Abstract: Provided are a lithium secondary battery having improved initial capacity and excellent cycle property, an electrolyte solution for the lithium secondary battery, and an additive for the electrolyte solution for the lithium secondary battery. The lithium secondary battery includes positive and negative electrodes both having a lithium-ion intercalation/de-intercalation ability, and a non-aqueous electrolyte solution contacted with the positive and negative electrodes. The non-aqueous electrolyte solution contains lithium hexafluorophosphate and a boroxine compound represented by (RO)3(BO)3 liquefying at 25° C. R(s) each independently represent an organic group of a linear chain alkyl group having 3 or more carbon atoms. Herein, the chain alkyl group may have a branch, and when the branch is included, the number of carbon atoms of the chain alkyl group constructing a linear portion thereof is 3 or more.

Abstract: Provided are a cathode active material used for a lithium ion secondary battery capable of sufficiently realizing both high charge/discharge capacities and excellent cycle properties, and a lithium ion secondary battery using the cathode active material. The cathode active material contains a plurality of secondary particles formed via agglomeration of a plurality of primary particles of a lithium transition metal composite oxide. Spreading resistance distributions of the secondary particles respectively observed in cross-sections at optional three positions of the cathode active material are measured so as to afford average values of spreading resistance of the secondary particles in the respective cross-sections. The average values of spreading resistance of the secondary particles are further averaged. The resultant averaged value of spreading resistance is made to enter the range of 1.0×106 ?/cm or more and 1.0×1010 ?/cm or less.

Abstract: Provided is a method for producing a cathode active material used for a lithium secondary battery, via efficiently firing a nickel-containing precursor in a short time. The method includes the steps of mixing lithium carbonate with a compound other than Li, and firing the precursor obtained through the mixing step thereby to obtain a lithium composite compound. The firing step includes a heat treating substep of heat-treating a precursor rotating in a furnace tube (10) of a firing furnace (1). The firing furnace (1) includes a first gas feeding system that injects an oxidative gas, and a second gas feeding system that makes an oxidative gas flow in the axis direction of the furnace tube (10). The heat treating substep includes spraying an oxidative gas onto the precursor, and simultaneously exhausting a carbon dioxide gas generated from the precursor by a gas flow.

Abstract: Provided are a cathode active substance used for a lithium ion secondary battery capable of suppressing an increase in an internal resistance inside the battery caused following charge/discharge cycles, a cathode including the cathode active substance, and a lithium ion secondary battery provided with the cathode. The cathode active substance includes a lithium composite compound represented by Formula: Li1+?NixCoyM11-x-y-zM2zO2+?. When Pi is defined as porosity with respect to an opening diameter of 0.6 ?m or less and measured by subjecting the active substance to a mercury press-in method, and Pp is defined as porosity with respect to the same diameter and measured by filling the active substance in a mold with an inner diameter of 10 mm, pressing the filled substance by a load of 40 MPa, and subjecting the pressed substance to the same method, a value of Pp/Pi is 1.5 or less.

Abstract: Disclosed is an electrolyte solution used for a lithium secondary battery having high capacity, less undergoing aging deterioration of capacity, and also excellent in life characteristic. The electrolyte solution used for a lithium secondary battery contains a compound having a trivalent or higher boron formed by incorporation of a boroxine compound represented by (RO)3(BO)3 in which R(s) each represent independently an organic group of 1 to 6 carbon atoms and LiPF6, and a non-aqueous solvent.

Abstract: Provided are a non-aqueous electrolyte solution used for a lithium secondary battery etc. capable of decreasing aging deterioration of a discharge capacity, a cathode used for a lithium secondary battery, and a method for producing the same, as well as a storage device like a lithium secondary battery etc. To the non-aqueous electrolyte solution, added are POF2? or a salt thereof, and, PO2F2? or a salt thereof or PO3F2? or a salt thereof. Alternatively, added is a reaction product between a boroxine compound and lithium hexafluorophosphate. In the cathode, the average oxidation number of a transition metal present in a surface layer of a composite oxide is more than 4 in Mn, more than 3 in Co and more than 2 in Ni, respectively. Further, a boron-containing compound is present on a surface of the composite oxide.

Abstract: A current collector for a lithium ion secondary battery, on which an electrode mixture layer is formed, satisfies A?0.10 ?m and 6?(B/A)?15 when assuming that a three-dimensional center plane average roughness SRa of a surface of at least one side of the current collector on which the electrode mixture layer is formed is A and a ratio of an actual surface area of the surface of at least one side of the current collector to a geometric area of the surface of at least one side of the current collector, which is (actual surface area)/(geometric area), is B.

Abstract: There is provided a grommet with water-blocking performance improved by suppression of deformation of a rear end caused by deformation of a fastening fixing portion. The grommet includes: a rear band mounting portion 415 which fastens and fixes a portion displaced from the rear end and overlapping a corrugated tube 5 fitted in the grommet by using a band-shaped binding band 8; and a plurality of rear end-side annular protruding portion 411, first fixed-side annular protruding portion 412, and second fixed-side annular protruding portion 413 protruding from an inner peripheral face and extending in a circumferential direction and disposed along a front-rear direction X so as to be fitted with the corrugated tube 5 by use of protruding and recessed shapes.

Abstract: A positive-electrode material for a lithium ion secondary battery contains a lithium complex compound that is represented by the formula: Li1+aNibMncCodTieMfO2+?, and has an atomic ratio Ti3+/Ti4+ between Ti3+ and Ti4+, as determined through X-ray photoelectron spectroscopy, of greater than or equal to 1.5 and less than or equal to 20. In the formula, M is at least one element selected from the group consisting of Mg, Al, Zr, Mo, and Nb, and a, b, c, d, e, f, and ? are numbers satisfying ?0.1?a?0.2, 0.7<b?0.9, 0?c<0.3, 0?d<0.3, 0<e?0.25, 0?f<0.3, b+c+d+e+f=1, and ?0.2???0.2.

Abstract: The present invention relates to a method for predicting responsiveness to cancer drug therapy for colorectal cancer. More particularly, the present invention relates to a method for predicting the responsiveness of a colorectal cancer patient to cancer drug therapy, the method comprising analyzing the level of DNA methylation in a specimen comprising a colorectal cancer tissue, colorectal cancer cells, or colorectal cancer cell-derived DNA of a subject, and then determining the responsiveness of the subject to cancer drug therapy based on the level of DNA methylation.

Abstract: An object of the present invention is to provide lithium ion secondary batteries having cycle characteristics as well as high energy density and rate characteristics during high-potential charging of a layered compound. The following is provided, a positive electrode active material for lithium ion secondary batteries, comprising particles each having: a core part comprising a lithium metal composite oxide; and a surface layer part comprising a lithium metal composite oxide having a composition differing from that in the core part, the surface layer part being formed on the surface of the core part, wherein both the core part and the surface layer part have a layered structure, the surface layer part contains Ni, Mn, and Li, and Ni/Mn mole ratio in the surface is less than 1.

Abstract: Provided are a lithium secondary battery having improved initial capacity and excellent cycle property, an electrolyte solution for the lithium secondary battery, and an additive for the electrolyte solution for the lithium secondary battery. The lithium secondary battery includes positive and negative electrodes both having a lithium-ion intercalation/de-intercalation ability, and a non-aqueous electrolyte solution contacted with the positive and negative electrodes. The non-aqueous electrolyte solution contains lithium hexafluorophosphate and a boroxine compound represented by (RO)3(BO)3 liquefying at 25° C. R(s) each independently represent an organic group of a linear chain alkyl group having 3 or more carbon atoms. Herein, the chain alkyl group may have a branch, and when the branch is included, the number of carbon atoms of the chain alkyl group constructing a linear portion thereof is 3 or more.

Abstract: Provided is a method for manufacturing a cathode electrode material, including the step of performing calcination of a mixture of lithium carbonate and a compound containing Ni, and capable of mass-producing a cathode electrode material including a lithium composite oxide with high Ni concentration industrially. The manufacturing method includes a mixture step of mixing lithium carbonate and a compound including Ni, and a calcination step of performing calcination of a mixture obtained in the mixture step under oxidizing atmosphere to obtain a lithium composite compound with high Ni concentration. The calcination step includes: a first heat treatment step to obtain a first precursor; a second heat treatment step of performing heat treatment of the first precursor to obtain a second precursor; and a third heat treatment step of performing heat treatment of the second precursor to obtain the lithium composite compound.

Abstract: A compound having a layered structure that is used for a positive electrode active material for a lithium ion secondary battery achieves both a high energy density and a high cyclability. The positive electrode active material for a lithium ion secondary battery contains a compound having a layered structure belonging to a space group R-3m, in which the compound having a layered structure is represented by a compositional formula: Li1+aM1O2+?wherein M1 represents a metal element or metal elements other than Li, and contains at least Ni, ?0.03?a?0.10, and ?0.1<?<0.1, a proportion of Ni in M1 is larger than 70 atom %, and a site occupancy of a transition metal or transition metals at a 3a site obtained by structural analysis by a Rietveld method is less than 2%, and a content of residual lithium hydroxide in the positive electrode active material is 1 mass % or less.

Abstract: A positive electrode active material includes a primary particle represented by Compositional Formula (1): Li1+xNiyCozM1?x?y?zO2 (1), where x is a number satisfying a relation represented by an expression ?0.12?x?0.2; y is a number satisfying a relation represented by an expression 0.7?y?0.9; z is a number satisfying a relation represented by an expression 0.05?z?0.3; and M is at least one element selected from the group consisting of Mg, Al, Ti, Mn, Zr, Mo, and Nb; or a secondary particle into which the primary particle aggregates. The primary particle or the secondary particle includes a free lithium compound in a weight proportion of 0.1% or more and 2.0% or less, and the weight of lithium hydroxide in the free lithium compound is 60% or less of the weight of lithium carbonate in the free lithium compound.

Abstract: A current collector for a lithium ion secondary battery, on which an electrode mixture layer is formed, satisfies A?0.10 ?m and 6?(B/A)?15 when assuming that a three-dimensional center plane average roughness SRa of a surface of at least one side of the current collector on which the electrode mixture layer is formed is A and a ratio of an actual surface area of the surface of at least one side of the current collector to a geometric area of the surface of at least one side of the current collector, which is (actual surface area)/(geometric area), is B.

Abstract: A positive electrode active material for a non-aqueous secondary battery having high capacity and high rate characteristics is intended to be provided. Further, a positive electrode for a non-aqueous secondary battery and a non-aqueous secondary battery are intended to be provided by using the positive electrode active material. The positive electrode active material for the non-aqueous secondary battery contains a lithium composite oxide having an olivine structure represented by the chemical formula: Li1+AMnXM1?X(PO4)1+B in which A>0, B>0, M represents a metal element, M in the chemical formula is one or more metal elements selected from Fe, Ni, Co, Ti, Cu, Zn, Mg, V, and Zr, the ratio A/B in the chemical formula is within a range of: 2<A/B?7, and the value of X is within a range of: 0.3?X<1.

Abstract: Provided is a positive electrode active material for lithium secondary batteries, which uses a highly safe polyanion compound and has high capacity, high rate characteristics and high energy density. A positive electrode active material for lithium secondary batteries, which contains polyanion compound particles coated with carbon. This positive electrode active material for lithium secondary batteries is characterized in that: the polyanion compound has a structure represented by chemical formula (1); the roughness factor of the polyanion compound, said roughness factor being represented by formula (1), is 1-2; and the average primary particle diameter of the polyanion compound is 10-150 nm. LixMAyOz (chemical formula (1)) (In chemical formula (1), M comprises at least one transition metal element; A represents a typical element that combines with oxygen (O) and forms an anion; 0<x?2, 1?y?2 and 3?z?7.

Abstract: A cathode for a lithium-ion secondary battery is provided, which not only efficiently absorbs oxygen released from a solid solution based cathode active material when initial charging is applied but prevents a cathode energy density from lowering. Further, a lithium-ion secondary battery, a vehicle and a power storage system equipped with the lithium-ion secondary battery are provided. The cathode for a lithium-ion secondary battery comprises a cathode active material represented by the general formula: xLi2MO3-(1?x)LiM?O2 (where 0<x<1; M is at least one element selected from the group of Mn, Ti and Zr; and M? is at least one element selected from the group of Ni, Co, Mn, Fe, Ti, Zr, Al, Mg, Cr and V), and an oxygen absorbing substance having both oxygen absorbing and lithium-ion intercalation/de-intercalation abilities. Herein, the oxygen absorbing substance is disposed on the cathode active material.

Abstract: Disclosed is an electrolyte solution used for a lithium secondary battery having high capacity, less undergoing aging deterioration of capacity, and also excellent in life characteristic. The electrolyte solution used for a lithium secondary battery contains a compound having a trivalent or higher boron formed by incorporation of a boroxine compound represented by (RO)3(BO)3 in which R(s) each represent independently an organic group of 1 to 6 carbon atoms and LiPF6, and a non-aqueous solvent.