Abstract: An alternative to aqueous film forming foams containing fluorine for firefighting foams for flammable liquid fires is a mist of aqueous ethyleneamine polyphosphate solution or fumed silica doped ethyleneamine polyphosphate solution. The method consists of spraying a mist of such solutions into a flammable liquid fire to suppress the flames and cool the fire. The mist approach also suppresses flames of wood fires. An alternate approach is to add ethyleneamine polyphosphate or fumed silica doped ethyleneamine polyphosphate to a fluorine free foam to form a flame retarded foam that is able to smother a flammable liquid fire.

Abstract: Ethyleneamine polyphosphates are doped with organo silanes and hydrophilic fumed metal oxides such as hydrophilic fumed silica. Such doped EAPPA can then be added to polymers, with subsequently formed FR polymer having improved resistance to becoming sticky in humid air. These compositions are inherently drip resistant in a flame. Substantial addition of hydrophilic fumed silica stops stickiness in air and improves FR as measured by LOI.

Abstract: The flame-retardants of this invention were formed by the direct reaction of ethyleneamines and commercial polyphosphoric acid at an elevated temperature. It was unexpected that a high temperature had to be used to overcome reaction barrier to formation. These compounds are found to be efficient flame retardants.

Abstract: A flame retardant containing composition resistant to becoming sticky from moisture is prepared by the introduction of epoxy containing compound either into the ethyleneamine polyphosphates or into the polymeric composition.

Abstract: The flame-retardants of this invention were formed by the direct reaction of ethyleneamines and commercial polyphosphoric acid at an elevated temperature. It was unexpected that a high temperature had to be used to overcome reaction barrier to formation. These compounds are found to be efficient flame retardants.

Abstract: A flame retardant containing composition resistant to becoming sticky from moisture is prepared by the introduction of epoxy containing compound either into the ethyleneamine polyphosphates or into the polymeric composition.

Abstract: Ethyleneamine polyphosphates are good flame retardants. Use of non viscous phase enables making modified ethyleneamine polyphosphate of enhanced thermal stability and greatly reduced waste stream. Addition of fillers such as fumed silica unexpectedly improve the flame retardance. Organic phosphates improve compatibility.

Abstract: Ethyleneamine polyphosphates are good flame retardants. Use of non viscous phase enables making modified ethyleneamine polyphosphate of enhanced thermal stability and greatly reduced waste stream. Addition of fillers such as fumed silica unexpectedly improve the flame retardance. Organic phosphates improve compatibility.

Abstract: Ethyleneamine polyphosphates are good flame retardants. Use of non viscous phase enables making modified ethyleneamine polyphosphate of enhanced thermal stability and greatly reduced waste stream. Addition of fillers such as fumed silica unexpectedly improve the flame retardance. Organic phosphates improve compatibility.

Abstract: This invention relates to flame barrier compositions as well as a method for the preparation of the flame barrier compositions formed from a flame retardant composition and water. A protective barrier comprises a flame barrier composition or a flame barrier polymer on top of a layer or sandwiched between two or more layers of glass, wood, paper, polymer films, and other layered materials as well as mixtures of layers.

Abstract: This invention relates to flame barrier compositions as well as a method for the preparation of the flame barrier compositions formed from a flame retardant composition and water. A protective barrier comprises a flame barrier composition or a flame barrier polymer on top of a layer or sandwiched between two or more layers of glass, wood, paper, polymer films, and other layered materials as well as mixtures of layers.

Abstract: Flame retardants, and compositions containing the flame retardants are disclosed. The flame retardants are prepared reacting ethylene diamine with polyphosphoric acid; or reacting an ethyleneamine or a mixture of ethyleneamines with phosphoric acid, polyphosphoric acid, pyrophosphoric acid, or a mixtures thereof. A 10% by weight solution of the product in water has a pH between about 3.5 to 6.5. The flame retardants are non-halogen containing flame retardants that do not gas undesirably during processing at temperatures of 235° C. or even higher.

Abstract: This invention relates to a novel process for the preparation of condensed melamine phosphates, and to melamine pyrophosphate prepared by this process having improved thermal stability as a flame retardant.

Abstract: This invention relates to polyester and polyamide compositions which contain a flame retardant, one or more alkaline earth metal salts, and a reinforcing agent. The flame retardant includes a melamine phosphate compound. Addition of at least one alkaline earth metal salt maintains the physical properties and the electrical properties of the resin composition, which degrade upon addition of melamine or melamine salts, while retaining the desired flame retardancy.

Abstract: This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide and synthetic aliphatic, aromatic polyamide copolymers or a mixture thereof; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 5 to about 45 weight percent of melamine polyphosphate; (b) about 15 to about 30 weight percent of melamine polyphosphate and up to about 10 weight percent of a charring catalyst; (c) about 15 to about 30 weight percent of melamine polyphosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, wherein all percents by weight are based on the total weight of (1)+(2)+(3) only.

Abstract: A flame retardant composition comprising coated particles, said particles having a core comprising melamine phosphate, melamine polyphosphate, melamine pyrophosphate, or mixtures thereof, said core having at least one coating comprising an organo silane, ester, polyol, dianhydride, dicarboxylic acid, melamine formaldehyde, or mixtures thereof; a polymer composition containing said flame retardant; a polymer composition containing a flame retardant comprising melamine phosphate, melamine polyphosphate, melamine pyrophosphate or mixtures thereof, and dicarboxylic acid, dianhydride, or mixtures thereof; and a process for preparation of said polymer compositions by increasing extruder throughput are disclosed.

Abstract: A flame retardant composition comprising coated particles, said particles having a core comprising melamine phosphate, melamine polyphosphate, melamine pyrophosphate, or mixtures thereof, said core having at least one coating comprising an organo silane, ester, polyol, dianhydride, dicarboxylic acid, melamine formaldehyde, or mixtures thereof; a polymer composition containing said flame retardant; a polymer composition containing a flame retardant comprising melamine phosphate, melamine polyphosphate, melamine pyrophosphate or mixtures thereof, and dicarboxylic acid, dianhydride, or mixtures thereof; and a process for preparation of said polymer compositions by increasing extruder throughput are disclosed.

Abstract: This invention relates to flame retardants for synthetic resin compositions. It is a composition comprising:(A) about 30 to about 70 wt. percent of a synthetic resin which is,(1) about 30 to about 70 wt. percent of a first resin which is polypropylene, polycarbonate, polyphenylene oxide or polystyrene, or copolymers of polystyrene and maleic anhydride, and(2) about 30 to about 70 wt. percent of a second resin which is polyethylene terephthalate, or nylon 6,6, or blends or mixtures thereof,wherein the wt. percentages of (A)(1) and (A)(2) total 100% as between (A)(1) and (A)(2),(B) a flame retardant selected from the group consisting of(1) about 20 to about 45 wt. percent of melamine pyrophosphate, or(2) about 15 to about 30 wt. percent of melamine pyrophosphate and up to about 10 wt. percent charring catalyst; or(3) about 15 to about 30 wt. percent of melamine pyrophosphate, up to about 10 wt. percent charring catalyst, and up to about 10 wt. percent of a char former, or(4) about 20 to about 40 wt.

Abstract: This invention relates to flame retardants for polyester and polyamide compositions, and specifically relates to compositions containing (1) about 30 to about 70 weight percent of a polyester or a synthetic, aliphatic polyamide or a mixture thereof; (2) about 15 to about 40 weight percent of glass or mineral reinforcing agent; and (3) a flame retardant of (a) about 20 to about 30 weight percent of melamine phosphate and up to about 10 weight percent of a charring catalyst; (b) about 15 to about 30 weight percent of melamine phosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former; (c) about 5 to about 45 weight percent of melamine pyrophosphate; (d) about 15 to about 30 weight percent of melamine pyrophosphate and up to about 10 weight percent of a charring catalyst; (e) about 15 to about 30 weight percent of melamine pyrophosphate, up to about 10 weight percent of a charring catalyst and up to about 10 weight percent of a char former, or (f) about 20

Abstract: Disclosed herein are compositions containing an aliphatic polyamide, a selected tungstic acid or its salt, and a coagent such as melamine cyanurate. These compositions exhibit good fire resistance and good physical toughness, particularly good elongation, and are useful as molding resins. The reaction product of a tungstic acid and melamine may alternatively be incorporated.