Abstract: A post-deterioration performance estimating apparatus estimates a post-deterioration performance value indicating performance of an energy storage device at a predetermined deterioration point, wherein discharge capacity of the energy storage device discharging at a predetermined first current is referred to as energy storage capacity, discharge capacity of the energy storage device discharging at a second current of a current value smaller than that of the first current is referred to as small current discharge capacity, a relational expression on relation among initial capacity of the energy storage device, a first capacity decreased amount obtained by subtracting the small current discharge capacity from the initial capacity, a second capacity decreased amount obtained by subtracting the energy storage capacity from the small current discharge capacity, and a cumulative operating period as a cumulative value of operating periods of the energy storage device is referred to as a first relational expression,

Abstract: A performance deterioration detecting apparatus detects an initial state of sudden deterioration in performance of an energy storage device as a performance deterioration start state, and includes: a first acquiring unit configured to acquire a first maximum variation amount as a maximum value of a capacity variation amount that is a degree of variation in current carrying capacity relative to variation in voltage of the charged or discharged energy storage device, regarding a capacity-voltage property at a first time point, indicating relation between the capacity variation amount and the voltage; a second acquiring unit configured to acquire a second maximum variation amount as a maximum value of the capacity variation amount regarding the capacity-voltage property at a second time point after the first time point; and a performance deterioration determiner configured to determine that the energy storage device is in the performance deterioration start state at the second time point if a variation amount ra

Abstract: An additive typified by tris(trimethylsilyl)phosphate, tris(trimethylsilyl)borate, and tetrakis(trimethylsiloxy)titanium (Chem. 3) are applied to a nonaqueous electrolyte containing a chain carbonate and/or a chain carboxylate as a main solvent (contained at a ratio of 70 volume % or higher). It is preferable that 0?a<30 is satisfied, in which “a” denotes the volume of a cyclic carbonate among carbonates having no carbon-carbon double bond in the entire volume, defined as 100, of the carbonates having no carbon-carbon double bond and chain carboxylates in a nonaqueous solvent contained in the nonaqueous electrolyte (0<a<30 in the case no chain carboxylate is contained).

Abstract: Gas generation of a non-aqueous electrolyte battery having a negative active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium as negative electrode is suppressed. A non-aqueous electrolyte battery comprising a non-aqueous electrolyte containing an electrolyte salt and a non-aqueous solvent, a positive electrode and a negative electrode is characterized in that the main active material of said negative electrode is an active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium and the auxiliary active material of said negative electrode is an active material that at least intercalates lithium ions at a potential lower than 1.

Abstract: A non-aqueous electrolyte battery includes a non-aqueous electrolyte containing an electrolytic salt and a non-aqueous solvent, a positive electrode, and a negative electrode having a negative active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium, wherein a film coat having a carbonate structure and a thickness of not less than 10 nm exists on the surface of the negative electrode. A non-aqueous electrolyte battery is operated in a region of potential of the negative electrode higher than 0.8 V relative to the potential of lithium.

Abstract: An additive typified by tris(trimethylsilyl)phosphate, tris(trimethylsilyl)borate, and tetrakis(trimethylsiloxy)titanium (Chem. 3) are applied to a nonaqueous electrolyte containing a chain carbonate and/or a chain carboxylate as a main solvent (contained at a ratio of 70 volume % or higher). It is preferable that 0?a<30 is satisfied, in which “a” denotes the volume of a cyclic carbonate among carbonates having no carbon-carbon double bond in the entire volume, defined as 100, of the carbonates having no carbon-carbon double bond and chain carboxylates in a nonaqueous solvent contained in the nonaqueous electrolyte (0<a<30 in the case no chain carboxylate is contained).

Abstract: A nonaqueous electrolytic cell manufacturing method is characterized in that a nonaqueous electrolyte containing vinylene carbonate is used, a coating on the surface of the negative electrode is formed at the initial charging/discharging in such a way by lowering the negative electrode potential to less than 0.4 V with relative to the lithium potential, wherein the nonaqueous electrolytic cell comprises a nonaqueous electrolyte containing an electrolytic salt and a nonaqueous solvent, a positive electrode, and a negative electrode containing a negative electrode material into/from which lithium ions are inserted/desorbed at a potential higher than the lithium potential by 1.2 V. The nonaqueous electrolytic cell is used in a range of negative electrode potential nobler than the lithium potential by 0.8 V.

Abstract: The present invention provides a non-aqueous electrolyte secondary battery having high energy density and satisfactory cycle performance by using an alloy comprising Ni and Sn as a negative active material. The non-aqueous electrolyte secondary battery comprises a negative electrode with a composite layer containing a negative active material, a positive electrode and a non-aqueous electrolyte. The negative active material consists of an alloy containing 5 to 25 mass % of nickel and 75 to 95 mass % of tin and the alloy contains Sn4Ni3 phase and Sn phase. It is preferable that the content ratio of Sn4Ni3 phase and Sn phase in the alloy be 0.2?Z?3, when m1 is the mass of Sn4Ni3 phase, m2 is the mass of said Sn phase, and Z=ml /m2; and that the composite layer contain carbon material.

Abstract: The invention aims to suppress gas generation in a nonaqueous electrolytic cell having a negative electrode containing negative active material such as lithium titanate and particularly suppress swelling in a nonaqueous electrolytic cell by suppressing gas generation at the time of storage at a high temperature. The nonaqueous electrolytic cell comprises a nonaqueous electrolyte containing an electrolytic salt and a nonaqueous solvent, a positive electrode, and a negative electrode containing a negative electrode material into/from which lithium ions are inserted/extracted at a potential higher than the lithium potential by 1.2 V. The nonaqueous electrolytic cell is characterized in that the nonaqueous electrolyte contains vinylene carbonate, the negative electrode has a coat thereon, and the nonaqueous electrolytic cell is used in a range of negative electrode potential nobler than the lithium potential by 0.8 V.

Abstract: Gas generation of a non-aqueous electrolyte battery having a negative active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium as negative electrode is suppressed. A non-aqueous electrolyte battery comprising a non-aqueous electrolyte containing an electrolyte salt and a non-aqueous solvent, a positive electrode and a negative electrode is characterized in that the main active material of said negative electrode is an active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium and the auxiliary active material of said negative electrode is an active material that at least intercalates lithium ions at a potential lower than 1.

Abstract: A non-aqueous electrolyte battery suppresses gas generation in a non-aqueous electrolyte battery having a negative active material that intercalates and deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium for the negative electrode thereof. The non-aqueous electrolyte battery comprises a non-aqueous electrolyte containing an electrolytic salt and a non-aqueous solvent, a positive electrode and a negative electrode having a negative active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium and is characterized in that a film coat having a carbonate structure and a thickness of not less than 10 nm exists on the surface of said negative electrode and that the non-aqueous electrolyte battery is operated in a region of potential of the negative electrode higher than 0.8 V relative to the potential of lithium.

Abstract: It is an object of the present invention to provide a non-aqueous electrolyte secondary battery having high energy density and satisfactory cycle performance by using an alloy comprising Ni and Sn as a negative active material; and the non-aqueous electrolyte secondary battery comprising a negative electrode with a composite layer containing a negative active material, a positive electrode and a non-aqueous electrolyte is characterized in that said negative active material consists of an alloy containing 5 to 25 mass % of nickel and 75 to 95 mass % of tin, and that such alloy contains Sn4Ni3 phase and Sn phase. It is preferable that the content ratio of Sn4Ni3 phase and Sn phase in the above described alloy be 0.2?Z?3, supposing that ml is the mass of Sn4Ni3 phase, m2 is the mass of said Sn phase, and Z=m1/m2; and that the above described composite layer contain carbon material.