Abstract: The reactor forms a chamber which contains the reaction process. There are accesses to the chamber for receiving shredded tires and oil. There are egresses from the chamber for discharging the tire oil and for discharging unreacted elements. Apparatus is located within the chamber which separates the unreacted components of the shredded tires from the tire oil. The apparatus also provides for the removal of the unreacted elements from the chamber means. The reactor also includes a heater which heats the inside of the chamber to a temperature sufficient to cause a reaction between the shredded tires and the oil.

Abstract: A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation.The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

Abstract: The locus of a processing zone advancing through a fragmented permeable mass of formation particles in an in situ oil shale retort in a subterranean formation containing oil shale and which generates an effluent fluid is determined by placing a halogen source in the permeable mass for providing an identifiable halogen and monitoring effluent fluid from the processing zone for presence of such halocarbon. The halogen source provides halogen at a predetermined temperature.

Abstract: An in situ oil shale retort is formed in a subterranean formation containing oil shale. The retort contains a fragmented permeable mass of formation particles containing oil shale. During retorting, oxygen-supplying gas is introduced into an upper level of the fragmented mass for establishing a combustion zone and for advancing the combustion zone downwardly through the fragmented mass. Liquid and gaseous products, including shale oil and off gas, are withdrawn from a generally U-shaped production level drift at a lower level of the fragmented mass. Liquid in a lower portion of the U seals against the roof of the drift to provide a gas seal which inhibits passage of off gas from a first leg of the drift in communication with the retort to a second leg of the drift remote from the retort. A retaining wall in the second leg of the drift can provide lateral support for the liquid forming the gas seal, and help minimize the depth of excavation of the U-shaped drift.

Abstract: An in situ oil shale retort is formed in a subterranean formation containing oil shale. The retort contains a fragmented permeable mass of formation particles containing oil shale. During retorting, oxygen-supplying gas is introduced into an upper level of the fragmented mass for establishing a combustion zone and for advancing the combustion zone through the fragmented mass. Liquid and gaseous products, including shale oil and off gas, are withdrawn from a sealed portion of a production level drift which extends laterally away from the lower level of the fragmented mass. A bulkhead sealed across the drift inhibits passage of off gas from behind the bulkhead to the portion of the drift on the side of the bulkhead opposite the fragmented mass. Off gas, shale oil and water are separately withdrawn from behind the bulkhead.

Abstract: An in situ oil shale retort in which a cavity filled with broken particles of oil shale is formed within the subsurface oil shale formation and air is forced down through the cavity to sustain combustion of the top layer of oil shale particles, the products of combustion being withdrawn at the bottom of the cavity. A plurality of exhaust pipes traverse the bottom of the cavity and extend out through the sealed entrance to the retort cavity. The pipes are supported above the floor of the cavity and have holes opening on the bottom side of the pipes through which the product gases are withdrawn from the cavity. Valves in each pipe control the flow so as to balance the flow distribution of air and exhaust gases through the retorting cavity.

Abstract: An in situ fragmented permeable mass of particles containing treated oil shale is formed by excavating a void in a subterranean formation containing oil shale, explosively expanding formation toward such a void to form a fragmented permeable mass of formation particles containing oil shale, and retorting the particles containing oil shale in the fragmented mass. Water containing impurities is introduced into such an in situ fragmented permeable mass of particles containing treated oil shale, i.e., retorted or combusted oil shale or both, for disposal, purification, or generation of steam. The water introduced can be water containing hydrocarbons such as process water from retorting oil shale or water containing suspended solids such as blowdown from a steam generator. When the fragmented permeable mass is still hot from retorting, steam is generated which can be withdrawn for use in oil shale recovery operations.

Abstract: An in situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale is formed in a subterranean formation. The void fraction of the fragmented mass is from about 10 to about 25 percent, and the weight average diameter of particles in the fragmented mass is from about 0.02 to about 0.3 foot. Combustion zone feed containing oxygen is introduced to a combustion zone established in the fragmented mass. The rate at which the combustion zone feed is introduced to the combustion zone is controlled for maintaining the modified Reynolds number of gas passing through the combustion zone in the range of from about 0.1 to about 20.

Abstract: The locus of a processing zone advancing through a fragmented permeable mass of particles in an in situ oil shale retort in a subterranean formation containing oil shale and which generates an effluent fluid is determined by placing an indicator source for providing an indicator, and monitoring effluent fluid from the processing zone for presence of indicator. The indicator source provides indicator at a predetermind temperature.

Abstract: Oil shale is pyrolyzed by introducing an oil shale feed to a retorting zone fluidized bed to yield, as products of retorting, retorted oil shale containing residual carbonaceous material and volatilized hydrocarbons. The retorted oil shale particles are passed to the top of a combustion zone fluidized bed into which a gaseous source of oxygen is introduced for fluidizing the combustion zone fluidized bed and oxidizing residual carbonaceous material contained in the retorted oil shale particles to yield combustion gases for fluidizing the retorting zone fluidized bed and for maintaining the retorting zone fluidized bed at a temperature sufficient to retort oil shale.

Abstract: A method for retorting oil shale in an in situ oil shale retort includes the steps of excavating a void in a subterranean formation containing oil shale and placing combustible material in the void adjacent an ignition situs. Formation is then explosively expanded toward the void to form a retort containing a fragmented permeable mass of formation particles containing oil shale, the top layer of the fragmented mass adjacent an ignition situs containing such combustible material. The combustible material is then ignited for establishing a combustion zone in the retort.

Abstract: An in situ oil shale retort is formed in a subterranean formation containing oil shale. The retort contains a fragmented permeable mass of particles containing oil shale. An open base of operation is excavated in the formation above the retort site, and an access drift is excavated to the bottom of the retort site. Formation is explosively expanded to form the fragmented mass between the access drift and an elevation spaced below the bottom of the base of operation, leaving a horizontal sill pillar of unfragmented formation between the top of the fragmented mass and the bottom of the base of operation. The sill pillar provides a safe base of operation above the fragmented mass after it is formed. The fragmented mass is formed by, among other steps, drilling blasting holes from the base of operation down through the sill pillar and detonating explosive in the holes to form the fragmented mass of particles in the retort below the sill pillar.

Abstract: The locus of a processing zone advancing through a fragmented permeable mass of particles in an in situ oil shale retort in a subterranean formation containing oil shale is determined by monitoring pressure in the retort. Monitoring can be effected by placing a pressure transducer in a well extending through the formation adjacent the retort and/or in the fragmented mass such as in a well extending into the fragmented mass.

Abstract: Values are recovered from a subterranean in situ oil shale retort containing a fragmented permeable mass of formation particles by passing a measuring gas through the retort to determine the presence of a blockage in the fragmented mass. If there is such a blockage, only a portion of the fragmented mass is processed and the portion of the fragmented mass having the blockage is left unprocessed. This is effected by introducing a processing gas to the retort at an intermediate location between opposing ends of the fragmented mass and withdrawing gaseous and liquid products of processing at an end of the fragmented mass remote from such blockage.

Abstract: A technique is described for breaking the very strong emulsion of shale oil and water produced by an in situ oil shale retorting process so that separate shale oil and water phases can be recovered. The emulsion is broken by heating it to a temperature of at least about 120.degree. F. and holding at a temperature in the range of from about 120.degree. to 180.degree. F. for about one day. Preferably the shale oil and water are held in the range of from about 130.degree. to 150.degree. F. for about one day and the phases separated by gravity. Heat for the process can be obtained by injecting water into a spent in situ oil shale retort for generating steam and transferring heat from the steam to the emulsion.

Abstract: In a process for retorting oil shale in an situ oil shale retort having a tunnel adjacent the retort, off gas is produced. Leakage of the off gas into the tunnel is prevented by withdrawing off gas from the retort at a rate sufficient to reduce the pressure in the retort adjacent the tunnel to a pressure below the ambient pressure within the tunnel.

Abstract: A method of processing oil shale in which an in situ oil shale retort comprising an elongated cavity containing a fragmented permeable mass of formation particles containing oil shale is formed in a subterranean formation containing oil shale to recover liquid and gaseous products. Access to the cavity is by a drift or conduit at each end of the cavity and through a drift at an intermediate position. A processing zone is established in the fragmented mass at one end of the cavity and processing gas is introduced at that end of the retort and heating of the fragmented mass of formation particles is conducted from that end towards the other end. Initially, off gas is withdrawn at the intermediate drift. When the processing zone passes the intermediate drift, processing gas is introduced through the intermediate drift and off gas including gaseous products is withdrawn by way of the drift at the other end.

Abstract: An in situ oil shale retort is ignited by directing a combustible inlet gas mixture into an ignition zone extending across the top of the in situ retort and igniting the combustible mixture to create a combustion zone in the in situ retort. The ignition zone has a sufficient volume of interconnected open spaces for the movement of inlet gas through the ignition zone with minimal pressure loss, and the in situ retort below the ignition zone has sufficient void volume that inlet gas can be introduced into the ignition zone and moved downwardly through the in situ retort to the bottom. After ignition of the combustible mixture, additional quantities of a combustible mixture are directed into the ignition zone to maintain the combustion zone. Flue gases generated in the combustion zone are moved from the combustion zone toward the bottom of the in situ oil shale retort to establish a retorting zone on the advancing side of the combustion zone.

Abstract: An underground room in substantially undisturbed shale is filled with fragmented oil shale particles for in situ retorting. A comprehensive system is provided for feeding air to the top of the retort and recovering oil and flue gas from the bottom of the retort. The oil is separated from admixed water and both are recovered. Flue gas is withdrawn from the bottom of the retort, scrubbed clean and a portion may be recycled through the retort while another portion is vented or burned in a turbine. Means are also provided for passing scrubbed gas through a second spent shale retort prior to venting, burning or recycle.

Abstract: A technique is provided for cooling the flue gas or off gas from the bottom of an in situ oil shale retort. The gas is collected in a conduit that has a vertical portion through which the gas flows upwardly. It is then withdrawn from the retort through a gas tight bulkhead. Water is sparged downwardly through the vertical portion of the conduit for cooling and cleaning the gas. Means are provided for draining the sparged water into a sump at the bottom of the retort wherein oil and water are collected. Water and oil are separated and the water may be recycled for additional cooling.