Abstract: Copolymers of PEEK and PEEK/PEK and methods of preparation thereof are provided. The melt temperatures of the PEEK copolymer and PEEK/PEK copolymer compositions are in the range of 350° C. to 420° C. The compositions are based on PEEK monomers biphenol and 4,4?-difluorobenzophenone with other PEEK co-monomers such as hydroquinone and PEK co-monomers such as 4-chloro-4?-hydroxybenzophenone, 4,4?-difluorobenzophenone and 4,4?-dihydroxybenzophenone.

Abstract: A process for the preparation of an alkali metal salt of 4-chloro-4?-hydroxy benzophenone including the steps of (a) preparing purified 4-chloro-4?-hydroxy benzophenone by a process including distilling under reduced pressure a liquid containing 4-chloro-4?-hydroxy benzophenone and a solvent selected from diphenyl sulphone, diphenylene sulphone, benzophenone and dichlorobenzophenone, and then (b) preparing the alkali metal salt of thus purified 4-chloro-4?-hydroxy benzophenone by the reaction of the purified 4-chloro-4?-hydroxy benzophenone with a stoichiometric excess of at least one alkali metal base. There is also described a polymerization process using the alkali metal salt to yield PEK with high inherent viscosity and improved mechanical and thermal properties.

Abstract: A process for the preparation of an alkali metal salt of 4-chloro-4?-hydroxy benzophenone including the steps of (a) preparing purified 4-chloro-4?-hydroxy benzophenone by a process including distilling under reduced pressure a liquid containing 4-chloro-4?-hydroxy benzophenone and a solvent selected from diphenyl sulphone, diphenylene sulphone, benzophenone and dichlorobenzophenone, and then (b) preparing the alkali metal salt of thus purified 4-chloro-4?-hydroxy benzophenone by the reaction of the purified 4-chloro-4?-hydroxy benzophenone with a stoichiometric excess of at least one alkali metal base. There is also described a polymerization process using the alkali metal salt to yield PEK with high inherent viscosity and improved mechanical and thermal properties.