Patents by Inventor Ryuma Mizushima
Ryuma Mizushima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9878558Abstract: There is provided a water-based ink for ink-jet printing which is excellent in optical density when printed on any of a high-water absorbing recording medium and a low-water absorbing recording medium, spreading of the dot size on the low-water absorbing recording medium, and rub fastness.Type: GrantFiled: June 4, 2014Date of Patent: January 30, 2018Assignee: KAO CORPORATIONInventors: Tetsuya Eguchi, Ryuma Mizushima
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Patent number: 9388321Abstract: The present invention relates to an ink jet printing method for printing images or characters on a recording medium using a water-based ink, in which the water-based ink includes pigment-containing water-insoluble polymer particles A, water-insoluble polymer particles B, an organic solvent C and water; the water-insoluble polymer particles A includes a water-insoluble polymer (a) containing constitutional units derived from an ionic monomer (a-1), an aromatic ring-containing hydrophobic monomer (a-2) and a specific hydrophilic monomer (a-3), the constitutional unit derived from the hydrophilic monomer (a-3) being present in an amount of from 13 to 45% by mass; the organic solvent C includes one or more organic solvents having a boiling point of 90° C. or higher, and has an average boiling point of 250° C. or lower as a weighted mean value; and the recording medium has a water absorption of from 0 to 10 g/m2 as measured in a pure water contact time of 100 ms.Type: GrantFiled: December 10, 2013Date of Patent: July 12, 2016Assignee: KAO CORPORATIONInventors: Ryuma Mizushima, Tetsuya Eguchi
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Publication number: 20160130453Abstract: There is provided a water-based ink for ink-jet printing which is excellent in optical density when printed on any of a high-water absorbing recording medium and a low-water absorbing recording medium, spreading of the dot size on the low-water absorbing recording medium, and rub fastness.Type: ApplicationFiled: June 4, 2014Publication date: May 12, 2016Applicant: KAO CORPORATIONInventors: Tetsuya EGUCHI, Ryuma MIZUSHIMA
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Publication number: 20150344713Abstract: The present invention relates to an ink jet printing method for printing images or characters on a recording medium using a water-based ink, in which the water-based ink includes pigment-containing water-insoluble polymer particles A, water-insoluble polymer particles B, an organic solvent C and water; the water-insoluble polymer particles A includes a water-insoluble polymer (a) containing constitutional units derived from an ionic monomer (a-1), an aromatic ring-containing hydrophobic monomer (a-2) and a specific hydrophilic monomer (a-3), the constitutional unit derived from the hydrophilic monomer (a-3) being present in an amount of from 13 to 45% by mass; the organic solvent C includes one or more organic solvents having a boiling point of 90° C. or higher, and has an average boiling point of 250° C. or lower as a weighted mean value; and the recording medium has a water absorption of from 0 to 10 g/m2 as measured in a pure water contact time of 100 ms.Type: ApplicationFiled: December 10, 2013Publication date: December 3, 2015Applicant: KAO CORPORATIONInventors: Ryuma MIZUSHIMA, Tetsuya EGUCHI
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Patent number: 9022542Abstract: The present invention relates to [1] an ink-jet printing method including the steps of applying an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer onto a recording medium, and then applying by ink-jet printing, a water-based ink (B) onto the recording medium; [2] a recording paper for ink-jet printing which is obtainable by applying an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer onto a recording medium; and [3] a water-based ink set including an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer, and a water-based ink (B) containing an anionic colorant.Type: GrantFiled: August 19, 2010Date of Patent: May 5, 2015Assignee: Kao CorporationInventors: Yuki Wakabayashi, Ryuma Mizushima
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Publication number: 20140063155Abstract: The present invention relates to [1] an ink-jet printing method including the steps of applying an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer onto a recording medium, and then applying by ink-jet printing, a water-based ink (B) onto the recording medium; [2] a recording paper for ink-jet printing which is obtainable by applying an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer onto a recording medium; and [3] a water-based ink set including an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer, and a water-based ink (B) containing an anionic colorant.Type: ApplicationFiled: August 19, 2010Publication date: March 6, 2014Applicant: KAO CORPORATIONInventors: Yuki WAKABAYASHI, Ryuma MIZUSHIMA
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Patent number: 8222318Abstract: The present invention relates to (1) a process for producing a water dispersion for ink-jet printing containing colorant-containing polymer particles which includes a step I of obtaining a dispersion of colorant-containing polymer particles; a step II of obtaining a water dispersion of the colorant-containing polymer particles from the dispersion obtained in the step I; a step III of mixing the water dispersion obtained in the step II with an organic solvent (B) to suitably control a relative dielectric constant of a mixed solvent in the resultant dispersion, thereby precipitating the colorant-containing polymer particles; and a step IV of separating precipitates obtained in the step III from the dispersion and re-dispersing the precipitates in a water-based solvent; (2) a water-based ink for ink-jet printing which is excellent in ejection stability and optical density; (3) a process for purifying a water dispersion for ink-jet printing; and (4) a process for producing a dispersion containing groups of fine pType: GrantFiled: December 13, 2007Date of Patent: July 17, 2012Assignee: Kao CorporationInventors: Ryuma Mizushima, Nobuyuki Takizawa
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Publication number: 20120147106Abstract: The present invention relates to [1] an ink-jet printing method including the steps of applying an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer onto a recording medium, and then applying by ink-jet printing, a water-based ink (B) onto the recording medium; [2] a recording paper for ink-jet printing which is obtainable by applying an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer onto a recording medium; and [3] a water-based ink set including an ink (A) having a static surface tension of from 23 to 70 mN/m and containing a poly(N-acylalkylene imine)-modified silicone and a cationic polymer, and a water-based ink (B) containing an anionic colorant.Type: ApplicationFiled: August 19, 2010Publication date: June 14, 2012Applicant: NEC CORPORATIONInventors: Yuki Wakabayashi, Ryuma Mizushima
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Patent number: 8013053Abstract: The present invention relates to a water-based ink for ink-jet printing which exhibits a high optical density even upon one-pass printing on plain papers and is suitable for high-speed printing, and a dispersion used in the water-base ink. There are provided a water dispersion for ink-jet printing, including water-insoluble polymer particles containing a colorant, and a nonionic organic compound satisfying the following conditions I and II: I: Water containing 0.001% by weight of the nonionic organic compound has a surface tension of 70 mN/m or less as measured at 25° C.; and II: A solubility of the nonionic organic compound in 100 g of water is 0.30 g or less as measured at 25° C., a water-based ink containing the water dispersion, and a method of conducting a one-pass printing using the water-based ink.Type: GrantFiled: December 27, 2006Date of Patent: September 6, 2011Assignee: Kao CorporationInventors: Hiroyuki Yoshida, Isao Tsuru, Ryuma Mizushima
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Patent number: 7795327Abstract: A water dispersion containing colorant-containing water-insoluble vinyl polymer particles, and a water-based ink containing the water dispersion. The water-insoluble vinyl polymer contains constitutional units of formulae (1) and (2): where R1 is a hydrogen atom or a methyl group; and R2 is a substituted or unsubstituted arylalkyl group or a substituted or unsubstituted aryl group; and where R3 is a hydrogen atom or a methyl group; R4O is an oxypropylene group; R5O is an oxyalkylene group having 2 or 4 carbon atoms; R6 is a hydrogen atom, an alkyl group or an unsubstituted or alkyl-substituted phenyl group; x is a number from 1 to 30; and y is a number from 0 to 30, and a weight ratio of the constitutional units of formula (1) to formula (2) in the polymer ranges from 1/2 to 10/1.Type: GrantFiled: August 26, 2005Date of Patent: September 14, 2010Assignee: KAO CorporationInventors: Ryuma Mizushima, Isao Tsuru, Hirotaka Takeno
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Patent number: 7749316Abstract: The present invention relates to a water dispersion for ink-jet printing, including a colorant, particles (A) (except for pigments) having a refractive index of 1.0 to 2.2, and a nonionic organic compound containing a saturated or unsaturated hydrocarbon group having 8 to 30 carbon atoms, and exhibiting a solubility of 1 g or less in 100 g of water as measured at 25° C., as well as a water based ink containing the water dispersion. There are provided a water-based ink for ink-jet printing which can exhibit a high optical density upon one-pass printing on plain papers and, therefore, is suitable for high-speed printing, as well as a water dispersion used in the water-based ink.Type: GrantFiled: February 2, 2007Date of Patent: July 6, 2010Assignee: Kao CorporationInventors: Ryuma Mizushima, Hiroyuki Yoshida, Isao Tsuru, Yusuke Shimizu
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Publication number: 20100036048Abstract: The present invention relates to (1) a process for producing a water dispersion for ink-jet printing containing colorant-containing polymer particles which includes a step I of obtaining a dispersion of colorant-containing polymer particles; a step II of obtaining a water dispersion of the colorant-containing polymer particles from the dispersion obtained in the step I; a step III of mixing the water dispersion obtained in the step II with an organic solvent (B) to suitably control a relative dielectric constant of a mixed solvent in the resultant dispersion, thereby precipitating the colorant-containing polymer particles; and a step IV of separating precipitates obtained in the step III from the dispersion and re-dispersing the precipitates in a water-based solvent; (2) a water-based ink for ink-jet printing which is excellent in ejection stability and optical density; (3) a process for purifying a water dispersion for ink-jet printing; and (4) a process for producing a dispersion containing groups of fine pType: ApplicationFiled: December 13, 2007Publication date: February 11, 2010Inventors: Ryuma Mizushima, Nobuyuki Takizawa
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Patent number: 7495039Abstract: The present invention relates to a water dispersion for ink jet recording, comprising water-insoluble vinyl polymer particles containing a colorant, wherein the water-insoluble vinyl polymer is a water-insoluble vinyl polymer obtained by polymerizing a monomer mixture comprising: (A) a monomer represented by the formula (I): wherein R1 represents a hydrogen atom or a methyl group, R2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or a phenyl group whose hydrogen atom may be substituted with an alkyl group having 1 to 9 carbon atoms and m denotes a number from 65 to 100; (B) a salt-forming group-containing monomer; and (C) a hydrophobic monomer and the average particle diameter of the water-insoluble vinyl polymer particles containing a colorant is 0.02 to 0.50 ?m.Type: GrantFiled: June 25, 2004Date of Patent: February 24, 2009Assignee: Kao CorporationInventors: Koji Azuma, Takehiro Tsutsumi, Ryuma Mizushima, Isao Tsuru
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Patent number: 7354961Abstract: The invention provides a process for producing a water dispersion for ink jet recording,which comprises the following steps 1 and 2: (Step 1) a step of obtaining a pigment treated with (a) a water-insoluble vinyl polymer particles by making a pigment and (a) a water-insoluble vinyl polymer particles present in an aqueous solvent and then removing the solvent; and (Step 2) a step of obtaining a water dispersion of a pigment-containing water-insoluble vinyl polymer particles by dispersing a mixture comprising the water-insoluble vinyl polymer particle (a)—treated pigment obtained in step 1, an organic solvent, (b) a water-insoluble vinyl polymer and water and then removing the organic solvent.Type: GrantFiled: June 30, 2004Date of Patent: April 8, 2008Assignee: Kao CorporationInventors: Koji Azuma, Takehiro Tsutsumi, Ryuma Mizushima, Hirotaka Takeno, Toshiya Iwasaki
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Patent number: 7345098Abstract: A water-based ink comprising an aqueous dispersion of polymer particles made of a water-insoluble vinyl polymer containing a colorant, wherein the water-insoluble vinyl polymer is prepared by polymerizing a monomer composition comprising a specific monomer A such as a monomer A1 represented by the formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen, alkyl or alkylphenyl, and n is 1 to 30; a monomer having a salt-forming group; and a monomer copolymerizable with the monomer A and the monomer having a salt-forming group. The water-based ink can be suitably used as a water-based ink for inkjet recording and the like.Type: GrantFiled: December 27, 2002Date of Patent: March 18, 2008Assignee: Kao CorporationInventors: Ryuma Mizushima, Isao Tsuru, Koji Azuma, Takehiro Tsutsumi
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Publication number: 20080028981Abstract: The present invention relates to a water dispersion for ink-jet printing, including a colorant, particles (A) (except for pigments) having a refractive index of 1.0 to 2.2, and a nonionic organic compound containing a saturated or unsaturated hydrocarbon group having 8 to 30 carbon atoms, and exhibiting a solubility of 1 g or less in 100 g of water as measured at 25° C., as well as a water based ink containing the water dispersion. There are provided a water-based ink for ink-jet printing which can exhibit a high optical density upon one-pass printing on plain papers and, therefore, is suitable for high-speed printing, as well as a water dispersion used in the water-based ink.Type: ApplicationFiled: February 2, 2007Publication date: February 7, 2008Applicant: Kao CorporationInventors: Ryuma Mizushima, Hiroyuki Yoshida, Isao Tsuru, Yusuke Shimizu
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Patent number: 7291659Abstract: There are provided a water dispersion for ink-jet printing comprising colorant-containing water-insoluble graft polymer particles in which the water-insoluble graft polymer contains a main chain which is a polymer chain containing a constitutional unit derived from a salt-forming group-containing monomer (a) and a constitutional unit derived from an aromatic ring-containing (meth)acrylate monomer (b), and a side chain which is a polymer chain containing a constitutional unit derived from a hydrophobic monomer (c); a water-based ink for ink-jet printing using the water dispersion; and an ink-jet printing method using the water-based ink. In accordance with the present invention, printed images or characters formed on a coated paper are excellent in gloss, image clarity and image clarity property including both of the image clarity and the gloss, and printed images or characters formed on an ordinary paper exhibit a high print density.Type: GrantFiled: July 28, 2005Date of Patent: November 6, 2007Assignee: KAO CorporationInventors: Isao Tsuru, Ryuma Mizushima, Katsuhiko Inada, Takehiro Tsutsumi
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Publication number: 20070149647Abstract: The present invention relates to a water-based ink for ink-jet printing which exhibits a high optical density even upon one-pass printing on plain papers and is suitable for high-speed printing, and a dispersion used in the water-base ink. There are provided a water dispersion for ink-jet printing, including water-insoluble polymer particles containing a colorant, and a nonionic organic compound satisfying the following conditions I and II: I: Water containing 0.001% by weight of the nonionic organic compound has a surface tension of 70 mN/m or less as measured at 25° C.; and II: A solubility of the nonionic organic compound in 100 g of water is 0.30 g or less as measured at 25° C., a water-based ink containing the water dispersion, and a method of conducting an one-pass printing using the water-based ink.Type: ApplicationFiled: December 27, 2006Publication date: June 28, 2007Inventors: Hiroyuki Yoshida, Isao Tsuru, Ryuma Mizushima
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Publication number: 20070078200Abstract: The present invention relates to a water dispersion for ink-jet printing including a colorant, metal oxide fine particles having an average particle size of 110 to 400 nm, and water-insoluble polymer particles, a weight ratio of the metal oxide fine particles to the colorant (metal oxide fine particles/colorant) being from 0.15 to 10; a water dispersion for ink-jet printing including metal oxide fine particles having an average particle size of 400 nm or smaller, and colorant-containing water-insoluble polymer particles; a water dispersion for ink-jet printing including plate-shaped metal oxide fine particles, and colorant-containing water-insoluble polymer particles; and a water-based ink for ink-jet printing including any of these water dispersions. According to the present invention, it is possible to achieve a high optical density of images upon printing the images with the water-based ink on a plain paper.Type: ApplicationFiled: August 30, 2006Publication date: April 5, 2007Applicant: KAO CORPORATIONInventors: Hiroyuki YOSHIDA, Ryuma Mizushima
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Patent number: 7112619Abstract: A water-based ink containing an aqueous dispersion of water-insoluble vinyl polymer particles containing a pigment, wherein the water-insoluble vinyl polymer is prepared by copolymerizing a monomer mixture containing (a) a monomer having a salt-forming group, (b) a monomer having a long-chain alkyl group, (c) a macromer, (d) a monomer having a polyoxyalkylene group, and (e) a monomer copolymerizable with the monomer having a salt-forming group (a), the monomer having a long-chain alkyl group (b), the macromer (c) and the monomer having a polyoxyalkylene group (d). The water-based ink can be suitably used, for instance, as a water-based ink for inkjet recording and the like.Type: GrantFiled: December 22, 2003Date of Patent: September 26, 2006Assignee: Kao CorporationInventors: Makoto Sakakibara, Nobushige Tanaka, Ryuma Mizushima, Kenji Kaida, Takehiro Tsutsumi