Abstract: A method and system are provided for creating a mercury halide standard, and for using that standard to test a mercury analyzer system. Gaseous elemental mercury of a known concentration from a gas cylinder and a halogen donor are fed to a reaction chamber where they react to form mercury halide. The mercury halide is fed to a mercury analyzer system where it is converted to reform gaseous elemental mercury which is then measured by a mercury analyzer. By comparing either the amount of elemental mercury supplied to the reaction chamber or the amount of mercury halide formed in the reaction chamber with the amount of elemental mercury converted from the mercury halide, the ability of the mercury analyzer system to convert mercury halide to gaseous elemental mercury can be evaluated.

Abstract: A method and apparatus for providing output emission data corresponding to output emissions from a source of emissions includes a sensing emission monitoring system that senses the output emissions directly from the source of emissions and a predictive emission monitoring system that predicts the output emissions from the source of emissions. The sensing emission monitoring system provides a first set of output values indicative of the output emissions, while the predictive emission monitoring system provides a second set of output values indicative of the output emissions. The system checks the operating state of the sensing emission monitoring system and generates output emission data from the first set of output values if the sensing emission monitoring system is operable and from the second set of the output values if the sensing emission monitoring system is inoperable.