Abstract: A gas barrier material comprising a polycarboxylic acid polymer, and containing 0.10 to 1.4% by weight of a monovalent metal element, at least not less than 5.0% by weight of a polyvalent metal element, and 0.01 to 3.0% by weight of a nitrogen element per the total weight of nitrogen and carbon. The gas barrier material exhibits excellent gas barrier property, excellent waterproof property after the bend working and excellent appearance on the surface of the coating.

Abstract: A gas barrier laminate (10) having a very thin metal oxide film (ALD film) (5) formed on an inorganic oxide layer (3) by an atomic layer deposition method, the inorganic oxide layer (3) including a metal oxide or a metal oxynitride that contains at least either Si or Al, and a ratio (d1/d2) of a thickness (d1) of the inorganic oxide layer (3) and a thickness (d2) of the ALD film (5) being 3 to 50. The gas barrier laminate features not only a high degree of gas-barrier property but also excellent productivity.

Abstract: To provide a coating composition for undercoating which, in forming a gas-barrier layer having a crosslinked structure between a polycarboxylic acid type polymer and polyvalent metal ions by the heating at a low temperature for a short period of time, permits polyvalent metal ions to be easily and quickly fed into the polycarboxylic acid type polymer and, besides, into the whole gas-barrier layer. A coating composition containing, as chief components, a nonaqueous polyester polyol, an isocyanate compound, and an alkaline compound of a polyvalent metal that serves as an ion source for forming the crosslinked structure, wherein the nonaqueous polyester polyol contains a nonaqueous polyester polyol which contains a metal element in the resin skeleton thereof as an essential component, and the alkaline compound of the polyvalent metal has an average primary particle size in a range of 0.005 to 0.5 ?m.

Abstract: A gas-barrier laminate (10) of a structure in which a first inorganic barrier layer (3), a water-trapping layer (5) and a second inorganic barrier layer (9) are provided in this order on a plastic base material (1), wherein the water-trapping layer (5) is a layer in which a granular moisture-absorbing agent is dispersed in a matrix of an ionic polymer, the granular moisture-absorbing agent being capable of absorbing moisture to a degree lower than that attained by the matrix, and an organic layer (7) is provided between the water-trapping layer (5) and the second inorganic barrier layer (9), the organic layer (7) serving as an underlying layer for forming the second inorganic barrier layer. The water-trapping layer has excellent barrier property against water and is, at the same time, effectively suppressed from swelling despite it has absorbed moisture. The water-trapping layer is, further, effectively suppressed from losing its activity.

Abstract: A gas barrier laminate 10 having an inorganic barrier layer 3 and a water-trapping layer 5 that are formed on a plastic base material 1, the water-trapping layer 5 including a matrix of a cationic polymer (a) in which is distributed a hygroscopic agent (b) having such a hygroscopic property as to attain a humidity lower than a humidity that can be attained by using the matrix. The gas barrier laminate exhibits super barrier property against water despite of a structure of a small number of layers.

Abstract: A gas barrier laminate having an undercoating (A) which comprises a main resin, an isocyanate type curing agent and an alkaline compound of a polyvalent metal; and a barrier layer (B) of a polycarboxylic acid polymer forming an ionic crosslinking due to the polyvalent metal among the carboxyl groups; formed on at least one surface of a plastic base material (P), wherein a region (b) free of the alkaline compound of the polyvalent metal is formed in the undercoating (A) on the side of the barrier layer (B), the content of nitrogen in the region (b) being larger than the content of nitrogen in the undercoating (A) other than the region (b), the gas barrier laminate having excellent gas barrier property, retort resistance, producibility as well as excellent flexibility without developing interlayer peeling even if it is folded and featuring excellent interlayer adhesion.

Abstract: A gas barrier material comprising a polycarboxylic acid polymer, and containing 0.10 to 1.4% by weight of a monovalent metal element, at least not less than 5.0% by weight of a polyvalent metal element, and 0.01 to 3.0% by weight of a nitrogen element per the total weight of nitrogen and carbon. The gas barrier material exhibits excellent gas barrier property, excellent waterproof property after the bend working and excellent appearance on the surface of the coating.

Abstract: To provide a gas barrier laminate having a gas barrier layer obtained by crosslinking the carboxyl groups of a polycarboxylic acid-type polymer with polyvalent metal ions maintaining good productivity, the crosslinking being accelerated with polyvalent metal ions to exhibit more excellent gas barrier property. A gas barrier laminate comprising a layer (A) of a non-aqueous resin containing a metal element in the polymer skeleton thereof, and a layer (B) of a polycarboxylic acid-type polymer in which an ionic crosslinking is formed with a polyvalent metal among the carboxyl groups.

Abstract: A gas barrier laminate having an undercoating (A) which comprises a main resin, an isocyanate type curing agent and an alkaline compound of a polyvalent metal; and a barrier layer (B) of a polycarboxylic acid polymer forming an ionic crosslinking due to the polyvalent metal among the carboxyl groups; formed on at least one surface of a plastic base material (P), wherein a region (b) free of the alkaline compound of the polyvalent metal is formed in the undercoating (A) on the side of the barrier layer (B), the content of nitrogen in the region (b) being larger than the content of nitrogen in the undercoating (A) other than the region (b), the gas barrier laminate having excellent gas barrier property, retort resistance, producibility as well as excellent flexibility without developing interlayer peeling even if it is folded and featuring excellent interlayer adhesion.

Abstract: To provide a coating composition for undercoating which, in forming a gas-barrier layer having a crosslinked structure between a polycarboxylic acid type polymer and polyvalent metal ions by the heating at a low temperature for a short period of time, permits polyvalent metal ions to be easily and quickly fed into the polycarboxylic acid type polymer and, besides, into the whole gas-barrier layer. A coating composition containing, as chief components, a nonaqueous polyester polyol, an isocyanate compound, and an alkaline compound of a polyvalent metal that serves as an ion source for forming the crosslinked structure, wherein the nonaqueous polyester polyol contains a nonaqueous polyester polyol which contains a metal element in the resin skeleton thereof as an essential component, and the alkaline compound of the polyvalent metal has an average primary particle size in a range of 0.005 to 0.5 ?m.

Abstract: To provide a gas barrier laminate having a gas barrier layer obtained by crosslinking the carboxyl groups of a polycarboxylic acid-type polymer with polyvalent metal ions maintaining good productivity, the crosslinking being accelerated with polyvalent metal ions to exhibit more excellent gas barrier property. A gas barrier laminate comprising a layer (A) of a non-aqueous resin containing a metal element in the polymer skeleton thereof, and a layer (B) of a polycarboxylic acid-type polymer in which an ionic crosslinking is formed with a polyvalent metal among the carboxyl groups.