Abstract: A process for producing solid carbon and gaseous oxygen from CO2 via electrolysis using an electrolysis apparatus is disclosed. The apparatus includes a chamber with an electrolyte inlet, an electrolyte outlet, a liquid electrolyte containing CO2 in the chamber, at least one cathode-anode pair, with the cathode including a liquid metal capable of catalysing reduction of CO2 to solid carbon at a selected operating temperature of the process. The process includes causing the electrolyte to flow from the inlet to the outlet in fluid communication with the cathode-anode pair, applying a voltage between the cathode-anode pair and causing solid carbon to form on the cathode from CO2 in the electrolyte and gaseous oxygen to be evolved at the anode from CO2 in the electrolyte.

Abstract: An improved direct smelting vessel comprising a smelt reduction vessel (SRV) and optionally a cyclone converter furnace (CCF). The SRV provides means for promoting metal mixing at a zone below a slag layer adjacent to a vessel wall of the direct smelting vessel. The means for promoting metal mixing may include a split-level refractory hearth with two refractory floor levels, a refractory hearth with one or more gas bubbling devices, and/or at least one pair of solids injection lances that provide alternating solids injection at any given time (or other means). The means for promoting the metal mixing reduces a stagnant region capable of supporting a semi-solid slag layer that restricts metal-slag heat transfer. The means for promoting the metal mixing maintains an effective temperature delta between tapped metal at a forehearth and metal at the vessel wall of no greater than 40° C.

Abstract: An apparatus for removing a blockage in a solids injection lance extending into a direct smelting vessel The solids injection lance has a single inlet coupled to a section of supply line that conveys gas and solids to the solids injection lance and that is upstream and co-axial with the solids injection lance. The apparatus has a tool that extends through the supply line section and the solids injection lance to remove a blockage of solid material and an assembly for advancing the tool through the solids injection lance and the supply line section to the blockage from an upstream side of the blockage.

Abstract: A method and an apparatus method for producing direct reduced iron (DRI) from iron ore using biomass as a source of reductant and as a heating source of the iron ore and electromagnetic energy as a further heating source in a furnace having multiple zones. The zones include a preheat zone and a reduction zone between an inlet for briquettes of iron ore and biomass and an outlet for direct reduced iron. The method includes counter-current movement of (a) briquettes of iron ore and biomass in a direction from the inlet to the outlet and (b) combustible gases in an opposite direction in the furnace.

Abstract: A method for producing direct reduced iron (“DRI”) from iron ore and biomass is disclosed. The method includes heating a batch of iron ore and biomass in each oven chamber of a non-recovery batch oven by a combination (i) the thermal mass of a lining of the oven chamber and (ii) combustion of a fuel gas from at least one other oven chamber and at least partially reducing the iron ore and forming DRI. The method also includes discharging gases from the oven chamber through passageways in a wall and a floor of the oven chamber and further combusting combustible gases and transferring heat to the wall and the floor of the oven chamber as the gases move through the passageways. The method also includes discharging at least a portion of gases from the oven chamber, without passing the gases through passageways in the floor of the oven chamber, and using these gases as a fuel gas in subsequent combustion heating in other batch oven chambers when a first predetermined trigger point is reached.

Abstract: A process for producing direct reduced iron (“DRI”) from iron ore and biomass in a single stage fluidised bed includes injecting (a) iron ore, (b) gaseous oxygen and (c) a solid reductant including biomass into a reaction zone of the fluidized bed operating in a temperature range of 750-850#C and reducing iron ore and forming DRI in the fluidized bed and discharging DRI having a metallisation of at least 70% from the fluidised bed.

Abstract: A process and an apparatus for producing direct reduced iron (“DRI”) from iron ore and biomass are disclosed. The process includes heating a batch of iron ore and biomass in a batch oven (3) and reducing iron ore and forming a solid DRI product having a metallisation of 80-99% and generating an offgas. The process includes discharging the solid product at the end of the batch cycle and discharging offgas during the course of the batch cycle. The process operates the batch oven in a temperature range of 700-1100#C in a batch cycle time of 10-100 hours.

Abstract: A smelting vessel includes a plurality of heat pipes (21) positioned in a refractory lining of at least a part of the hearth (9) for cooling at least a part of the refractory lining. At least one of the heat pipes includes (a) a liquid phase of a heat transfer fluid, typically water, in a lower section of the heat pipe and (b) a vapor phase of the heat transfer fluid, typically steam, in an upper section of the heat pipe. The heat pipe also includes a vent to allow vapour phase to escape from the heat pipe to reduce the pressure or the temperature within the heat pipe when the vapour pressure or the temperature in the heat pipe exceeds a predetermined threshold pressure or temperature.

Abstract: An apparatus for removing a blockage in a solids injection lance extending into a direct smelting vessel The solids injection lance has a single inlet coupled to a section of supply line that conveys gas and solids to the solids injection lance and that is upstream and co-axial with the solids injection lance. The apparatus has a tool that extends through the supply line section and the solids injection lance to remove a blockage of solid material and an assembly for advancing the tool through the solids injection lance and the supply line section to the blockage from an upstream side of the blockage.

Abstract: A method of removing a blockage in a solids injection lance under normal operating conditions of a direct smelting vessel is disclosed. The direct smelting vessel contains a bath of molten metal and slag and the solids injection lance extends into the direct smelting vessel and has an outlet end that is submerged in the molten slag. The solids injection lance further has a single inlet coupled to a section of supply line that conveys gas and solid feed material to the solids injection lance. The method comprises (a) advancing a blockage-removing tool through the supply line section and through the solids injection lance to an upstream side of the blockage, (b) operating the tool under elevated gas pressure conditions to remove the blockage such that solid feed material and gas are able to flow through the solids injection lance. The method further comprises (c) retracting the tool from the solids injection lance and the supply line section.

Abstract: A method of sealing a slag drain in a direct smelting vessel is disclosed. Also disclosed are a method of maintaining a slag drain channel and a direct smelting vessel with a slag drain channel that extends through a sleeve of refractory material installed in the direct smelting vessel. The method for sealing the slag drain includes locating a pre-formed refractory material at an inlet end of the slag drain channel so that it is exposed to a molten bath contained within the direct smelting vessel and sealing the slag drain channel with sealing material downstream of the pre-formed refractory material.

Abstract: A method for injecting a solid feed material through a solids injection lance includes creating flow conditions in an injection passageway of the lance so that at least a part of the feed material flowing along the passageway forms a buffer zone between a wall of a tube that defines the passageway and feed material flowing along a central section of the passageway.

Abstract: A smelting apparatus that includes (a) a smelting vessel (4) that is adapted to contain a bath of molten metal and slag and (b) a smelt cyclone (2) for pre-treating a metalliferous feed material positioned above and communicating directly with the smelting vessel The apparatus also includes an oft-gas duct (9) extending from the smelt, cyclone for discharging an off-gas from the smelt cyclone. The off-gas duct has an inlet section (18) that extends upwardly from the smelt cyclone and is formed to cause off-gas to undergo a substantial change of direction as it flows through the inlet section of the off-gas duct.

Abstract: A smelting vessel includes a plurality of heat pipes (21) positioned in a refractory lining of at least a part of the hearth (9) for cooling at least a part of the refractory lining. At least one of the heat pipes includes (a) a liquid phase of a heat transfer fluid, typically water, in a lower section of the heat pipe and (b) a vapor phase of the heat transfer fluid, typically steam, in an upper section of the heat pipe. The heat pipe also includes a vent to allow vapour phase to escape from the heat pipe to reduce the pressure or the temperature within the heat pipe when the vapour pressure or the temperature in the heat pipe exceeds a predetermined threshold pressure or temperature.

Abstract: A molten bath-based direct smelting process comprises controlling the process conditions in a direct smelting vessel so that molten slag in a molten bath of metal and slag in the vessel has a viscosity in a range of 0.5-5 poise when the slag temperature is in the range of 1400-1550° C. in the molten bath in the vessel.

Abstract: A process and apparatus for direct smelting metalliferous material is disclosed. The invention concentrates injection of solid feed materials comprising metalliferous material and carbonaceous material into a direct smelting vessel during the course of the process into a relatively small region within a metal layer in a molten bath in the vessel in order to generate a substantial upward movement of molten material and gas from the metal layer into a region in the vessel that is above the molten bath. In particular, the invention injects the solid food materials with sufficient momentum and/or velocity via an opposed pair of lances that are oriented within the vessel and arranged to form overlapping plumes of injected material in the molten bath.

Abstract: A molten bath-based direct smelting process comprises controlling the process conditions in a direct smelting vessel so that molten slag in a molten bath of metal and slag in the vessel has a viscosity in a range of 0.5-5 poise when the slag temperature is in a range of 1400-1550° C. in the molten bath in the vessel.

Abstract: A solids injection lance includes (a) a tube that defines a passageway for solid feed material to be injected through the tube and has an inlet for solid material at a rear end and an outlet for discharging solid material at a forward end of the tube and (b) a puncture detection system for detecting a puncture in the solids injection tube.

Abstract: A molten bath-based direct smelting process includes controlling the process conditions in a direct smelting vessel so that molten slag in a molten bath of metal and slag in the vessel has a viscosity in a range of 0.5-5 poise in an operating temperature range for the process.

Abstract: A method of removing a blockage in a solids injection lance under normal operating conditions of a direct smelting vessel is disclosed. The direct smelting vessel contains a bath of molten metal and slag and the solids injection lance extends into the direct smelting vessel and has an outlet end that is submerged in the molten slag. The solids injection lance further has a single inlet coupled to a section of supply line that conveys gas and solid feed material to the solids injection lance. The method comprises (a) advancing a blockage-removing tool through the supply line section and through the solids injection lance to an upstream side of the blockage, (b) operating the tool under elevated gas pressure conditions to remove the blockage such that solid feed material and gas are able to flow through the solids injection lance. The method further comprises (c) retracting the tool from the solids injection lance and the supply line section.