Patents by Inventor Samuel Joseph Camardello
Samuel Joseph Camardello has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10720554Abstract: A device including an LED light source optically coupled to a green-emitting U6+-doped phosphor having a composition selected from the group consisting of U6+-doped phosphate-vanadate phosphors, U6+-doped halide phosphors, U6+-doped oxyhalide phosphors, U6+-doped silicate-germanate phosphors, U6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).Type: GrantFiled: September 20, 2017Date of Patent: July 21, 2020Assignee: General Electric CompanyInventors: Samuel Joseph Camardello, Anant Achyut Setlur
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Patent number: 10600604Abstract: A phosphor composition is presented. The phosphor composition includes a solid solution of aluminum nitride and a complex oxide including europium and strontium, where an amount of oxygen in the solid solution is at least 0.4 weight percent and less than 1 weight percent. A lighting apparatus including a phosphor material including the phosphor composition is also provided.Type: GrantFiled: June 23, 2017Date of Patent: March 24, 2020Assignee: CURRENT LIGHTING SOLUTIONS, LLCInventor: Samuel Joseph Camardello
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Publication number: 20200028033Abstract: A device including an LED light source optically coupled to a phosphor material including a green-emitting phosphor selected from the group consisting of compositions of (A1)-(A70), and combinations thereof.Type: ApplicationFiled: September 7, 2018Publication date: January 23, 2020Inventors: Samuel Joseph CAMARDELLO, Anant Achyut SETLUR
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Publication number: 20190280165Abstract: A device including an LED light source optically coupled to a phosphor material including a green-emitting phosphor selected from the group consisting of compositions (A1)-(A62) and combinations thereof.Type: ApplicationFiled: March 8, 2018Publication date: September 12, 2019Inventors: Samuel Joseph Camardello, Anant Achyut Setlur
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Publication number: 20190088827Abstract: A device including an LED light source optically coupled to a green-emitting U6+-doped phosphor having a composition selected from the group consisting of U6+-doped phosphate-vanadate phosphors, U6+-doped halide phosphors, U6+-doped oxyhalide phosphors, U6+-doped silicate-germanate phosphors, U6+-doped alkali earth oxide phosphors, and combinations thereof, is presented. The U6+-doped phosphate-vanadate phosphors are selected from the group consisting of compositions of formulas (A1)-(A12). The U6+-doped halide phosphors are selected from the group consisting of compositions for formulas (B1)-(B3). The U6+-doped oxyhalide phosphors are selected from the group consisting of compositions of formulas (C1)-(C5). The U6+-doped silicate-germanate phosphors are selected from the group consisting of compositions of formulas (D1)-(D11). The U6+-doped alkali earth oxide phosphors are selected from the group consisting of formulas (E1)-(E11).Type: ApplicationFiled: September 20, 2017Publication date: March 21, 2019Inventors: Samuel Joseph Camardello, Anant Achyut Setlur
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Publication number: 20180374668Abstract: A phosphor composition is presented. The phosphor composition includes a solid solution of aluminum nitride and a complex oxide including europium and strontium, where an amount of oxygen in the solid solution is at least 0.4 weight percent and less than 1 weight percent. A lighting apparatus including a phosphor material including the phosphor composition is also provided.Type: ApplicationFiled: June 23, 2017Publication date: December 27, 2018Inventor: Samuel Joseph CAMARDELLO
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Publication number: 20180163126Abstract: A process for preparing a Mn+4 doped phosphor of formula I Ax[MFy]:Mn+4?? I includes combining a first solution comprising a source of A and a second solution comprising H2MF6 in the presence of a source of Mn, to form the Mn+4 doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and wherein a value of a Hammett acidity function of the first solution is at least ?0.9. Particles produced by the process may have a particle size distribution with a D50 particle size of less than 10 ?m.Type: ApplicationFiled: December 2, 2017Publication date: June 14, 2018Inventors: James Edward Murphy, Srinivas Prasad Sista, Samuel Joseph Camardello
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Patent number: 9890328Abstract: A lighting apparatus that includes a light source and a phosphor composition radiationally coupled to the light source is presented. The phosphor composition includes a first phosphor that includes a phase of general formula (I): L3ZO4(Br2-nXn):Eu2+ wherein 0?n?1; L is Zn, Mg, Ca, Sr, Ba, or combinations thereof; Z is Si, Ge, or a combination thereof; and X is F, Cl, I, or combinations thereof.Type: GrantFiled: June 23, 2015Date of Patent: February 13, 2018Assignee: General Electric CompanyInventors: Samuel Joseph Camardello, Alok Mani Srivastava, Fangming Du, Holly Ann Comanzo, William Winder Beers, William Erwin Cohen
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Patent number: 9537061Abstract: A phosphor composition is disclosed. A phosphor composition, comprises at least 10 atomic % bromine; silicon, germanium or combination thereof; oxygen; a metal M, wherein M comprises zinc (Zn), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), or combinations thereof; and an activator comprising europium. The phosphor composition is formed from combining carbonate or oxides of metal M, silicon oxide, and europium oxide; and then firing the combination. A lighting apparatus including the phosphor composition is also provided. The phosphor composition may be combined with an additional phosphor to generate white light.Type: GrantFiled: December 12, 2014Date of Patent: January 3, 2017Assignee: General Electric CompanyInventors: Alok Mani Srivastava, Holly Ann Comanzo, William Winder Beers, Samuel Joseph Camardello, Fangming Du, William Erwin Cohen
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Publication number: 20160172549Abstract: A phosphor composition is disclosed. A phosphor composition, comprises at least 10 atomic % bromine; silicon, germanium or combination thereof; oxygen; a metal M, wherein M comprises zinc (Zn), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), or combinations thereof; and an activator comprising europium. The phosphor composition is formed from combining carbonate or oxides of metal M, silicon oxide, and europium oxide; and then firing the combination. A lighting apparatus including the phosphor composition is also provided. The phosphor composition may be combined with an additional phosphor to generate white light.Type: ApplicationFiled: December 12, 2014Publication date: June 16, 2016Inventors: Alok Mani Srivastava, Holly Ann Comanzo, William Winder Beers, Samuel Joseph Camardello, Fangming Du, William Erwin Cohen
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Publication number: 20160168457Abstract: A phosphor composition is presented. The phosphor composition includes a first phosphor that includes a phase of general formula (I): L3ZO4(Br2-nXn):Eu2+?? (I) wherein 0?n?1; L is Zn, Mg, Ca, Sr, Ba, or combinations thereof; Z is Si, Ge, or a combination thereof; and X is F, Cl, I, or combinations thereof. A lighting apparatus that includes a light source and the phosphor composition radiationally coupled to the light source is also presented.Type: ApplicationFiled: June 23, 2015Publication date: June 16, 2016Inventors: Samuel Joseph Camardello, Alok Mani Srivastava, Fangming Du, Holly Ann Comanzo, William Winder Beers, William Erwin Cohen
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Patent number: 9321959Abstract: Processes for producing particles of rare earth-containing phosphor materials, in which the particles have a core-shell structure and the shell has a lower rare earth content than the core. Such a process may include contacting a core particle with a precursor comprising Na(La,Ce,Tb)P2O7 to form a mixture, and then heating the mixture to a temperature sufficient to decompose the Na(La,Ce,Tb)P2O7 to evolve and melt an NaPO3 flux and initiate deposition of a (La,Ce,Tb)PO4 shell on each core particle in the presence of the molten NaPO3 flux.Type: GrantFiled: August 25, 2014Date of Patent: April 26, 2016Assignee: GENERAL ELECTRIC COMAPNYInventors: Alok Mani Srivastava, Holly Ann Comanzo, William Winder Beers, Samuel Joseph Camardello, Digamber Gurudas Porob, William Erwin Cohen
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Publication number: 20160053171Abstract: Processes for producing particles of rare earth-containing phosphor materials, in which the particles have a core-shell structure and the shell has a lower rare earth content than the core. Such a process may include contacting a core particle with a precursor comprising Na(La,Ce,Tb)P2O7 to form a mixture, and then heating the mixture to a temperature sufficient to decompose the Na(La,Ce,Tb)P2O7 to evolve and melt an NaPO3 flux and initiate deposition of a (La,Ce,Tb)PO4 shell on each core particle in the presence of the molten NaPO3 flux.Type: ApplicationFiled: August 25, 2014Publication date: February 25, 2016Inventors: Alok Mani SRIVASTAVA, Holly Ann COMANZO, William Winder BEERS, Samuel Joseph CAMARDELLO, Digamber Gurudas POROB, William Erwin COHEN
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Patent number: 9123525Abstract: Phosphor particles, methods for their use to produce fluorescent lamps, and fluorescent lamps that make use of such particles. Such a phosphor particle has a core surrounded by a shell, and the shell contains GdMgB5O10 doped (activated) with at least terbium ions as a rare earth-containing phosphor composition that absorbs ultraviolet photons to emit green-spectrum light. The core is formed of a mineral material that is chemically compatible with the rare earth-containing phosphor composition of the shell, but does not contain intentional additions of terbium.Type: GrantFiled: December 23, 2013Date of Patent: September 1, 2015Assignee: GENERAL ELECTRIC COMPANYInventors: Alok Mani Srivastava, Holly Ann Comanzo, William Winder Beers, Samuel Joseph Camardello, Digamber Gurudas Porob, William Erwin Cohen
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Publication number: 20150179423Abstract: Phosphor particles, methods for their use to produce fluorescent lamps, and fluorescent lamps that make use of such particles. Such a phosphor particle has a core surrounded by a shell, and the shell contains GdMgB5O10 doped (activated) with at least terbium ions as a rare earth-containing phosphor composition that absorbs ultraviolet photons to emit green-spectrum light. The core is formed of a mineral material that is chemically compatible with the rare earth-containing phosphor composition of the shell, but does not contain intentional additions of terbium.Type: ApplicationFiled: December 23, 2013Publication date: June 25, 2015Applicant: General Electric CompanyInventors: Alok Mani SRIVASTAVA, Holly Ann COMANZO, William Winder BEERS, Samuel Joseph CAMARDELLO, Digamber Gurudas POROB, William Erwin COHEN
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Patent number: 8866372Abstract: Mercury vapor discharge fluorescent lamps are provided. The lamp can include a lamp envelope enclosing a discharge space and having an inner surface. First and second electrodes can be positioned on the lamp, such as on opposite ends of the lamp envelope. An ionizable medium that includes mercury and an inert gas can be within said lamp envelope. A phosphor layer can be on the inner surface of the lamp envelope. The phosphor layer generally includes a phosphor blend of a calcium halophosphor, a blue phosphor having an emission peak at about 440 nm to about 490 nm, a blue-green phosphor having an emission peak at about 475 nm to about 530 nm, and a red phosphor having an emission peak at about 600 nm to about 650 nm.Type: GrantFiled: December 5, 2011Date of Patent: October 21, 2014Assignee: General Electric CompanyInventors: William Winder Beers, Jon Bennett Jansma, Fangming Du, William Erwin Cohen, Alok Mani Srivastava, Samuel Joseph Camardello, Holly Ann Comanzo
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Patent number: 8663501Abstract: Cerium, gadolinium and terbium doped aluminum phosphates of formula I may be used in fluorescent lamps Al1-x-y-z-a-b-c-d-eTbxCeyGdzLuaScbIncLadGaePO4??I wherein x is greater than or equal to about 0.001 and less than or equal to about 0.3; y is greater than or equal to about 0.001 and less than or equal to about 0.3; z is greater than or equal to about 0.01 and less than or equal to about 0.3; a is greater than or equal to about 0.01 and less than or equal to about 0.1; b is greater than or equal to about 0.01 and less than or equal to about 0.1; c is greater than or equal to about 0.01 and less than or equal to about 0.1. d is greater than or equal to about 0.01 and less than or equal to about 0.1; and e is greater than or equal to about 0.01 and less than or equal to about 0.1.Type: GrantFiled: June 29, 2011Date of Patent: March 4, 2014Assignee: General Electric CompanyInventors: Alok Mani Srivastava, Holly Ann Comanzo, Gopi Chandran Ramachandran, Samuel Joseph Camardello, Swarnagowri Addepalli, Florencio Garcia
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Patent number: 8593062Abstract: An LED lamp includes a light source configured to emit radiation with a peak intensity at a wavelength between about 250 nm and about 550 nm; and a phosphor composition configured to be radiationally coupled to the light source. The phosphor composition includes particles of a phosphor of formula I, said particles having a coating composition disposed on surfaces thereof; ((Sr1-zMz)1-(x+w)AwCex)3(Al1-ySiy)O4+y+3(x?w)F1-y-3(x?w)??I wherein the coating composition comprises a material selected from aluminum oxide, magnesium oxide, calcium oxide, barium oxide, strontium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, and combinations thereof; and A is Li, Na, K, or Rb, or a combination thereof; M is Ca, Ba, Mg, Zn, or a combination thereof; and 0<x?0.10, 0?y?0.5, 0?z?0.5, 0?x?x.Type: GrantFiled: April 5, 2011Date of Patent: November 26, 2013Assignee: General Electric CompanyInventors: James Edward Murphy, Anant Achyut Setlur, Samuel Joseph Camardello
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Patent number: 8531098Abstract: A phosphor blend suitable for use in a fluorescent lamp for emitting white light is disclosed. The phosphor blend includes a first phosphor, a second phosphor and a third phosphor. The first phosphor is selected from a europium doped barium magnesium aluminate, a europium doped strontium aluminate, and a combination thereof; and the second phosphor has formula Y2O3:Eu3+. The third phosphor is selected from a phosphor of formula I: (A1-xMnx)E4O7, a phosphor of formula II: (L1-y-zMyMnz)2P2O7, and a combination thereof, where 0<x?0.10, 0<y?0.20, 0<z?0.10; A is Ca, Ba, Sr, Zn, Mg, or a combination thereof; E is Ga, Al, In, or a combination thereof; L is Ca, Ba, Sr, Zn, Mg, Na, or a combination thereof; and M is at least one of Sn, and Ce. A fluorescent lamp including such phosphor blend is also disclosed.Type: GrantFiled: November 29, 2011Date of Patent: September 10, 2013Assignee: General Electric CompanyInventors: Alok Mani Srivastava, Holly Ann Comanzo, Samuel Joseph Camardello
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Publication number: 20130140978Abstract: Mercury vapor discharge fluorescent lamps are provided. The lamp can include a lamp envelope enclosing a discharge space and having an inner surface. First and second electrodes can be positioned on the lamp, such as on opposite ends of the lamp envelope. An ionizable medium that includes mercury and an inert gas can be within said lamp envelope. A phosphor layer can be on the inner surface of the lamp envelope. The phosphor layer generally includes a phosphor blend of a calcium halophosphor, a blue phosphor having an emission peak at about 440 nm to about 490 nm, a blue-green phosphor having an emission peak at about 475 nm to about 530 nm, and a red phosphor having an emission peak at about 600 nm to about 650 nm.Type: ApplicationFiled: December 5, 2011Publication date: June 6, 2013Inventors: William Winder BEERS, Jon Bennett Jansma, Fangming Du, William Erwin Cohen, Alok Mani Srivastava, Samuel Joseph Camardello, Holly Ann Comanzo