: 8791165
    Abstract: This invention discloses a method for making a dimethylether (DME) product from a synthesis gas (syngas) in the presence of a catalyst in a fluid pluralized bed reactor operating in the gas phase. The reactions generate a significant amount of heat and the heat management is balanced between supplying quench recycle syngas to the pluralized sections along the reactor and also by controlling the preheat temperature of the reactant streams. Gas phase fluidization of the catalyst is controlled so that the pluralized reactive zones are maintained in a backmix configuration.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: July 29, 2014
    Assignee: Unitel Technologies, Inc.
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Todd L. Harvey
  • Patent number: 8679439
    Abstract: This invention provides a process for making ammonia from biomass. The biomass may be first reacted with oxygen and steam to generate a biosyngas comprising hydrogen (H2) and carbon monoxide (CO) as the active components. The gasification step may be regulated to reduce the amount of methane in the biosyngas that may leave the gasifier.
    Type: Grant
    Filed: August 18, 2009
    Date of Patent: March 25, 2014
    Assignee: Syngest, Inc.
    Inventors: Sarabjit S. Randhava, Surjit S. Randhava, Todd Harvey, Richard L. Kao
  • Patent number: 8546454
    Abstract: Disclosed herein is a process for the production of fuel grade DME from carbonaceous fuels, including a pressurized multi-stage progressively expanding fluidized bed gasifier and an oxyblown autothermal reformer to produce a synthesis gas (syngas) with desirable hydrogen to carbon monoxide molar ratio, which then undergoes gas-phase DME one-step direct synthesis in a fluid pluralized bed reactor over an attrition resistant bifunctional catalyst. The crude DME thus obtained is purified in a two column distillation unit to produce a fuel grade DME having a purity greater than 99.98 mole %.
    Type: Grant
    Filed: July 26, 2011
    Date of Patent: October 1, 2013
    Assignee: Unitel Technologies, Inc.
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Todd L. Harvey
  • Publication number: 20130035406
    Abstract: This invention discloses a method for making a dimethylether (DME) product from a synthesis gas (syngas) in the presence of a catalyst in a fluid pluralized bed reactor operating in the gas phase. The reactions generate a significant amount of heat and the heat management is balanced between supplying quench recycle syngas to the pluralized sections along the reactor and also by controlling the preheat temperature of the reactant streams. Gas phase fluidization of the catalyst is controlled so that the pluralized reactive zones are maintained in a backmix configuration.
    Type: Application
    Filed: August 3, 2011
    Publication date: February 7, 2013
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Todd L. Harvey
  • Publication number: 20130030063
    Abstract: Disclosed herein is a process for the production of fuel grade DME from carbonaceous fuels, including a pressurized multi-stage progressively expanding fluidized bed gasifier and an oxyblown autothermal reformer to produce a synthesis gas (syngas) with desirable hydrogen to carbon monoxide molar ratio, which then undergoes gas-phase DME one-step direct synthesis in a fluid pluralized bed reactor over an attrition resistant bifunctional catalyst. The crude DME thus obtained is purified in a two column distillation unit to produce a fuel grade DME having a purity greater than 99.98 mole %.
    Type: Application
    Filed: July 26, 2011
    Publication date: January 31, 2013
    Inventors: SARABJIT S. RANDHAVA, Richard L. Kao, Todd L. Harvey
  • Patent number: 7819070
    Abstract: The present application discloses an apparatus for gasification of solid, liquid and gaseous organic feed materials having a fuel value into synthesis gas. The apparatus comprises: a gasification reactor vessel having a tapered interior with a minimum of four zones for introducing reaction gas mixtures, a central perforated diffuser pipe, a solid and liquid material inlet at the upper end of the uppermost zone, a solid and gas discharge outlet at the lower end of the bottom zone, wherein the reactor vessel defining a sequence of reaction zones from the material inlet to the material outlet including drying, pyrolysis, combustion and gasification zones, and confining downwardly moving the column of the feed materials within the zones, gas feed inlet pipes for introducing reaction gas into the zones, a synthesis gas discharge pipe below the zones, and a heat exchanger below the zones.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: October 26, 2010
    Assignee: JC Enviro Enterprises Corp.
    Inventors: Amirali G Rehmat, Richard L Kao, Jin Soo Chung
  • Publication number: 20100040527
    Abstract: This invention provides a process for making ammonia from biomass. The biomass may be first reacted with oxygen and steam to generate a biosyngas comprising hydrogen (H2) and carbon monoxide (CO) as the active components. The gasification step may be regulated to reduce the amount of methane in the biosyngas that may leave the gasifier.
    Type: Application
    Filed: August 18, 2009
    Publication date: February 18, 2010
    Inventors: Sarabjit S. Randhava, Surjit S. Randhava, Todd Harvey, Richard L. Kao
  • Publication number: 20100040510
    Abstract: The invention provides systems and methods for converting biomass into syngas using a pressurized multi-stage progressively expanding fluidized bed gasifier to eliminate or reduce the formation of methane, volatiles such as BTX, and tars. The gasifier may include a reactive stage that may receive a biomass feed through a feed line and oxygen through an oxygen feed line. The gasifier may also include a fluidized bed section that may be configured to receive the reaction products from the first stage, mix them and perform fluidized bed activity. A gasifier may also have a disengagement section that may be configured to separate fluidized media and particulate matter from syngas product. A gasification system may also include oxyblown catalytic autothermal reactor and a cryogenic air separation unit.
    Type: Application
    Filed: August 18, 2009
    Publication date: February 18, 2010
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Todd Harvey, Ajaib S. Randhava, Surjit S. Randhava
  • Publication number: 20080176298
    Abstract: A corn oil extraction process is disclosed. The process includes the recovery of corn oil and other co-products, including but not limited to steam, electric power and chemicals, from an ethanol production process and in particular, a process that involves dry corn milling methods. The process involves extraction of oil from milled corn and residues from the fermentation step, including thick stillage, distillers wet grain, distillers dry grain and distillers dry grains with solubles, by the application of an alkyl acetate, phase separation and recovery of the separated matter. A process of drying wet co-product using ethanol and carbon dioxide from the production facility is also disclosed.
    Type: Application
    Filed: November 13, 2007
    Publication date: July 24, 2008
    Inventors: Sarabjit S. Randhava, Richard L. Kao, Steven G. Calderone, Ajaib S. Randhava
  • Patent number: 6984372
    Abstract: This invention relates to a sulfur tolerant, dynamic, compact, lightweight fuel process and system that is capable of converting sulfur bearing carbonaceous fuels to hydrogen rich gases suitable for fuel cells or chemical processing applications. The process and system is based on the AHR and WGS reactions, followed by cleanup of byproduct sulfur-containing gases and carbon oxides that would otherwise poison the fuel cell electrocatalyst. Advantageously, this is accomplished via an ASMS and a methanator or an AWMR. The process and system preferably uses a special sulfur tolerant catalysts and hardware designs that enable the conversion in an energy efficient manner while maintaining desirable performance characteristics such as rapid start-stop and fast response to load change capabilities.
    Type: Grant
    Filed: September 6, 2002
    Date of Patent: January 10, 2006
    Assignees: Unitel Technologies, Inc., University of Kentucky Research Foundation
    Inventors: Surjit Randhava, W. S. Winston Ho, Richard L. Kao, Elias H. Camara
  • Publication number: 20040047799
    Abstract: This invention relates to a sulfur tolerant, dynamic, compact, lightweight fuel process and system that is capable of converting sulfur bearing carbonaceous fuels to hydrogen rich gases suitable for fuel cells or chemical processing applications. The process and system is based on the AHR and WGS reactions, followed by cleanup of byproduct sulfur-containing gases and carbon oxides that would otherwise poison the fuel cell electrocatalyst. Advantageously, this is accomplished via an ASMS and a methanator or an AWMR. The process and system preferably uses a special sulfur tolerant catalysts and hardware designs that enable the conversion in an energy efficient manner while maintaining desirable performance characteristics such as rapid start-stop and fast response to load change capabilities.
    Type: Application
    Filed: September 6, 2002
    Publication date: March 11, 2004
    Applicants: H2fuel, LLC, University of Kentucky Research Foundation
    Inventors: Surjit Randhava, W.S. Winston Ho, Richard L. Kao, Elias H. Camara
  • Publication number: 20030188475
    Abstract: A dynamic, compact, lightweight fuel processor that is capable of converting carbonaceous fuels to hydrogen rich gases suitable for all types of fuel cells or chemical processing applications. The fuel processor and process are based on the autothermal hydrodesulfurizing reforming reaction, followed by clean up of byproduct sulfur-containing gases and carbon monoxide that poison the fuel cell electrocatalyst. The fuel processor uses proprietary catalysts and hardware designs that enable the conversion in an energy efficient manner while maintaining desirable performance characteristics such as rapid start-stop and fast response to load change capabilities.
    Type: Application
    Filed: March 29, 2002
    Publication date: October 9, 2003
    Inventors: Shabbir Ahmed, Sheldon H. Lee, Steven G. Calderone, Richard L. Kao, Elias H. Camara, Steven A. Lottes, Michael Krumpelt, Todd L. Harvey
  • Publication number: 20020141402
    Abstract: An auto-looper for a telecommunications network. The auto-looper detects the existence of continuity in a network path between at least two nodes of the network by activating at least one switch connecting the at least two nodes upon receipt of at least one addressable code to produce a loop-up state or a loop-down state.
    Type: Application
    Filed: March 8, 2001
    Publication date: October 3, 2002
    Inventors: Li-tien Chang, Richard L. Kao
  • Patent number: 5855666
    Abstract: This invention relates to thermo-chemical remediation and decontamination of sediments and soils contaminated with organic contaminants as well as inorganic materials with subsequent beneficial reuse. Novel environmentally stable products of commercial value are produced when certain additives such as calcium and metal oxides are mixed with the contaminated materials. In the process, the mixture is heated to 1150.degree. C..about.1500.degree. C. to produce a molten reaction product with at least part of an excess amount of oxygen mixture or air is continuously bubbled through the melt in order to provide mixing and achieve high thermal destruction and removal efficiencies of the organic contaminants. The melt is then quickly quenched in moist air, steam, or water to avoid the transformation of the amorphous material into crystals. The inorganic contaminants such as chromium, nickel, zinc, etc. are incorporated and completely immobilized within the amorphous silicate network.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: January 5, 1999
    Assignee: Cement-Lock Group, L.L.C.
    Inventors: Richard L. Kao, Sarabjit S. Randhava, Surjit S. Randhava, Michael C. Mensinger, Amirali G. Rehmat, Anthony L. Lee
  • Patent number: 5803894
    Abstract: This invention relates to thermo-chemical remediation and decontamination of sediments and soils contaminated with organic contaminants as well as inorganic materials with subsequent beneficial reuse. Novel environmentally stable products of commercial value are produced when certain additives such as calcium and metal oxides are mixed with the contaminated materials. In the process, the mixture is heated to 1150.degree. C..about.1500.degree. C. to produce a molten reaction product with at least part of an excess amount of oxygen mixture or air is continuously bubbled through the melt in order to provide mixing and achieve high thermal destruction and removal efficiencies of the organic contaminants. The melt is then quickly quenched in moist air, steam, or water to avoid the transformation of the amorphous material into crystals. The inorganic contaminants such as chromium, nickel, zinc, etc. are incorporated and completely immobilized within the amorphous silicate network.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: September 8, 1998
    Assignee: Cement-Lock L.L.C.
    Inventors: Richard L. Kao, Sarabjit S. Randhava, Surjit S. Randhava, Michael C. Mensinger, Amirali G. Rehmat, Anthony L. Lee
  • Patent number: 5266281
    Abstract: An improved double tube reactor having a plurality of inner and outer tube assemblies each of the assemblies having a reaction annular volume between the inner tube and outer tube and a closed center plug within the inner tube forming an annular thermal exchange volume between the center plug and the inner tube to obtain desired temperature control of exothermic and endothermic catalytic chemical reactions. In one embodiment of the invention, the improved double tube reactor is used in a process for production of high purity methanol from process gas produced by steam reforming hydrocarbon feedstocks in a tube type reformer followed by removing substantially all CO.sub.2 and H.sub.2 O from the process gas, adjusting the H.sub.2 /CO molar ratio to about 2 when necessary, and feeding the adjusted process gas to a methanol synthesis reactor contacting a methanol forming catalyst not requiring CO.sub.2 activation at about 200.degree. to about 300.degree. C.
    Type: Grant
    Filed: October 22, 1991
    Date of Patent: November 30, 1993
    Assignee: Xytel Technologies Partnership
    Inventors: Richard L. Kao, Sarabjit S. Randhava, Surjit S. Randhava, Shaw-Yaw Kang
  • Patent number: 5079267
    Abstract: A process for production of methanol from process gas produced by steam reforming hydrocarbon feedstocks in a tube type reformer followed by removing substantially all CO.sub.2 and H.sub.2 O from the process gas, adjusting the H.sub.2 /CO molar ratio to about 2 when necessary, and feeding the adjusted process gas to a methanol synthesis reactor contacting a methanol forming catalyst not requiring CO.sub.2 activation at about 200.degree. to about 300.degree. C. to produce product gas comprising methanol, and recovering liquid methanol having purity greater than about 99.85% pure by cooling the product gas to a temperature below the boiling point of methanol and separating the liquid methanol from gaseous components of the product gas. In a preferred embodiment, process gas of H.sub.2 /CO molar ratio of about 2.0 to about 2.
    Type: Grant
    Filed: September 16, 1989
    Date of Patent: January 7, 1992
    Assignee: Xytel Technologies Partnership
    Inventors: Richard L. Kao, Sarabjit S. Randhava, Surjit S. Randhava