Patents by Inventor Robert Piorr
Robert Piorr has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5104585Abstract: The invention relates to a detergent mixture containingA) at least one alkyl glycoside corresponding to general formula (I)RO(G).sub.x (I)in whichR is an aliphatic radical containing at least 8 carbon atoms, preferably a primary alcohol radical and, more preferably, a fatty alkyl or fatty alkenyl radical containing 8 to 22 and preferably 12 to 18 carbon atoms,G is a symbol which stands for a glycose unit, i.e.Type: GrantFiled: March 7, 1991Date of Patent: April 14, 1992Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Fabry, Brigitte Giesen, Karlheinz Hill, Martina Kihn-Botulinski, Robert Piorr
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Patent number: 4990288Abstract: In light colored surfactants produced by sulfonation of fatty acid alkyl esters with less than 2 moles of SO.sub.3 per mole of fatty acid alkyl ester and subsequent work-up of the crude sulfonate in aqueous medium to form salts, the content of .alpha.-sulfofatty acid disalts is regulated and reduced by transesterifying the sulfonation product before its treatment with an aqueous medium with at least about 0.5 mole equivalent of an alcohol, based on the SO.sub.3 which is not for .alpha.-sulfonation.Type: GrantFiled: June 18, 1987Date of Patent: February 5, 1991Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Piorr, Guenter Panthel, Karl H. Schmid, Dietmar Colignon, Hans J. Rommerskirchen, Wolfgang Schmidt, Horst Ritterbex
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Patent number: 4981617Abstract: The sulfonation of epoxidized ricinoleic acid glycerides with a dry stream of gaseous sulfur trioxide diluted with a carrier gas, followed by a reaction of the sulfonated reaction product with nucleophiles, leads to salt-free and anhydrous products showing surface-active properties.Type: GrantFiled: September 2, 1988Date of Patent: January 1, 1991Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Fabry, Robert Piorr, Frank Clasen, Horst Ritterbex, Hans Bornmann
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Patent number: 4973423Abstract: Short-chain polyethlene glycol ethers corresponding to the formula:R.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2wherein:R.sup.1 is a linear or branched C.sub.6 -C.sub.18 alkyl or alkenyl radical,R.sup.2 is a C.sub.4 -C.sub.8 alkyl radical, andN is an integer of from 2 to 6,are used as foam-inhibiting additives for low-foam cleaning compositions.Type: GrantFiled: August 17, 1988Date of Patent: November 27, 1990Assignee: Ecolab Inc.Inventors: Juergen Geke, Erich Boebers, Gilbert Schenker, Robert Piorr, Karl-Heinz Schmid
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Patent number: 4943393Abstract: Compounds of the formula ##STR1## wherein X and Y are different and are OH or SO.sub.3 M wherein M is selected from the group consisting of hydrogen, an alkali metal ion, an alkaline earth metal ion, NR.sub.4 wherein R is hydrogen, an alkyl or hydroxy alkyl radical having from 1 to 4 carbon atoms; a and c are integers having a value of from 0 to 18; b is an integer having a value of from 0 to 2 such that the sum of a+b+c is from 12 to 18; Z is an oxyethylene, oxypropylene, or oxybutylene group; n is an integer having a value of from 0 to 30 reduce the viscosity of highly concentrated, aqueous pastes of alkali metal salts of .alpha.-sulfonated fatty acid alkyl esters by as much as 90% of their original value.Type: GrantFiled: February 13, 1989Date of Patent: July 24, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Fabry, Robert Piorr
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Patent number: 4936551Abstract: Fatty acid polyoxyalkyl ester sulfonates obtained by reaction of C.sub.11 -C.sub.22 monounsaturated monocarboxylic acid polyoxyalkyl esters corresponding to the following general formulaC.sub.m H.sub.2m-1 --CO--(O--C.sub.n H.sub.2n).sub.x --OR (I)in whichR is a C.sub.1 -C.sub.22 alkyl radical or a C.sub.3 -C.sub.22 alkenyl radical,m has a value of 10, 15, 17, 19 or 21,n has a value of 2 or 3 andx has a value of 1 to 20,with sulfur trioxide and subsequent reaction of the sulfonated fatty acid polyoxyalkyl ester obtained with aqueous alkali metal salts. The sulfonates have high surface activity and favorable performance properties as surfactants.Type: GrantFiled: June 15, 1988Date of Patent: June 26, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ansgar Behler, Robert Piorr, Michael Schaefer
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Patent number: 4935159Abstract: Long-chain hydroxyalkyl ether amines corresponding to the general formulaR.sup.1 --CHOH--CH.sub.2 --(O--CH.sub.2 --CH.sub.2 --).sub.X NR.sup.2 R.sup.3are suitable as wetting agents for textile products of all kinds and are distinguished by particularly low-foaming behavior. In the formula, R.sup.1 is a linear C.sub.6 -C.sub.22 alkyl group, R.sup.2 and R.sup.3 independently of one another represent a linear or branched C.sub.1 -C.sub.6 alkyl radical, and x is a number of 3 to 20.Type: GrantFiled: October 31, 1988Date of Patent: June 19, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gilbert Schenker, Andreas Syldatk, Robert Piorr
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Patent number: 4931218Abstract: Sulfated hydroxyalkyl polyethylene glycol and hydroxyalkyl polypropylene glycol ethers corresponding to general formula (II) ##STR1## in which R.sup.1 is hydrogen or a linear C.sub.1 -C.sub.16 alkyl radical,R.sup.2 is a linear or branched, saturated C.sub.1 -C.sub.22 alkyl radical,R.sub.3 is hydrogen or a linear C.sub.1 -C.sub.16 alkyl radical,R.sup.4 is hydrogen or a methyl group,M represents hydrogen, ammonium, alkylammonium, alkanolammonium, in which the alkyl and alkanol radicals each contain from 1 to 4 carbon atoms, or a monovalent metal atom, andn is a number of 1 to 30,with the proviso that the total number of carbon atoms in R.sup.1 and R.sub.Type: GrantFiled: July 13, 1988Date of Patent: June 5, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gilbert Schenker, Robert Piorr, Sabine Luettge
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Patent number: 4929504Abstract: Salts of sulfonic acids of the type formed in the sulfonation of alkenyl alkyl polyglycol ethers corresponding to the following formulaR--O(--C.sub.n H.sub.2n O).sub.x --R.sup.1with sulfur trioxide, followed by hydrolysis, are used as antistatic agents for plastics. R is a straight chain C.sub.10 -C.sub.22 alkenyl group, R.sup.1 is a C.sub.1 -C.sub.12 alkyl group, n is an integer of from 2 or 4, and x is an integer of from 0 to 35. The products show a particularly long-lasting effect as external antistatic agents on polyamide fibers.Type: GrantFiled: February 3, 1989Date of Patent: May 29, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rudolf Veitenhansl, Wolfgang Froeschke, Robert Piorr
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Patent number: 4925587Abstract: Hydroxyalkyl polyethylene glycol and hydroxyalkyl polypropylene glycol ethers of the formula ##STR1## in which R.sup.1 is a linear C.sub.6 -C.sub.16 alkyl radical, R.sup.2 is a linear or branched, C.sub.1 -C.sub.22 alkyl or alkenyl radical, R.sup.3 is hydrogen or a methyl group, and n is a number of from 0 to 30, and to mixtures of several such compounds. Also, a process for the preparation of these hydroxy ethers, wherein epoxides are reacted with alcohol alkoxylates at an elevated temperature in the presence of a catalyst and in an inert gas atmosphere. The compounds or their mixtures are used as foam inhibiting additives in low-foam cleaning preparations.Type: GrantFiled: July 14, 1988Date of Patent: May 15, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gilbert Schenker, Robert Piorr, Sabine Luettge
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Use of hydroxyalkyl polyethylene glycol ethers as surfactants in rinse aids for dishwashing machines
Patent number: 4898621Abstract: The invention relates to the use of hydroxyalkyl polyethylene glycol ethers corresponding to the following general formula ##STR1## in which R.sup.1 is hydrogen or a linear C.sub.1 -C.sub.16 alkyl radical,R.sup.2 is a linear or branched C.sub.4 -C.sub.8 alkyl radical,R.sup.3 is hydrogen or a C.sub.1 -C.sub.16 alkyl radical andn is a number of 7 to 30with the proviso that the total number of carbon atoms in R.sup.1 and R.sup.3 is 6 to 16, and mixtures thereof in rinse aid compositions for dishwashing machines in addition to other additives typically used in rinse aids.Type: GrantFiled: July 15, 1988Date of Patent: February 6, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Pruehs, Gilbert Schenker, Theodor Altenschoepfer, Robert Piorr -
Patent number: 4865774Abstract: Aqueous solutions of surface-active hydroxysulfonates are obtained by reaction of unsaturated fatty alkenyl or fatty alkenyl polyalkoxyl esters, for example of oleyl acetate or oleyl polyethoxyl acetate, with sulfur trioxide, introduction of the reaction product into aqueous alkali metal, alkaline-earth or ammonium hydroxide and heating of the solutions until the ester and sultone groups present have been hydrolyzed.Type: GrantFiled: July 29, 1988Date of Patent: September 12, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Fabry, Robert Piorr, Astrid Schumacher
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Patent number: 4826998Abstract: Salts of sulfonic acids of the type formed in the sulfonation of alkenyl alkyl polyglycol ethers corresponding to the following formulaR--O (--C.sub.n H.sub.2n O).sub.x --R.sup.1with sulfur trioxide, followed by hydrolysis, are used as antistatic agents for plastics. R is a straight chain C.sub.10 -C.sub.22 alkenyl group, R.sub.1 is a C.sub.1 -C.sub.12 alkyl group, n is an integer of from 2 or 4, and x is an integer of from 0 to 35. The products show a particularly long-lasting effect as external antistatic agents on polyamide fibers.Type: GrantFiled: September 5, 1985Date of Patent: May 2, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rudolf Veitenhansl, Wolfgang Froeschke, Robert Piorr
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Patent number: 4820451Abstract: In the production of washing-active .alpha.-sulfofatty acid esters by sulfonation of fatty acid alkyl esters with SO.sub.3 in molar ratios of up to 1:2 and more especially of from 1:1.2 to 1:1.8 and subsequent working-up of the crude sulfonic acid in aqueous medium with salt formation, aqueous pastes which are mobile, more especially pumpable, at moderately elevated temperatures are obtained by subjecting the crude sulfonate before the treatment with the aqueous medium to a post-reaction with at least about 0.5 mole equivalent, based on the SO.sub.3 which is not used for the .alpha.-sulfonation, of monohydric alcohols and/or alkoxylation products thereof at temperatures above 70.degree. C. and adjusting the solids contents of the .alpha.-sulfofatty acid ester salts to more than 35% by weight in the subsequent aqueous working-up step.Type: GrantFiled: October 31, 1986Date of Patent: April 11, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Piorr, Hans-Josef Rommerskirchen, Horst Ritterbex, Frantisek Jost
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Patent number: 4792582Abstract: A method for emulsifying, emulsion-stabilizing, and/or foam-inhibiting an aqueous polymer dispersion or latex by incorporating therein a polyglycol ether; and a polymer dispersion or latex composition containing such polyglycol ether.Type: GrantFiled: August 11, 1986Date of Patent: December 20, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rainer Hoefer, Alfred Meffert, Robert Piorr, Bernd Wegemund, Uwe Held
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Patent number: 4792419Abstract: Ether sulfonates are produced by reacting a C.sub.10 -C.sub.20 fatty alkyl C.sub.1 -C.sub.6 lower alkyl ether or a fatty alkyl (polyoxyalkyl) lower alkyl ether corresponding to the following formulaR--O--(C.sub.n H.sub.2n O).sub.x --R.sup.1 (I) psin which R is an oleyl, palmitoleyl, or linoleyl radical, or mixtures thereof, n is an integer of from 2 to 4, x is an integer of from 0 to 30, and R.sup.1 is a saturated C.sub.1 -C.sub.6 lower alkyl radical, with sulfur trioxide, contacting the sulfonate with aqueous alkali metal hydroxide solution and heating the solution until the sultones formed have been hydrolyzed.Type: GrantFiled: August 24, 1984Date of Patent: December 20, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Piorr, Alfred Meffert
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Patent number: 4744923Abstract: Alkylaminopolyethylene glycol ethers corresponding to the following formula ##STR1## in which R represents a C.sub.6 -C.sub.20 alkyl or alkenyl radical, R.sup.1 and R.sup.2 are the same or different and represent a C.sub.1 -C.sub.8 alkyl radical and the indices m and n are the same or different and represent a number of from 3 to 20, with the proviso that the sum of m and n is from 5 to 25, are suitable as foam inhibitors for detergent preparations. The foam inhibitors are stable to strong alkalis and strong acids and may be used in concentrations of from 10 to 2500 ppm.Type: GrantFiled: April 30, 1987Date of Patent: May 17, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Piorr, Gilbert Schenker
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Patent number: 4735735Abstract: A method for corrosion inhibition in oil or oil emulsions comprising adding thereto a corrosion-inhibition-effective amount of at least one salt corresponding to the general formula ##STR1## in which R.sup.1 is a linear or branched C.sub.8-36 alkyl or C.sub.8-36 alkenyl or a mono- or polyethoxylated C.sub.8-18 alkyl containing from 1 to 10 ethoxy groups,R.sup.2 is a linear or branched C.sub.10-20 alkyl andM is half an equivalent of a divalent metal which is magnesium, calcium, barium, or zinc.Type: GrantFiled: May 22, 1987Date of Patent: April 5, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gerhard Borggrefe, Robert Piorr, Alfred Struve
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Patent number: 4719044Abstract: Hydroxyalkyl polyethylene glycol ethers corresponding to the formula ##STR1## in which X is R.sup.3 --CHOH--CHR.sup.4 --(OCH.sub.2 CH.sub.2).sub.n --, R.sup.1 is a linear or branched C.sub.1-6 alkyl, R.sup.2 =R.sup.1 or X, R.sup.3 is a straight-chain C.sub.6-18 alkyl, R.sup.4 is hydrogen or a C.sub.1-8 alkyl, and and n is an average number of from 3 to 20, with the proviso that the sum of the carbon atoms in R.sup.3 and R.sup.4 is from 6 to 18, are suitable for depressing foam in detergent preparations.Type: GrantFiled: April 30, 1987Date of Patent: January 12, 1988Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Piorr, Gilbert Schenker
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Patent number: 4695409Abstract: In light colored surfactants produced by sulfonation of fatty acid alkyl esters with less than 2 moles of SO.sub.3 per mole of fatty acid alkyl ester and subsequent work-up of the crude sulfonate in aqueous medium to form salts, the content of .alpha.-sulfofatty acid disalts is regulated and reduced by transesterifying the sulfonation product before its treatment with an aqueous medium with at least about 0.5 mole equivalent of an alcohol, based on the SO.sub.3 which is not for .alpha.-sulfonation.Type: GrantFiled: July 10, 1985Date of Patent: September 22, 1987Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Piorr, Guenter Panthel, Karl H. Schmid, Dietmar Colignon, Hans J. Rommerskirchen, Wolfgang Schmidt, Horst Ritterbex