Abstract: Provided are method of producing a shaped fluoropolymer articles. The methods include subjecting a composition comprising a fluoropolymer to additive processing in an additive processing device. Also provided are articles obtained with the methods and 3D-printable compositions.

Abstract: The method of making a three-dimensional article includes heating a composition comprising a fluoropolymer and inorganic filler, extruding the composition in molten form from an extrusion head to provide at least a portion of a first layer of the three-dimensional article, and extruding at least a second layer of the composition in molten form from the extrusion head onto at least the portion of the first layer to make at least a portion of the three-dimensional article. Three-dimensional articles are also described. A composition including a fluoropolymer and inorganic fillers is also described. The composition may be a filament. The composition can be useful, for example, in melt extrusion additive manufacturing. The fluoropolymer is semi-crystalline with a melting point of up to 325° C. and less than 50 percent by weight interpolymerized units of vinylidene fluoride or amorphous with a glass transition temperature of up to 280° C.

Abstract: The method of making a three-dimensional article includes heating a composition comprising a polymer and hollow ceramic microspheres, extruding the composition in molten form from an extrusion head to provide at least a portion of a first layer of the three-dimensional article, and extruding at least a second layer of the composition in molten form from the extrusion head onto at least the portion of the first layer to make at least a portion of the three-dimensional article. Three-dimensional articles are also described. A composition including a polymer and hollow ceramic microspheres is also described. The composition may be a filament. The polymer is at least one of a low-surface-energy polymer or polyolefin. The composition can be useful, for example, in melt extrusion additive manufacturing, for example, fused filament fabrication.

Abstract: Provided are method of producing a shaped fluoropolymer articles. The methods include subjecting a composition comprising a fluoropolymer to additive processing in an additive processing device. Also provided are articles obtained with the methods and 3D-printable compositions.

Abstract: A method of making a nanostructure and nanostructured articles by depositing a layer to a major surface of a substrate by plasma chemical vapor deposition from a gaseous mixture while substantially simultaneously etching the surface with a reactive species. The method includes providing a substrate; mixing a first gaseous species capable of depositing a layer onto the substrate when formed into a plasma, with a second gaseous species capable of etching the substrate when formed into a plasma, thereby forming a gaseous mixture; forming the gaseous mixture into a plasma; and exposing a surface of the substrate to the plasma, wherein the surface is etched and a layer is deposited on at least a portion of the etched surface substantially simultaneously, thereby forming the nanostructure. The substrate can be a (co)polymeric material, an inorganic material, an alloy, a solid solution, or a combination thereof.

Abstract: A method of making a nanostructure and nanostructured articles by depositing a layer to a major surface of a substrate by plasma chemical vapor deposition from a gaseous mixture while substantially simultaneously etching the surface with a reactive species. The method includes providing a substrate; mixing a first gaseous species capable of depositing a layer onto the substrate when formed into a plasma, with a second gaseous species capable of etching the substrate when formed into a plasma, thereby forming a gaseous mixture; forming the gaseous mixture into a plasma; and exposing a surface of the substrate to the plasma, wherein the surface is etched and a layer is deposited on at least a portion of the etched surface substantially simultaneously, thereby forming the nanostructure. The substrate can be a (co)polymeric material, an inorganic material, an alloy, a solid solution, or a combination thereof.

Abstract: A multilayer optical film is provided comprising first optical layers of a first fluoropolymeric material and second optical layers of a second fluoropolymeric material wherein at least a portion of the first layers and at least a portion of the second layers are in intimate contact.

Abstract: A method of making a nanostructure and nanostructured articles by depositing a layer to a major surface of a substrate by plasma chemical vapor deposition from a gaseous mixture while substantially simultaneously etching the surface with a reactive species. The method includes providing a substrate; mixing a first gaseous species capable of depositing a layer onto the substrate when formed into a plasma, with a second gaseous species capable of etching the substrate when formed into a plasma, thereby forming a gaseous mixture; forming the gaseous mixture into a plasma; and exposing a surface of the substrate to the plasma, wherein the surface is etched and a layer is deposited on at least a portion of the etched surface substantially simultaneously, thereby forming the nanostructure. The substrate can be a (co)polymeric material, an inorganic material, an alloy, a solid solution, or a combination thereof.

Abstract: A method and apparatus for enhancing a cognitive ability of a user may comprise: conducting, via a user interface display of a user computing device, a training session which may comprise: presenting a transportation routing network having a source of travelers and a respective unique destination for each traveler and a path from the source to the respective unique destination, each path comprising at least one direction modification element operable by the user to correctly direct the traveler from the source to the respective unique destination; displaying to the user a traveler moving along a path from the source to the at least one direction modification element; allowing the user to control the position of the at least one direction modification element so as to direct the traveler from the source to the respective unique destination.

Abstract: This disclosure relates to an architectural article comprising a multilayer optical film comprising optically thin polymeric layers, wherein at least one of the optically thin polymeric layers comprises a fluoropolymer, and wherein the multilayer optical film is UV-stable.

Abstract: An article, method of using, and method of making a multilayer optical film comprising an optical stack, wherein the optical stack comprises a plurality of first optical layers, each first optical layer comprising a melt-processible copolymer comprising interpolymerized monomers of tetrafluoroethylene, with the proviso that the melt-processible copolymer is not fluorinated ethylene-propylene copolymer or a perfluoroalkoxy resin; and a second polymer layer disposed in a repeating sequence with the plurality of first optical layers, each second optical layer comprising a non-fluorinated polymeric material selected from the group consisting of poly(methyl methacrylate); copolymers of poly(methyl methacrylate); polypropylene; copolymers of polypropylene; polystyrenes; copolymers of styrene; polyvinylidene chloride; polycarbonates; thermoplastic polyurethanes; copolymers of ethylene; cyclic olefin copolymers; and combinations thereof is described.

Abstract: A multilayer optical film is provided comprising first optical layers of a first fluoropolymeric material and second optical layers of a second fluoropolymeric material wherein at least a portion of the first layers and at least a portion of the second layers are in intimate contact

Abstract: A process for making an optical film includes stretching a polyolefin film in a first direction and stretching the polyolefin film in a second direction different than the first direction forming a biaxially stretched polyolefin film. At least a portion of the stretching of the polyolefin film in the second direction occurs simultaneous with the stretching of the polyolefin film in the first direction. The biaxially stretched polyolefin film has a length and a width and substantially non-absorbing and non-scattering for at least one polarization state of visible light. The biaxially stretched polyolefin film has x, y, and z orthogonal indices of refraction where at least two of the orthogonal indices of refraction are not equal, an in-plane retardance being 100 nm or less and an out-of-plane retardance being 50 nm or greater.

Abstract: A process for making an optical film includes stretching a polyolefin film in a first direction and stretching the polyolefin film in a second direction different than the first direction forming a biaxially stretched polyolefin film. At least a portion of the stretching of the polyolefin film in the second direction occurs simultaneous with the stretching of the polyolefin film in the first direction. The biaxially stretched polyolefin film has a length and a width and substantially non-absorbing and non-scattering for at least one polarization state of visible light. The biaxially stretched polyolefin film has x, y, and z orthogonal indices of refraction where at least two of the orthogonal indices of refraction are not equal, an in-plane retardance being 100 nm or less and an out-of-plane retardance being 50 nm or greater.