Patents by Inventor Roger F. Malherbe

Roger F. Malherbe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5300647
    Abstract: Hindered amines based on various 2,2,6,6-tetraalkylated nitrogen-containing heterocyclic moieties wherein the hindered nitrogen atom on the ring is substituted with O-acyl, O-carbamoyl or O-carbonate substituents and the 4-position of the ring is substituted with a variety of groups, are effective as light stabilizers in diverse substrate systems.
    Type: Grant
    Filed: May 28, 1993
    Date of Patent: April 5, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Roger F. Malherbe, Roland A. E. Winter, James P. Galbo
  • Patent number: 5112890
    Abstract: N-OR.sub.1 substituted hindered amine light stabilizers impart outstanding stabilization properties to acid catalyzed thermoset coating compositions providing enhanced resistance against the deleterious effects of light, moisture or oxygen without inhibition of cure.
    Type: Grant
    Filed: October 19, 1988
    Date of Patent: May 12, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Roland A. E. Winter, Andrew Mar, Peter J. Schirmann, Raymond Seltzer, Roger F. Malherbe
  • Patent number: 5064883
    Abstract: N-hydroxy substituted hindered amine light stabilizers impart outstanding stabilization properties to acid catalyzed thermoset coating compositions with enhanced resistance against the deleterious effects of light, moisture or oxygen in the substantial absence of cure inhibition.
    Type: Grant
    Filed: October 19, 1988
    Date of Patent: November 12, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Roger F. Malherbe
  • Patent number: 4753979
    Abstract: Compounds of the formula (T).sub.g -E where T is a substituted 4-acyl-2-piperazinone group, g is 1 or 2 and E is a selected terminal or linking group, are effective light stabilizers for polyolefins and other organic polymers, particularly thermoset acrylic or alkyd acrylic resins.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: June 28, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Thomas E. Conetta, Roger F. Malherbe, Roland A. E. Winter
  • Patent number: 4665185
    Abstract: Nitroxyls of the formula ##STR1## where E.sub.1, E.sub.2, E.sub.3 and E.sub.4 are independently an organic radical so that the carbon atoms to which they are attached are each a quaternary carbon and T is a divalent radical are prepared by the oxidation of the corresponding amine in an inert organic solvent with a hydroperoxide in the presence of a metal carbonyl, metal oxide or metal alkoxide catalyst in high yield and purity. The nitroxyls may be directly reduced to the corresponding hydroxylamines by catalytic hydrogenation. The nitroxyls are useful as polymerization inhibitors and the hydroxylamines as polymer stabilizers.
    Type: Grant
    Filed: November 20, 1985
    Date of Patent: May 12, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Roger F. Malherbe
  • Patent number: 4650870
    Abstract: Compounds of the formula (T).sub.g -E where T is a substituted 4-acyl-2-piperazinone group, g is 1 or 2 and E is a selected terminal or linking group, are effective light stabilizers for polyolefins and other organic polymers.
    Type: Grant
    Filed: March 12, 1984
    Date of Patent: March 17, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Thomas E. Conetta, Roger F. Malherbe, Roland A. E. Winter
  • Patent number: 4649221
    Abstract: Polyhydroxylamines are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosynergists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: March 10, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Roger F. Malherbe, Raymond Seltzer
  • Patent number: 4547537
    Abstract: Compounds of the formula L-T, where L is an unsubstituted or substituted tetrahydro-1,4-oxazine-2-one group and T is a substituted 4-piperidinyl hindered amine moiety, are effective light stabilizers for polyolefins and other organic polymers.
    Type: Grant
    Filed: August 2, 1984
    Date of Patent: October 15, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Roger F. Malherbe, Michael H. Ackerman
  • Patent number: 4472547
    Abstract: Compounds of the formula (L--T).sub.g --E (I) or (L--T--G) .sub.h --Q (II), where L is a lactam group, T is a substituted 4-piperidinyl hindered amine moiety and E or Q are selected linking or terminal groups, are effective light stabilizers for polyolefins and other organic polymers.
    Type: Grant
    Filed: October 21, 1983
    Date of Patent: September 18, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Roger F. Malherbe
  • Patent number: 4439565
    Abstract: Oligomeric esteramides having recurring structural units of the formula ##STR1## where G is a hindered amine radical of formula I or II ##STR2## in which R.sup.1 is hydrogen or alkyl having 1 to 4 carbon atoms, R.sup.2 is hydrogen, alkyl having 1 to 12 carbon atoms, allyl, benzyl, acetyl, acryloyl or cyano, Z.sub.1 is a direct bond, --NHCH.sub.2 CH.sub.2 --, --NHCH.sub.2 CH.sub.2 CH.sub.2 -- or --OCH.sub.2 CH.sub.2 --, Z.sub.2 is ethylene or trimethylene, E is a divalent aliphatic, aromatic or alicyclic radical and L is unsubstituted or substituted alkylene, are useful light stabilizers for plastics.
    Type: Grant
    Filed: November 10, 1982
    Date of Patent: March 27, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Roger F. Malherbe, Frank Tieh-Yin Fu
  • Patent number: 4389321
    Abstract: Lubricants stabilized against oxidative degradation by the incorporation therein of 2,3-dihydroperimidine derivatives as well as certain 2,3-dihydroperimidines within the indicated group.
    Type: Grant
    Filed: December 28, 1981
    Date of Patent: June 21, 1983
    Assignee: Ciba-Geigy Corporation
    Inventor: Roger F. Malherbe