Abstract: Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Abstract: Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Abstract: A method for making proppant particles is provided. The method can include providing a slurry of ceramic raw material, the slurry containing a reactant including a polycarboxylic acid, and flowing the slurry through a nozzle in a gas while vibrating the slurry to form droplets. The method can also include receiving the droplets in a vessel containing a liquid having an upper surface in direct contact with the gas, the liquid containing a coagulation agent. The method can further include reacting the reactant with the coagulation agent to cause coagulation of the reactant in the droplets. The droplets can then be transferred from the liquid and dried to form green pellets. The method can include sintering the green pellets in a selected temperature range to form the proppant particles. In one or more exemplary embodiments, the reactant can be or include a PMA:PAA copolymer.

Abstract: Proppant compositions and methods for using same are disclosed herein. In particular, a proppant composition for use in hydraulic fracturing is disclosed herein. The proppant composition can contain a plurality of particulates and at least one particulate of the plurality of particulates containing a chemical treatment agent. The at least one particulate having a long term permeability measured in accordance with ISO 13503-5 at 7,500 psi of at least about 10 D. The at least one chemical treatment agent can separate from the at least one particulate when located inside a fracture of a subterranean formation after a period of time.

Abstract: Proppant compositions and methods for using same are disclosed herein. In particular, a proppant composition for use in hydraulic fracturing is disclosed herein. The proppant composition can contain a plurality of particulates and at least one particulate of the plurality of particulates containing a chemical treatment agent. The at least one particulate having a long term permeability measured in accordance with ISO 13503-5 at 7,500 psi of at least about 10 D. The at least one chemical treatment agent can separate from the at least one particulate when located inside a fracture of a subterranean formation after a period of time.

Abstract: Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Abstract: Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Abstract: A method for making proppant particles is provided. The method can include providing a slurry of ceramic raw material, the slurry containing a reactant including a polycarboxylic acid, and flowing the slurry through a nozzle in a gas while vibrating the slurry to form droplets. The method can also include receiving the droplets in a vessel containing a liquid having an upper surface in direct contact with the gas, the liquid containing a coagulation agent. The method can further include reacting the reactant with the coagulation agent to cause coagulation of the reactant in the droplets. The droplets can then be transferred from the liquid and dried to form green pellets. The method can include sintering the green pellets in a selected temperature range to form the proppant particles. In one or more exemplary embodiments, the reactant can be or include a PMA:PAA copolymer.

Abstract: Proppant compositions and methods for using same are disclosed herein. In particular, a proppant composition for use in hydraulic fracturing is disclosed herein. The proppant composition can contain a plurality of particulates and at least one particulate of the plurality of particulates containing a chemical treatment agent. The at least one particulate having a long term permeability measured in accordance with ISO 13503-5 at 7,500 psi of at least about 10 D. The at least one chemical treatment agent can separate from the at least one particulate when located inside a fracture of a subterranean formation after a period of time.

Abstract: Methods are provided for determining the location and height of a fracture in a subterranean formation using pulsed neutron capture (PNC) logging tools. The methods include obtaining a pre-fracture data set, hydraulically fracturing the formation with a slurry that includes a liquid and a proppant in which at least a portion of the proppant is tagged with a thermal neutron absorbing material, obtaining a post-fracture data set, comparing the pre-fracture data set and the post-fracture data set to determine the location of the proppant, and correlating the location of the proppant to a depth measurement of the borehole to determine the location and height of the propped fracture.

Abstract: Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Abstract: Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Abstract: Methods are provided for identifying the location and height of induced subterranean formation fractures and the presence of any associated frac-pack or gravel pack material in the vicinity of the borehole using pulsed neutron capture (PNC) logging tools. The proppant/sand used in the fracturing and packing processes is tagged with a thermal neutron absorbing material. When proppant is present, increases in detected PNC formation and/or borehole component cross-sections, combined with decreases in measured count rates, are used to determine the location of the formation fractures and the presence and percent fill of pack material in the borehole region. Changes in measured formation cross-sections relative to changes in other PNC parameters provide a relative indication of the proppant in fractures compared to that in the borehole region.

Abstract: A composition and method for hydraulically fracturing an oil or gas well to improve the production rates and ultimate recovery using a porous ceramic proppant infused with a chemical treatment agent is provided. The chemical treatment agent may be a tracer material that provides diagnostic information about the production performance of a hydraulic fracture stimulation by the use of distinguishable both water soluble and hydrocarbon soluble tracers. The tracer can be a biological marker, such as DNA. The porous ceramic proppant can be coated with a polymer which provides for controlled release of the chemical treatment agent into a fracture or well bore area over a period of time.

Abstract: Proppant placed in a subterranean fracture zone is detected with a spectral identification method in which capture gamma ray spectra are obtained during a logging run carried out with a logging tool having a neutron emitting source and at least one detector sensitive to thermal neutron capture gamma rays. Capture gamma rays from one or more high thermal neutron cross-section materials in the proppant are distinguished from capture gamma rays produced by thermal neutron capture reactions with other downhole formation and borehole constituents utilizing a spectral processing/deconvolution technique. The capture gammas rays from the high thermal neutron capture cross section material in the proppant are used to identify propped fracture zones either alone or in combination with other proppant identification methods which rely on measuring thermal neutron related count rates and/or thermal neutron capture cross-sections from neutron, compensated neutron, and/or pulsed neutron capture logging tools.

Abstract: Methods are provided for identifying the location and height of induced subterranean formation fractures and the presence of any associated frac-pack or gravel pack material in the vicinity of the borehole using pulsed neutron capture (PNC) logging tools. The proppant/sand used in the fracturing and packing processes is tagged with a thermal neutron absorbing material. When proppant is present, increases in detected PNC formation and/or borehole component cross-sections, combined with decreases in measured count rates, are used to determine the location of the formation fractures and the presence and percent fill of pack material in the borehole region. Changes in measured formation cross-sections relative to changes in other PNC parameters provide a relative indication of the proppant in fractures compared to that in the borehole region.

Abstract: Methods for determining the locations/heights of fractures in a subterranean formation use a post-fracture log obtained with a compensated neutron or pulsed neutron logging tool. Utilizing predetermined relationships between tool count rates and associated near/far count rate ratios, the methods detect the presence of proppant containing high thermal neutron capture cross-section material, substantially eliminating proppant determination uncertainty resulting from changes in formation hydrogen index. In an interval of a well with given borehole and formation conditions, and not containing proppant, a relationship is developed between detector count rate and near/far ratio. This relationship is used to compute count rate from the ratio in intervals of the well possibly containing proppant and which have similar formation and borehole conditions.

Abstract: Methods are provided for determining the locations and heights of fractures in a subterranean formation using a neutron-emitting logging tool. Utilizing predetermined relationships (1) between logging tool count rates and associated apparent formation hydrogen index values and (2) between logging tool count rate ratios and associated apparent formation hydrogen index values, the methods detect the presence and heights in the formation of proppant containing high thermal neutron capture cross section material in a manner substantially eliminating proppant determination uncertainty resulting from a prior change in formation hydrogen index values. A second, associated, method employing logging tool count rates and count rate ratios to determine the presence of proppant containing high thermal neutron capture cross section absorbers utilizes a crossplot of count rate versus ratio.

Abstract: Proppant placed in a subterranean fracture zone is detected with a spectral identification method in which capture gamma ray spectra are obtained during a logging run carried out with a logging tool having a neutron emitting source and at least one detector sensitive to thermal neutron capture gamma rays. Capture gamma rays from one or more high thermal neutron cross-section materials in the proppant are distinguished from capture gamma rays produced by thermal neutron capture reactions with other downhole formation and borehole constituents utilizing a spectral processing/deconvolution technique. The capture gammas rays from the high thermal neutron capture cross section material in the proppant are used to identify propped fracture zones either alone or in combination with other proppant identification methods which rely on measuring thermal neutron related count rates and/or thermal neutron capture cross-sections from neutron, compensated neutron, and/or pulsed neutron capture logging tools.

Abstract: A method for determining the location and height of a fracture in a subterranean formation using a neutron emitting logging tool. The method includes obtaining a pre-fracture data set, fracturing the formation with a slurry that includes a proppant doped with a high thermal neutron capture cross-section material, obtaining a post-fracture data set, comparing the pre-fracture data set and the post-fracture data set to determine the location of the proppant, and correlating the location of the proppant to a depth measurement of the borehole to determine the location and height of the fracture. Using a pulsed neutron capture tool, it is also possible to determine whether the proppant is located in the fracture, in the borehole adjacent to the fracture, or in both. The method may also include a plurality of post-fracture logging procedures used to determine various fracture and production characteristics in the formation.