Abstract: An organic-inorganic hybrid resin is formed by reacting a polyol organic resin with a polysilsesquioxane polymer. The organic-inorganic hybrid resin has T0, T1, T2, and T3 signals of 29Si-NMR, wherein a ratio of the sum of 3 times the integral value of T0 signal and 2 times the integral value of T1 signal and the integral value of T2 signal and the integral value of T3 signal ((3T0+2T1+T2)/T3) is from 0.3 to 1.2, wherein the T0 signal range is 35 ppm to 40 ppm, the T1 signal range is 48 ppm to 53 ppm, the T2 signal range is 55 ppm to 62 ppm, and the T3 signal range is 63 ppm to 72 ppm.

Abstract: An organic-inorganic hybrid resin is formed by reacting a polyol organic resin with a polysilsesquioxane polymer. The organic-inorganic hybrid resin has T0, T1, T2, and T3 signals of 29Si-NMR, wherein a ratio of the sum of 3 times the integral value of T0 signal and 2 times the integral value of T1 signal and the integral value of T2 signal and the integral value of T3 signal ((3T0+2T1+T2)/T3) is from 0.3 to 1.2, wherein the T0 signal range is 35 ppm to 40 ppm, the T1 signal range is 48 ppm to 53 ppm, the T2 signal range is 55 ppm to 62 ppm, and the T3 signal range is 63 ppm to 72 ppm.

Abstract: A method of forming a thermal insulation porous film includes mixing 100 parts by weight of polysilsesquioxane-containing polymer, 20 to 75 parts by weight of surfactant, and 20 to 2000 parts by weight of solvent to form a thermal insulation coating material, wherein the polysilsesquioxane-containing polymer in the thermal insulation coating material is tube-shaped or sheet-shaped. The thermal insulation coating material is coated on a substrate, and then dried and sintered to form a thermal insulation porous film.

Abstract: A method of forming a thermal insulation porous film includes mixing 100 parts by weight of polysilsesquioxane-containing polymer, 20 to 75 parts by weight of surfactant, and 20 to 2000 parts by weight of solvent to form a thermal insulation coating material, wherein the polysilsesquioxane-containing polymer in the thermal insulation coating material is tube-shaped or sheet-shaped. The thermal insulation coating material is coated on a substrate, and then dried and sintered to form a thermal insulation porous film.

Abstract: A method of forming a thermal insulation porous film includes mixing 100 parts by weight of polysilsesquioxane-containing polymer, 20 to 75 parts by weight of surfactant, and 20 to 2000 parts by weight of solvent to form a thermal insulation coating material, wherein the polysilsesquioxane-containing polymer in the thermal insulation coating material is tube-shaped or sheet-shaped. The thermal insulation coating material is coated on a substrate, and then dried and sintered to form a thermal insulation porous film.

Abstract: The embodiments of the present disclosure provide a coating composition, including: polysilsesquioxane polymer modified organic resin represented by Formula (1): Wherein, R1 is C3-12 epoxy group, C3-12 acrylate group, C3-12 alkylacryloxy group, C3-12 aminoalkyl group, C3-12 isocyanate-alkyl group, C3-12 alkylcarboxylic acid group, C3-12 alkyl halide group, C3-12 mercaptoalkyl group, C3-12 alkyl group, or C3-12 alkenyl group; R2 is half oxygen(O1/2), hydroxyl group, C1-8 alkyl group, or C1-8 alkoxy group; R3 is halide group, C1-8 alkyl halide group, C1-8 alkoxy group, C1-12 alkyl group, or C5-20 aromatic ring; R4 is hydrogen or C1-8 alkyl group; R5 is modified or unmodified carbonyl compound moiety; n is a positive integer from 1 to 200; m is a positive integer from 10 to 500, and s is an integer from 0 to 250.

Abstract: An aqueous coating material is provided. The aqueous coating material includes an aqueous resin and a surfactant. The surfactant having a hydrophilic segment of poly(alkylene glycol), a hydrophobic segment of siloxane, and a terminal hydrophilic group. The aqueous resin and the surfactant may have a weight ratio of 100:1 to 100:25.

Abstract: An aqueous coating material is provided. The aqueous coating material includes an aqueous resin and a surfactant. The surfactant having a hydrophilic segment of poly(alkylene glycol), a hydrophobic segment of siloxane, and a terminal hydrophilic group. The aqueous resin and the surfactant may have a weight ratio of 100:1 to 100:25.

Abstract: A method of forming a thermal insulation porous film includes mixing 100 parts by weight of polysilsesquioxane-containing polymer, 20 to 75 parts by weight of surfactant, and 20 to 2000 parts by weight of solvent to form a thermal insulation coating material, wherein the polysilsesquioxane-containing polymer in the thermal insulation coating material is tube-shaped or sheet-shaped. The thermal insulation coating material is coated on a substrate, and then dried and sintered to form a thermal insulation porous film.

Abstract: The embodiments of the present disclosure provide a coating composition, including: polysilsesquioxane polymer modified organic resin represented by Formula (1): Wherein, R1 is C3-12 epoxy group, C3-12 acrylate group, C3-12 alkylacryloxy group, C3-12 aminoalkyl group, C3-12 isocyanate-alkyl group, C3-12 alkylcarboxylic acid group, C3-12 alkyl halide group, C3-12 mercaptoalkyl group, C3-12 alkyl group, or C3-12 alkenyl group; R2 is half oxygen(O1/2), hydroxyl group, C1-8 alkyl group, or C1-8 alkoxy group; R3 is halide group, C1-8 alkyl halide group, C1-8 alkoxy group, C1-12 alkyl group, or C5-20 aromatic ring; R4 is hydrogen or C1-8 alkyl group; R5 is modified or unmodified carbonyl compound moiety; n is a positive integer from 1 to 200; m is a positive integer from 10 to 500, and s is an integer from 0 to 250.

Abstract: The disclosure provides a coating composition, a film made of the coating composition, and method for preparing the coating composition. The coating composition includes a product prepared from cross-linking a (a) polysilsesquioxane with a (b) compound with the structure represented by Formula (I): wherein R is independently a hydroxyl group, or C1-8 alkoxy group, R1 is a C3-12 epoxy group, C3-12 acrylate group, C3-12 alkylacryloxy group, C3-12 aminoalkyl group, C3-12 isocyanate-alkyl group, C3-12 alkylcarboxylic acid group, C3-12 alkyl halide group, C3-12 mercaptoalkyl group, C3-12 alkyl group, or C3-12 alkenyl group, and R2 is a hydroxyl group, C1-8 alkyl group, or C1-8 alkoxy group.

Abstract: The disclosure provides a coating composition, a film made of the coating composition, and method for preparing the coating composition. The coating composition includes a product prepared from cross-linking a (a) polysilsesquioxane with a (b) compound with the structure represented by Formula (I): wherein R is independently a hydroxyl group, or C1-8 alkoxy group, R1 is a C3-12 epoxy group, C3-12 acrylate group, C3-12 alkylacryloxy group, C3-12 aminoalkyl group, C3-12 isocyanate-alkyl group, C3-12 alkylcarboxylic acid group, C3-12 alkyl halide group, C3-12 mercaptoalkyl group, C3-12 alkyl group, or C3-12 alkenyl group, and R2 is a hydroxyl group, C1-8 alkyl group, or C1-8 alkoxy group.