Patents by Inventor Shawn D. Feist
Shawn D. Feist has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20220251115Abstract: Methods for preparing a catalyst precursor material from dihalo-substituted metalloids are provided. The methods In include mixing a first solution of a halogenated alkane, at least one solvent, and a first component selected from a dihalo-substituted-group-14 metalloid or an organolithium reagent in a first reaction zone. Continuously adding the first solution to a second reaction zone, and continuously adding a second solution to the second reaction zone. The second solution including at least one solvent and a second component of either the dihalo-substituted-group-14 metalloid or the organolithium reagent, the second component is different from the first component. Mixing the first solution and the second solution in the second reaction zone.Type: ApplicationFiled: March 27, 2020Publication date: August 11, 2022Inventors: Jayachandran Devaraj, Chunming Zhang, Shawn D. Feist, Heqi Pan, Donnie W. Blaylock, Ian B. Gillespie, Patrick L. Heider, Clark S. Davis, Andre Yvon-Bessette
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Patent number: 10570114Abstract: Improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalkyl and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates and arylalkyl and alkyl 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates, are described herein. The improved methods include a direct Suzuki coupling step, which eliminates the protection/de-protection steps in the current chemical process, and therefore eliminates or reduces various raw materials, equipment and cycle time as well as modification of other process conditions including use of crude AP, use of ABA-diMe, and varying pH, catalyst concentration, solvent composition, and/or workup procedures. This includes synthesis of 2-aryl-6-aminopyrimidine-4-carboxylates.Type: GrantFiled: July 26, 2018Date of Patent: February 25, 2020Assignee: Dow AgroSciences LLCInventors: Jason S. Fisk, Xiaoyong Li, Mark Muehlfeld, Robert S. Bauman, Jossian Oppenheimer, Siyu Tu, Mark A. Nitz, Reetam Chakrabarti, Shawn D. Feist, James W. Ringer, Ronald B. Leng
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Patent number: 10544121Abstract: Improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalkyl and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates and arylalkyl and alkyl 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates, are described herein. The improved methods include a direct Suzuki coupling step, which eliminates the protection/de-protection steps in the current chemical process, and therefore eliminates or reduces various raw materials, equipment and cycle time as well as modification of other process conditions including use of crude AP, use of ABA-diMe, and varying pH, catalyst concentration, solvent composition, and/or workup procedures. This includes synthesis of 2-aryl-6-aminopyrimidine-4-carboxylates.Type: GrantFiled: July 26, 2018Date of Patent: January 28, 2020Assignee: Dow AgroSciences LLCInventors: Jason S. Fisk, Xiaoyong Li, Mark Muehlfeld, Robert S. Bauman, Jossian Oppenheimer, Siyu Tu, Mark A. Nitz, Reetam Chakrabarti, Shawn D. Feist, James W. Ringer, Ronald B. Leng
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Publication number: 20180334444Abstract: Improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalkyl and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates and arylalkyl and alkyl 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates, are described herein. The improved methods include a direct Suzuki coupling step, which eliminates the protection/de-protection steps in the current chemical process, and therefore eliminates or reduces various raw materials, equipment and cycle time as well as modification of other process conditions including use of crude AP, use of ABA-diMe, and varying pH, catalyst concentration, solvent composition, and/or workup procedures. This includes synthesis of 2-aryl-6-aminopyrimidine-4-carboxylates.Type: ApplicationFiled: July 26, 2018Publication date: November 22, 2018Applicant: Dow AgroSciences LLCInventors: Jason S. Fisk, Xiaoyong Li, Mark Muehlfeld, Robert S. Bauman, Jooossian Oppenheimer, Siyu Tu, Mark A. Nitz, Reetam Chakrabarti, Shawn D. Feist, James W. Ringer, Ronald B. Leng
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Publication number: 20180334445Abstract: Improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalkyl and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates and arylalkyl and alkyl 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates, are described herein. The improved methods include a direct Suzuki coupling step, which eliminates the protection/de-protection steps in the current chemical process, and therefore eliminates or reduces various raw materials, equipment and cycle time as well as modification of other process conditions including use of crude AP, use of ABA-diMe, and varying pH, catalyst concentration, solvent composition, and/or workup procedures. This includes synthesis of 2-aryl-6-aminopyrimidine-4-carboxylates.Type: ApplicationFiled: July 26, 2018Publication date: November 22, 2018Applicant: Dow AgroSciences LLCInventors: Jason S. F, Xiaoyong Li, Mark Muehlfeld, Robert S. Bauman, Jossian Oppenheimer, Siyu Tu, Mark A. Nitz, Reetam Chakrabarti, Shawn D. Feist, James W. Ringer, Ronald B. Leng
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Patent number: 10087164Abstract: Improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalkyl and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates and arylalkyl and alkyl 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates, are described herein. The improved methods include a direct Suzuki coupling step, which eliminates the protection/de-protection steps in the current chemical process, and therefore eliminates or reduces various raw materials, equipment and cycle time as well as modification of other process conditions including use of crude AP, use of ABA-diMe, and varying pH, catalyst concentration, solvent composition, and/or workup procedures. This invention was expanded to include synthesis of 2-aryl-6-aminopyrimidine-4-carboxylates.Type: GrantFiled: May 19, 2017Date of Patent: October 2, 2018Assignee: Dow AgroSciences LLCInventors: Jason S. Fisk, Xiaoyong Li, Mark Muehlfeld, Robert S. Bauman, Jossian Oppenheimer, Siyu Tu, Mark A. Nitz, Reetam Chakrabarti, Shawn D. Feist, James W. Ringer, Ronald B. Leng
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Publication number: 20170334878Abstract: Improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalky and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates and arylalkyl and alkyl 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates, are described herein. The improved methods include a direct Suzuki coupling step, which eliminates the protection/de-protection steps in the current chemical process, and therefore eliminates or reduces various raw materials, equipment and cycle time as well as modification of other process conditions including use of crude AP, use of ABA-diMe, and varying pH, catalyst concentration, solvent composition, and/or workup procedures. This invention was expanded to include synthesis of 2-aryl-6-aminopyrimidine-4-carboxylates.Type: ApplicationFiled: May 19, 2017Publication date: November 23, 2017Applicant: Dow AgroSciences LLCInventors: Jason S. Fisk, Xiaoyong Li, Mark Muehlfeld, Robert S. Bauman, Jossian Oppenheimer, Siyu Tu, Mark A. Nitz, Reetam Chakrabarti, Shawn D. Feist, James W. Ringer, Ronald B. Leng
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Patent number: 9233908Abstract: The instant invention provides cycloaliphatic diamines and a method of making the same. The cycloaliphatic diamines according to the instant invention comprise the reaction product of one or more cycloaliphatic cyanoaldehydes selected from the group consisting of 1,3-cyanocyclohexane carboxaldehyde, 1,4-cyanocyclohexane carboxaldehyde, mixtures thereof, and combinations thereof, hydrogen, and ammonia fed into a continuous reductive amination reactor system; wherein the one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia are contacted with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C. and a pressure in the range of from 700 to 3500 psig; and wherein one or more cycloaliphatic diamines are formed; and wherein said one or more cycloaliphatic diamines are selected from the group consisting of 1,3-bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane, combinations thereof, and mixtures thereof.Type: GrantFiled: July 30, 2010Date of Patent: January 12, 2016Assignee: Dow Global Technologies LLCInventors: Abraham D. Schuitman, Shawn D. Feist, Barry B. Fish, Daniel A. Hickman, Erich J. Molitor, Michael L. Tulchinsky
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Patent number: 9193487Abstract: A method of packaging a food product using a polymer membrane, the polymer being a self assembling polymeric material, and the method including a.) rendering the said polymer into a film; and b.) packaging a food product in an atmosphere with the said polymer film, wherein said film regulates the atmosphere in which the food product is packaged.Type: GrantFiled: February 11, 2011Date of Patent: November 24, 2015Inventors: Scott T. Matteucci, Leonardo C. Lopez, Shawn D. Feist, Peter N. Nickias, Shrikant N. Khot
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Patent number: 9187403Abstract: The instant invention provides a process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities, and aliphatic diamines obtained via such a process. The process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities according to the instant invention comprises the steps of: (1) feeding one or more cycloaliphatic cyanoaldehydes, hydrogen, ammonia, and optionally one or more solvents into a continuous reductive amination reactor system; (2) contacting said one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C.Type: GrantFiled: July 30, 2010Date of Patent: November 17, 2015Assignee: Dow Global Technologies LLCInventors: Stacie Santhany, Patrick Ho Sing Au-Yeung, Gerald W. Dare, Shawn D. Feist, Barry B. Fish, Daniel A. Hickman, David Jean, Erich J. Molitor, Abraham D. Schuitman, Todd William Toyzan
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Publication number: 20150321915Abstract: The present disclosure provides a process and a system for producing dichlorine (Cl2).Type: ApplicationFiled: July 17, 2015Publication date: November 12, 2015Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Eric E. Stangland, Daniel A. Hickman, Mark E. Jones, Simon G. Podkolzin, Shawn D. Feist
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Patent number: 9035098Abstract: A process for conversion of aliphatic bicyclic amines to aliphatic diamines including contacting one or more bicyclic amines selected from the group consisting of 3-azabicyclo[3.3.1]nonane and azabicyclo[3.3.1]non-2-ene with ammonia and hydrogen, and alcohols in the presence of heterogeneous metal based catalyst systems, a metal selected from the group consisting of Co, Ni, Ru, Fe, Cu, Re, Pd, and their oxides at a temperature from 140° C. to 200° C. and a pressure from 1540 to 1735 psig for at least one hour reactor systems; forming a product mixture comprising aliphatic diamine(s), bicyclic amine(s), ammonia, hydrogen, and alcohol(s); removing said product mixture from the reactor system; removing at least some of the ammonia, hydrogen, water, alcohols, bicyclic amines from said product mixture; thereby separating the aliphatic diamines from said product mixture.Type: GrantFiled: July 30, 2010Date of Patent: May 19, 2015Assignee: Dow Global Technologies LLCInventors: Shawn D. Feist, Daniel A. Hickman, Erich J. Molitor, David C. Molzahn, Stacie Santhany, Abraham D. Schuitman
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Patent number: 9024072Abstract: A process for reductive amination of aliphatic cyanoaldehydes to aliphatic diamines comprising (1) providing a mixture of 1,3-cyanocyclohexane carboxaldehyde and/or 1,4-cyanocyclohexane carboxaldehyde; (2) contacting said mixture with a metal carbonate based solid bed or a weak base anion exchange resin bed at a temperature from 15 to 40 ° C. for a period of at least 1 minute; (3) thereby treating said mixture, wherein said treated mixture has a pH in the range of 6 to 9; (4) feeding said treated mixture, hydrogen, and ammonia into a continuous reductive amination reactor system; (6) contacting said treated mixture, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature from 80 ° C. to 160 ° C. and a pressure from 700 to 3500 psig; (7) thereby producing one or more cycloaliphatic diamines is provided.Type: GrantFiled: July 30, 2010Date of Patent: May 5, 2015Assignee: Dow Global Technologies LLCInventors: Erich J. Molitor, Daniel A. Hickman, Shawn D. Feist, David C. Molzahn, Stacie Santhany, Abraham D. Schuitman
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Publication number: 20140033920Abstract: Described is an enhanced partially-aminated metal-organic framework comprising, or prepared from, metal cations and a synergistically effective ratio of a multi-carboxylic acid and an amino-substituted derivative of the multi-carboxylic acid, or the acceptable salts thereof, or any combination thereof; a manufactured article comprising the enhanced partially-aminated metal-organic framework; a method of preparing the enhanced partially-aminated metal-organic framework, and a method of using the enhanced partially-aminated metal-organic framework for separating carbon dioxide gas or other acid gas from an ad rem gas mixture.Type: ApplicationFiled: February 20, 2012Publication date: February 6, 2014Applicant: Dow Global Technologies LLCInventors: Michael P. Tate, Scott T. Matteucci, Shawn D. Feist, Dean M. Millar
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Publication number: 20130133515Abstract: A method of removing an acidic gas from a gas stream by contacting said gas stream with a polymer, wherein the polymer is a macromolecularly self assembling polymeric material, the method including the steps of contacting the gas mixture with the membrane; and extracting the acidic gas from the gas stream.Type: ApplicationFiled: February 11, 2011Publication date: May 30, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Scott T. Matteucci, Leonardo C. Lopez, Shawn D. Feist, Peter N. Nickias, William J. Harris
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Publication number: 20130074451Abstract: A method of packaging a food product using a polymer membrane, the polymer being a self assembling polymeric material, and the method including a.) rendering the said polymer into a film; and b.) packaging a food product in an atmosphere with the said polymer film, wherein said film regulates the atmosphere in which the food product is packaged.Type: ApplicationFiled: February 11, 2011Publication date: March 28, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Scott T. Matteucci, Leonardo C. Lopez, Shawn D. Feist, Peter N. Nickias, Shrikant N. Khot
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Patent number: 8404086Abstract: Effect separation of a composition of matter that includes at least two seed or plant oil derivatives into at least one desired product stream using at least two separation operations, which are independently selected from among several potential separation operations, in conjunction with at least one recycle stream from a separation operation.Type: GrantFiled: June 20, 2008Date of Patent: March 26, 2013Assignee: Dow Global Technologies LLCInventors: George J. Frycek, Shawn D. Feist, Timothy C. Frank, Zenon Lysenko, Joe D. Phillips, Bruce W. Pynnonen
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Publication number: 20130047843Abstract: A membrane for separation of gases, the membrane including a metal-organic phase and a polymeric phase, the metal-organic phase having porous crystalline metal compounds and ligands, the polymeric phase having a molecularly self assembling polymer.Type: ApplicationFiled: February 11, 2011Publication date: February 28, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Scott T. Matteucci, Leonardo C. Lopez, Shawn D. Feist, Peter N. Nickias, Dean M. Millar, Michael P. Tate
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Patent number: 8343257Abstract: The instant invention generally provides polymer pi-bond-philic filler composite comprising a molecularly self-assembling material and a pi-bond-philic filler, and a process of making and an article comprising the polymer pi-bond-philic filler composite. The instant invention also generally provides a process of separating a pi-bond-philic gas from a separable gas mixture comprising the pi-bond-philic gas.Type: GrantFiled: November 20, 2009Date of Patent: January 1, 2013Assignee: Dow Global Technologies LLCInventors: Scott T. Matteucci, Shawn D. Feist, Peter N. Nickias, Leonardo C. Lopez, Michael S. Paquette, Jeffrey C. Munro
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Publication number: 20120190905Abstract: An improved ionic liquid membrane and its preparation for separation of olefins/paraffins is described. The membrane comprises an ionic liquid with a metal salt. The ionic liquid includes a choline salt, selected from choline, chloride/hydroxide/bitratrate, phosphatidylcholine and is a deep eutectic liquid. The metal salt selected from silver, copper, gold, mercury, cadmium, zinc with choloride, nitrate, tetrafluoroborate, triflate, cyanide, thiocyanide, tetraphenylborate as anion. The ionic liquid is eutectic or a so-called deep eutectic liquid. The experimental examples use choline chloride, urea and silver nitrate/chloride and are tested for methane/ethene separation.Type: ApplicationFiled: September 16, 2010Publication date: July 26, 2012Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Johnathan T. Gorke, Shawn D. Feist, Scott T. Matteucci, Peter N. Nickias