Abstract: Process and apparatus for producing helium, neon, or argon product gas using an adsorption separation unit having minimal dead end volumes. A purification unit receives a stream enriched in helium, neon, or argon, and a stream is recycled from the purification unit back to the adsorption separation unit in a controlled manner to maintain the concentration of the helium, neon, or argon in the feed to the separation unit within a targeted range.

Abstract: Disclosed herein are rapid cycle pressure swing adsorption (PSA) process for separating O2 from N2 and/or Ar. The processes use a carbon molecular sieve (CMS) adsorbent having an O2/N2 and/or O2/Ar kinetic selectivity of at least 5 and an O2 adsorption rate (1/s) of at least 0.2000 as determined by linear driving force model at 1 atma and 86° F.

Abstract: Disclosed herein are multi-bed rapid cycle pressure swing adsorption (RCPSA) processes for separating O2 from N2 and/or Ar, wherein the process utilizes at least five adsorption beds each comprising a kinetically selective adsorbent for O2 having an O2 adsorption rate (1/s) of at least 0.20 as determined by linear driving force model at 1 atma and 86° F.

Abstract: Disclosed herein is a stator plate for a rotary bed PSA apparatus that has an exhaust slot that has first and second sections for receiving blowdown and purge exhaust gas streams, the sections being separated by a flow restriction that restricts but does not full prevent gas flow between the sections, or that has separate exhaust slots for separately receiving the blowdown and purge exhaust gas streams. Also disclosed is pressure swing adsorption (PSA) apparatus including such a stator plate, and a rotary bed PSA process using such an apparatus.

Abstract: Disclosed are novel, as-crystallized RHO zeolite compositions with improved uniformity in morphology. These RHO compositions are useful for preparing cation-exchanged RHO zeolites that can be used as adsorbents for oxygen and/or nitrogen with improved properties. The adsorbents can be used in pressure swing adsorption processes for selectively adsorbing oxygen and/or nitrogen from feed streams such as an air stream or crude argon stream. Also disclosed are novel methods of preparing RHO zeolites with improved morphology control.

Abstract: Disclosed herein are novel RHO zeolites useful as kinetically selective adsorbents for oxygen and/or nitrogen. The adsorbents can be used in pressure swing adsorption processes for selectively adsorbing oxygen and/or nitrogen from feed streams such as an air stream or crude argon stream. Also disclosed are novel methods of preparing RHO zeolites, including in particular mixed-cation RHO zeolites.

Abstract: Disclosed herein are multi-bed rapid cycle pressure swing adsorption (RCPSA) processes for separating O2 from N2 and/or Ar, wherein the process utilizes at least five adsorption beds each comprising a kinetically selective adsorbent for O2 having an O2 adsorption rate (1/s) of at least 0.20 as determined by linear driving force model at 1 atma and 86° F.

Abstract: Disclosed herein are rapid cycle pressure swing adsorption (PSA) process for separating O2 from N2 and/or Ar. The processes use a carbon molecular sieve (CMS) adsorbent having an O2/N2 and/or O2/Ar kinetic selectivity of at least 5 and an O2 adsorption rate (1/s) of at least 0.2000 as determined by linear driving force model at 1 atma and 86° F.

Abstract: Disclosed herein is a stator plate for a rotary bed PSA apparatus that has an exhaust slot that has first and second sections for receiving blowdown and purge exhaust gas streams, the sections being separated by a flow restriction that restricts but does not full prevent gas flow between the sections, or that has separate exhaust slots for separately receiving the blowdown and purge exhaust gas streams. Also disclosed is pressure swing adsorption (PSA) apparatus including such a stator plate, and a rotary bed PSA process using such an apparatus.

Abstract: Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

Abstract: Process and apparatus for producing helium, neon, or argon product gas using an adsorption separation unit having minimal dead end volumes. A purification unit receives a stream enriched in helium, neon, or argon, and a stream is recycled from the purification unit back to the adsorption separation unit in a controlled manner to maintain the concentration of the helium, neon, or argon in the feed to the separation unit within a targeted range.

Abstract: Disclosed herein are novel RHO zeolites useful as kinetically selective adsorbents for oxygen and/or nitrogen. The adsorbents can be used in pressure swing adsorption processes for selectively adsorbing oxygen and/or nitrogen from feed streams such as an air stream or crude argon stream. Also disclosed are novel methods of preparing RHO zeolites, including in particular mixed-cation RHO zeolites.

Abstract: Disclosed herein are new processes for adsorbing oxygen using adsorbent compositions comprising RHO zeolites kinetically selective for oxygen. The RHO zeolites can be used in pressure swing adsorption processes for separating oxygen from oxygen containing streams, such as for, but not limited to, purifying a crude argon feed stream or separating oxygen from an air feed stream.

Abstract: An adsorbent having a composition comprising at least 90% chabazite where the chabazite is a single phase chabazite having an Si/Al ratio of 1.2 to 1.8, the chabazite includes a mixture of at least two types of cations, and each of the at least two types of cations are in a molar ratio relative to Al of at least 0.05.

Abstract: A method for preparing an adsorbent is disclosed that includes mixing an NaY zeolite, aqueous Al(OH)3, and aqueous KOH, and then heating the resultant mixture for an allotted amount of time to achieve a composition comprising at least 90% single phase chabazite having an Si/Al ratio of 1.0 to 2.2.

Abstract: An adsorbent having a composition comprising at least 90% chabazite where the chabazite is a single phase chabazite having an Si/Al ratio of 1.2 to 1.8, the chabazite includes a mixture of at least two types of cations, and each of the at least two types of cations are in a molar ratio relative to Al of at least 0.05.

Abstract: Methods and systems for purifying argon from a crude argon stream are disclosed, employing pressure swing adsorption at cold temperatures from ?186° C. to ?20° C.; more preferably from ?150° C. to ?50° C.; and most preferably from ?130° C. to ?80° C. with oxygen-selective zeolite adsorbent. In some embodiments, the oxygen-selective zeolite adsorbent is a 4A zeolite, a chabazite, or a combination thereof.

Abstract: A method of separating oxygen from an oxygen-containing fluid stream is disclosed, the method including the step of contacting the oxygen-containing fluid stream with an oxygen-selective zeolite adsorbent comprising at least 90% chabazite, wherein the chabazite is a single phase chabazite having an Si/Al ratio of 1.2 to 1.8. The single phase chabazite may comprise a mixture of at least two types of cations.

Abstract: An adsorption vessel comprising a packed bed region of adsorbent particles contiguously arranged, comprising a perforated adsorbent particles, a gas separation process using the perforated adsorbent particles, and methods for making the perforated adsorbent particles. The perforated adsorbent particles each comprise an adsorbent material where the perforated adsorbent particles each have at least 10 channels extending through the particle. The equivalent diameter of the channels may range from 0.05 mm to 1.5 mm, and the void fraction of the channels may range from 0.05 to 0.5.

Abstract: An adsorption vessel comprising a packed bed region of adsorbent particles contiguously arranged comprising a perforated adsorbent particles, a gas separation process using the perforated adsorbent particles, and methods for making the perforated adsorbent particles. The perforated adsorbent particles each comprise an adsorbent material where the perforated adsorbent particles each have at least 10 channels extending through the particle. The equivalent diameter of the channels may range from 0.05 mm to 1.5 mm, and the void fraction of the channels may range from 0.05 to 0.5.