Patents by Inventor Richard M. Mullins

Richard M. Mullins has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8372291
    Abstract: The present invention is directed to a water treatment composition, comprising: 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 55 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. The present invention is also directed to a water treatment tablet, comprising 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 10 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. Methods of treating recreational water using the compositions are also disclosed.
    Type: Grant
    Filed: March 31, 2011
    Date of Patent: February 12, 2013
    Assignee: Arch Chemicals, Inc.
    Inventors: Richard M. Mullins, Michael J. Unhoch
  • Publication number: 20110233145
    Abstract: The present invention is directed to a water treatment composition, comprising: 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 55 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. The present invention is also directed to a water treatment tablet, comprising 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 10 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. Methods of treating recreational water using the compositions are also disclosed.
    Type: Application
    Filed: March 31, 2011
    Publication date: September 29, 2011
    Inventors: Richard M. Mullins, Michael J. Unhoch
  • Patent number: 7927510
    Abstract: The present invention is directed to a granular water treatment composition, comprising: 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 55 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. The present invention is also directed to a water treatment tablet, comprising 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 10 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: April 19, 2011
    Assignee: Arch Chemicals, Inc.
    Inventors: Richard M. Mullins, Michael J. Unhoch
  • Patent number: 7704467
    Abstract: A composition for the treatment of a liquid, particularly a body of water, such as a swimming pool, spa, or the like. The composition includes calcium hypochlorite, a water soluble zinc salt for controlling algae, and sodium aluminate as an agglomerating agent that may safely be combined with said calcium hypochlorite and said zinc salt. A floating chemical dispenser for containing and dispensing chemicals to treat a body of water. The dispenser includes an upper end float, a container adapted to contain chemicals, the container removably joined with the upper end float, and a free end float joined with the container. The free end float is configured so that a central axis of the container and upper end float is not substantially orthogonal to a surface of the water.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: April 27, 2010
    Assignee: Arch Chemicals, Inc.
    Inventors: Peter Kenneth Hodgetts, Richard M. Mullins
  • Publication number: 20090317486
    Abstract: A composition for the treatment of a liquid, particularly a body of water, such as a swimming pool, spa, or the like. The composition includes calcium hypochlorite, a water soluble zinc salt for controlling algae, and sodium aluminate as an agglomerating agent that may safely be combined with said calcium hypochlorite and said zinc salt. A floating chemical dispenser for containing and dispensing chemicals to treat a body of water. The dispenser includes an upper end float, a container adapted to contain chemicals, the container removably joined with the upper end float, and a free end float joined with the container. The free end float is configured so that a central axis of the container and upper end float is not substantially orthogonal to a surface of the water.
    Type: Application
    Filed: August 26, 2009
    Publication date: December 24, 2009
    Applicant: ARCH CHEMICALS, INC.
    Inventors: Peter Kenneth Hodgetts, Richard M. Mullins
  • Publication number: 20080258104
    Abstract: The present invention is directed to a granular water treatment composition, comprising: 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 55 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. The present invention is also directed to a water treatment tablet, comprising 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 10 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition.
    Type: Application
    Filed: April 20, 2007
    Publication date: October 23, 2008
    Inventors: Richard M. Mullins, Michael J. Unhoch
  • Patent number: 6638446
    Abstract: A non-Division 5.1 Oxidizer composition consisting essentially of a blend of hydrated calcium hypochlorite with magnesium sulfate heptahydrate, wherein the blend contains at least about 17% by weight of water based on the total weight of the blend.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: October 28, 2003
    Assignee: Arch Chemicals, Inc.
    Inventor: Richard M. Mullins
  • Patent number: 5928608
    Abstract: Swimming pool or drinking water is chlorinated by the use of an intermittent spray-type chlorinator assembly. The chlorinator assembly includes a chamber for holding a quantity of solid dry chlorinating chemical, typically in the form of briquettes or pellets.The water spray impacts, abrades, and dissolves the briquettes to a degree, and at a rate which is controlled by the velocity of the spray; the diameter of the support grid; the percentage of open space in, and the thickness of the support grid; and the cyclic timing of the spray. The chemical-water mixture falls into a chamber below the spray and is evacuated therefrom through discharge/check valve assembly to a return line that leads back to the source of the water being chlorinated. The spray duration times and the intervals therebetween can be selectively changed by an attendant.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: July 27, 1999
    Assignee: Arch Chemicals Inc.
    Inventors: Kenneth John Levesque, Richard M. Mullins, Rocco Telese, David W. Blanchette
  • Patent number: 5411727
    Abstract: A process for dissolving calcium carbonate solids in the presence of an aqueous chlorine-containing solution without the formation of chlorine gas comprising adding a sufficient amount of lactic acid to the solution dissolving said solids.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: May 2, 1995
    Assignee: Olin Corporation
    Inventors: Richard M. Mullins, Jeffrey J. Glen
  • Patent number: 5133381
    Abstract: An improved chemical feeder employing periodic partial immersion in a forced circulation system is provided having a soluble chemical hopper, and a dissolving chamber into which the soluble chemical chamber extends an adjustable distance and a discharge chamber in fluid flow communication with the dissolving chamber to selectively receive chemically treated water from the dissolving chamber and discharge it into a flow loop connected to the forced circulation system. A visual indicator ring is preferably present to show the height of the hopper. The adjustable hopper allows an expanded range of chemical feed rates for the feeder.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: July 28, 1992
    Assignee: Olin Corporation
    Inventors: Richard B. Wood, Christopher M. Zetena, Richard M. Mullins, Carl V. Schatz
  • Patent number: 5112521
    Abstract: A solid calcium hypochlorite composition contains calcium hypochlorite and an alkali metal salt of phosphonobutane polycarboxylic acid having an available chlorine concentration of at least 50 percent by weight.It has been found that the use of the novel compositions of the present invention can significantly reduce scale formation in dispensers for calcium hypochlorite particularly where water having high total alkalinity is used. The prevention or inhibition of scale formation is accomplished without harmfully affecting other properties of the pool water such as the pH.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: May 12, 1992
    Assignee: Olin Corporation
    Inventors: Richard M. Mullins, Richard B. Wood, John A. Wojtowicz
  • Patent number: 5004549
    Abstract: A solid calcium hypochlorite composition contains hydrated calcium hypochlorite and an alkali metal salt of phosphonobutane polycarboxylic acid having an available chlorine concentration of at least 50 percent by weight and a water content of at least 4 percent by weight.It has been found that the use of the novel compositions of the present invention can significantly reduce scale formation in dispensers for calcium hypochlorite particularly where water having high total alkalinity is used. The prevention or inhibition of scale formation is accomplished without harmfully affecting other properties of the pool water such as the pH.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 2, 1991
    Assignee: Olin Corporation
    Inventors: Richard B. Wood, Richard M. Mullins, John A. Wojtowicz
  • Patent number: 4827028
    Abstract: Described are anionic surfactants which are made by (1) reacting maleic acid, fumaric acid, itaconic acid or mixtures thereof with at least one selected epoxy-capped poly(oxyalkylated) alcohol in the presence of a peroxy-type free radical initiator to form a carboxylic acid group-containing addition product and (2) neutralizing said addition product with a sufficient amount of a neutralizing agent to convert at least a major proportion of said carboxylic acid groups to salt groups. These surfactants exhibit excellent surface activity as well as being highly soluble in caustic solutions.
    Type: Grant
    Filed: April 23, 1984
    Date of Patent: May 2, 1989
    Assignee: Olin Corporation
    Inventors: Michael Scardera, Richard M. Mullins
  • Patent number: 4569778
    Abstract: Disclosed is an improved water-based hydraulic fluid composition which comprises an aqueous composition having a viscosity of at least 5 centistokes at 40.degree. C. which contains up to about 95 percent by weight of water, at least 0.1 percent by weight of a carboxylic acid lubricity agent, and an effective amount of an anti-wear additive; wherein the improvement comprises:said anti-wear agent comprising the combination of:(a) mono-, di-, and trihydroxy-substituted aromatic non-carboxylic acid compounds; with(b) substituted aromatic compounds, wherein the substituents comprise mono-, di-, and trinitro groups.
    Type: Grant
    Filed: March 22, 1985
    Date of Patent: February 11, 1986
    Assignee: Olin Corporation
    Inventors: Philip A. Miller, Richard M. Mullins, Robert J. Bucko
  • Patent number: 4569777
    Abstract: Disclosed is an improved water-based hydraulic fluid composition which comprises an aqueous composition having a viscosity of at least 5 centistokes at 40.degree. C. which contains up to about 95 percent by weight of water, at least 0.1 percent by weight of a carboxylic acid lubricity agent, and an effective amount of at least one selected anti-wear additive; wherein the improvement comprises:said anti-wear agent comprising the combination of:(a) mono-, di-, or trihydroxy-substituted aromatic compound; with(b) an aromatic compound substituted with one to three electron-withdrawing substituents, wherein said electron-withdrawing substituents are selected from the group consisting of cyano, sulfo, and mixtures thereof.
    Type: Grant
    Filed: March 22, 1985
    Date of Patent: February 11, 1986
    Assignee: Olin Corporation
    Inventors: Philip R. Miller, Richard M. Mullins
  • Patent number: 4569776
    Abstract: Disclosed is an improved water-based hydraulic fluid composition which comprises an aqueous composition having a viscosity of at least 5 centistokes at 40.degree. C. which contains up to about 95 percent by weight of water, at least 0.1 percent by weight of a carboxylic acid lubricity agent, and an effective amount of at least one selected anti-wear additive; wherein the improvement comprises:said anti-wear agent comprising the combination of:(a) an aromatic compound containing one to three electron-releasing substituent components, wherein said electron-releasing substituents are selected from the group consisting of amino, alkyl-substituted amino having 1 to about 12 carbon atoms, amido groups of the formula --NHC(.dbd.
    Type: Grant
    Filed: March 22, 1985
    Date of Patent: February 11, 1986
    Assignee: Olin Corporation
    Inventors: Philip R. Miller, Richard M. Mullins