Abstract: A system includes a signal source that provides a first signal for measuring a gas content of a liquid sample. The system also includes an analyzer that determines the gas content of the liquid sample using a measurement of a second signal, where the second signal is based on the first signal. The system further includes an apparatus with a walled structure having a cavity. The apparatus also includes a piston that pulls the liquid sample into the cavity and pushes the liquid sample out of the cavity. The apparatus further includes at least one measurement window having at least one inner surface exposed within the cavity. The at least one measurement window receives the first signal from the signal source and provides the second signal to the analyzer. The piston could also clean the at least one inner surface, and the piston can include a reference material for calibrating the analyzer.

Abstract: A system includes a sensing cell having a walled structure configured to receive a fuel sample within an interior space of the walled structure. The sensing cell also has at least one cooling surface located on at least a portion of the walled structure and configured to cool the fuel sample. The sensing cell further has an optical port configured to couple to one or more optical fibers and to provide first radiation to the fuel sample. In addition, the sensing cell has a mirror configured to reflect the first radiation in order to provide second radiation to the optical port. The optical port defines a collinear optical geometry for providing the first radiation to the fuel sample and receiving the second radiation through the fuel sample. The system also includes at least one cooler configured to cool the fuel sample in the sensing cell by cooling the at least one cooling surface.

Abstract: A method includes identifying first data associated with cyclic voltammetry measurements of a material being examined. The cyclic voltammetry measurements include applying a varying first voltage to the material and measuring a first current. The method also includes identifying second data associated with impedance measurements. The impedance measurements include applying a second voltage to the material and measuring a second current. The second data includes a scaling factor. The method further includes adjusting at least part of the first data using the scaling factor and identifying a composition of the material using the adjusted first data. The first data could include a current versus voltage curve that associates values of the first current to values of a sweep voltage. The first data could be adjusted by normalizing the curve using the scaling factor, and the normalized curve could be used to generate a current derivative curve.

Abstract: A method includes receiving a measurement associated with a cloud point of a biofuel being produced in a refining system. The method also includes determining how to adjust the refining system based on a desired cloud point of the biofuel and the measurement associated with the cloud point. The method further includes outputting a control signal to adjust the refining system based on the determination. Determining how to adjust the refining system could include determining how to adjust an inlet temperature of a reactor in the refining system. The reactor could represent an isomerization reactor, and a heater could heat material entering the isomerization reactor. Determining how to adjust the inlet temperature of the reactor could include determining how to adjust operation of the heater. A model predictive control (MPC) technique could be used to determine how to adjust the inlet temperature of the isomerization reactor.

Abstract: Fluorescent nanoparticles such as quantum dots are incorporated into paper and other web products such as plastics to achieve cross-direction and machine direction on-line detection of selected components during manufacture. Fluorescent nanoparticles markers are added in known proportions into product formulations along with the selected components of interest. By detecting the fluorescence from the nanoparticles, the selected components can be traced at various stages of production. In addition, by using different fluorescent nanoparticles that emit radiation at different wavelengths, data from individual materials or layers in a composite structure can be ascertained simultaneously with a single sensor. The technique is particularly suited for monitoring expensive and difficult-to-measure components that may be present only in trace quantities.

Abstract: Scale formation on the electrode(s) of a liquor sensor can be prevented by continuously delivering a water-soluble scale inhibitor or dispersant into the vicinity of the electrodes of a liquor sensor device. Scale inhibitors include, for instance, polymers that are derived from acrylic acid, maleic acid, acrylamide acid, phosphonate, and combinations thereof. An aqueous mixture of scaling inhibitor continuously delivered to the probe tip of the liquor sensor that was placed in a kraft pulping liquor allowed the sensor to operate accurately for over a month without having to be cleaned of scale.

Abstract: A spectroscopic method and spectroscopy system therefrom for analyzing samples. A sample includes a first chemical component that has a characteristic first absorption peak is provided. The sample is irradiated in a measurement waveband proximate to the first absorption peak, and at a first and a second reference waveband where the first chemical component lacks characteristic absorption features. Reflected or transmitted detection data is obtained including a measured power proximate to the first absorption peak and first and second reference powers at the reference wavebands. A plurality of different waveband ratios are evaluated using pairs of detection data to generate a plurality of measured waveband ratio values.

Abstract: Fluorescent nanoparticles such as quantum dots are incorporated into plastic, paper and other web layered products to achieve cross-direction and machine direction on-line analysis of the individual layers therein. Fluorescent nanoparticles markers are added in known proportions into product formulations. By detecting the fluorescence from the nanoparticles, the thickness and other physical characteristics of the web can be traced at various stages of production. In addition, by using different populations of fluorescent nanoparticles that emit radiation at different wavelengths, data from individual layers in a composite structure can be ascertained simultaneously with a single sensor. The technique is particularly suited for monitoring difficult-to-measure polymers in complex multilayer structures.

Abstract: A spectroscopic method and spectroscopy system therefrom for analyzing samples. A sample includes a first chemical component that has a characteristic first absorption peak is provided. The sample is irradiated in a measurement waveband proximate to the first absorption peak, and at a first and a second reference waveband where the first chemical component lacks characteristic absorption features. Reflected or transmitted detection data is obtained including a measured power proximate to the first absorption peak and first and second reference powers at the reference wavebands. A plurality of different waveband ratios are evaluated using pairs of detection data to generate a plurality of measured waveband ratio values.

Abstract: Fluorescent nanoparticles such as quantum dots are incorporated into plastic, paper and other web layered products to achieve cross-direction and machine direction on-line analysis of the individual layers therein. Fluorescent nanoparticles markers are added in known proportions into product formulations. By detecting the fluorescence from the nanoparticles, the thickness and other physical characteristics of the web can be traced at various stages of production. In addition, by using different populations of fluorescent nanoparticles that emit radiation at different wavelengths, data from individual layers in a composite structure can be ascertained simultaneously with a single sensor. The technique is particularly suited for monitoring difficult-to-measure polymers in complex multilayer structures.

Abstract: A method includes identifying first data associated with cyclic voltammetry measurements of a material being examined. The cyclic voltammetry measurements include applying a varying first voltage to the material and measuring a first current. The method also includes identifying second data associated with impedance measurements. The impedance measurements include applying a second voltage to the material and measuring a second current. The second data includes a scaling factor. The method further includes adjusting at least part of the first data using the scaling factor and identifying a composition of the material using the adjusted first data. The first data could include a current versus voltage curve that associates values of the first current to values of a sweep voltage. The first data could be adjusted by normalizing the curve using the scaling factor, and the normalized curve could be used to generate a current derivative curve.

Abstract: An optical scanner for use in conjunction with an infrared spectrometer is disclosed. The optical scanner translates a beam of radiation to a stationary spot on a traveling sheet of material so that ample integration time within the spectrometer is achieved. The beam path impinges on the traveling web and the radiation is reflected off the traveling web back through the optical scanner and recombined at an interferometer. The beam of radiation is kept stationary with respect to both the traveling sheet and the carriage which houses the spectrometer.

Abstract: A spectroscopic sensor for measuring flat sheet product is disclosed. The disclosed sensor uses a combination of spectrometers and single-channel detectors and filters together with a broadband source of illumination to optimally measure multiple properties of a flat sheet product. A spectrometer is used to measure over a spectral range where an easily configurable set of wavelength channels is needed and where the signal-to-noise ratios and spectral resolutions of the channels are consistent with the spectral range and number of pixels of the spectrometer; while one or more single channel detector and filter combinations are used to measure, with high signal-to-noise ratio, at specific wavelengths within or outside the spectral range of the spectrometer(s).

Abstract: A system and method for analyzing the characteristics of a thin film is provided whereby the in-plane birefringence of thin films is determined by measuring the interference fringes in the transmission or reflection spectra using unpolarized light and light linearly polarized along the MD and CD directions. The three spectra can be measured simultaneously or sequentially. The in-plane birefringence data can be used to characterize clear polymer films, which are principally made of biaxial oriented polymer, as the film is being continuously fabricated on a production line.

Abstract: A spectroscopic sensor for measuring flat sheet product is disclosed. The disclosed sensor uses a combination of spectrometers and single-channel detectors and filters together with a broadband source of illumination to optimally measure multiple properties of a flat sheet product. A spectrometer is used to measure over a spectral range where an easily configurable set of wavelength channels is needed and where the signal-to-noise ratios and spectral resolutions of the channels are consistent with the spectral range and number of pixels of the spectrometer; while one or more single channel detector and filter combinations are used to measure, with high signal-to-noise ratio, at specific wavelengths within or outside the spectral range of the spectrometer(s).

Abstract: An optical scanner for use in conjunction with an infrared spectrometer is disclosed. The optical scanner translates a beam of radiation to a stationary spot on a traveling sheet of material so that ample integration time within the spectrometer is achieved. The beam path impinges on the traveling web and the radiation is reflected off the traveling web back through the optical scanner and recombined at an interferometer. The beam of radiation is kept stationary with respect to both the traveling sheet and the carriage which houses the spectrometer.

Abstract: A system and method for analyzing the characteristics of a thin film is provided whereby the in-plane birefringence of thin films is determined by measuring the interference fringes in the transmission or reflection spectra using unpolarized light and light linearly polarized along the MD and CD directions. The three spectra can be measured simultaneously or sequentially. The in-plane birefringence data can be used to characterize clear polymer films, which are principally made of biaxial oriented polymer, as the film is being continuously fabricated on a production line.