Abstract: Provided herein are polyolefin-based compositions useful for making rotomolded parts having useful properties, including those related to impact resistance and color. In one aspect, there are provided compositions comprising (a) a rotational molded polyolefin, comprising a resin, wherein the resin is polyethylene or a copolymer thereof, having a melt index (MI) ranging from about 1 g/10 minutes to about 10 g/10 minutes; and (b) an additive package comprising: (i) an antioxidant; (ii) a processing stabilizer; (iii) optionally a UV light stabilizer; (iv) optionally a fatty acid-based acid scavenger comprising a metal salt of a fatty acid; and (v) a dihydrotalcite-based acid scavenger present in the composition at between about 800 ppm to about 3,000 ppm. In some embodiments, the ARM Impact Percent Ductility is greater than or equal to about 60% for a molded part made from the cured composition and measured after the composition has been cured between 18-24 minutes at a temperature of 550° F.

Abstract: The present disclosure relates to pipes comprising bimodal high molecular weight high density polyethylene which has been extruded in the presence of one or more organic peroxides that are present in an amount ranging from 30 ppm to 200 ppm. The pipe has an improved long-term hydrostatic strength. Also provided are methods for preparing pipes having these characteristics.

Abstract: Provided herein are polyolefin-based compositions useful for making rotomolded parts having useful properties, including those related to impact resistance and color. In one aspect, there are provided compositions comprising (a) a rotational molded polyolefin, comprising a resin, wherein the resin is polyethylene or a copolymer thereof, having a melt index (MI) ranging from about 1 g/10 minutes to about 10 g/10 minutes; and (b) an additive package comprising: (i) an antioxidant; (ii) a processing stabilizer; (iii) optionally a UV light stabilizer; (iv) optionally a fatty acid-based acid scavenger comprising a metal salt of a fatty acid; and (v) a dihydrotalcite-based acid scavenger present in the composition at between about 800 ppm to about 3,000 ppm. In some embodiments, the ARM Impact Percent Ductility is greater than or equal to about 60% for a molded part made from the cured composition and measured after the composition has been cured between 18-24 minutes at a temperature of 550° F.

Abstract: The present disclosure relates to pipes comprising bimodal high molecular weight high density polyethylene which has been extruded in the presence of one or more organic peroxides that are present in an amount ranging from 30 ppm to 200 ppm. The pipe has an improved long-term hydrostatic strength. Also provided are methods for preparing pipes having these characteristics.

Abstract: A coated or jacketed wire or cable, and components thereof are disclosed. The coating, jacket, and components, which comprise a polyolefin and a phenolic polymeric antioxidant, exhibit outstanding oxidative thermal stability (as indicated by the increase in the oxidative inductive time (OIT)), when compared to polyolefins containing traditional non-polymeric antioxidants. A greater improvement in the thermal oxidative stability is observed after the polyolefin mixtures have been aged in water-blocking filler(s).

Abstract: A coated or jacketed wire or cable, and components thereof are disclosed. The coating, jacket, and components, which comprise a polyolefin and a phenolic polymeric antioxidant, exhibit outstanding oxidative thermal stability (as indicated by the increase in the oxidative inductive time (OIT)), when compared to polyolefins containing traditional non-polymeric antioxidants. A greater improvement in the thermal oxidative stability is observed after the polyolefin mixtures have been aged in water-blocking filler(s).

Abstract: Moisture curable flame retardant insulation compositions for wire and cable having improved adhesion are provided. The compositions are comprised of an ethylene-silane copolymer, high density polyethylene resin, halogenated flame retardant, silanol condensation catalyst and stabilizer combination consisting of a zinc mercaptobenzimidazole and aromatic secondary amine.

Abstract: Moisture curable flame retardant wire and cable formulations having improved abrasion resistance are provided. The compositions are comprised of a high density silane-containing polyethylene base resin which can be a blend of a bimodal HDPE and ethylene-silane copolymer or silane-grafted bimodal HDPE in combination with a flame retardant and silanol condensation catalyst.

Abstract: An insulating composition for electrical conductors that is composed essentially of an ethylene-vinyl acetate copolymer, a zinc salt, aluminum trihydrate, and a peroxide curing agent is surprisingly found to have excellent long-term thermal stability with fast cure.

Abstract: An electrical conductive assembly including an electrical conductor and an annular laminate insulator surrounding the electrical conductor. The annular laminate insulator includes an inner ply of a first polymeric composition and an outer ply of a second polymeric composition wherein the outer ply second polymeric composition has a hardness in excess of the inner ply first polymeric composition and wherein the abrasion resistance of the laminate is in excess of the combined individual abrasion resistance of the inner ply and outer plies. The annular laminate is flame retardant and stabilized against thermal oxidation by the inclusion of a flame retardant and a thermal antioxidant. The polymers of the first and second polymeric compositions are thermosetting resins, crystalline thermoplastics having a melting point of at least about 130° C. or amorphous thermoplastics having a glass transition temperature of at least about 130° C.

Abstract: Compositions useful for coating wire and cable to provide a radiation curable insulation layer are provided. The improved compositions of the invention, when cured, have a balance of properties making them suitable for automotive and appliance wire applications. The compositions are comprised of an ethylene copolymer, a hydrated inorganic filler, an alkoxysilane and a zinc salt of a mercaptobenzimidazole compound.

Abstract: Flame retardant and abrasion resistant crosslinkable compositions useful as insulation for wire and cable are provided. The compositions contain an ethylene-vinyl acetate copolymer having a vinyl ester content of 5 to 12 wt. %, a halogenated compound, antimony trioxide and an organic peroxide. Use of specific halogenated compounds, particularly brominated aromatic compounds, with low vinyl acetate content ethylene-vinyl acetate copolymers yield products which are highly resistant to abrasion after crosslinking.

Abstract: The present invention relates to flame retardant insulation and jacketing compositions useful for wire and cable products which exhibit improved adhesion to the metal conductor. This is achieved by the use of a specific stabilizer package comprised of three specific antioxidants and by varying their relative proportions. The compositions are based on ethylene-vinyl esters and ethylene-alkyl acrylate copolymers and are formulated with a hydrated inorganic filler, an alkoxy silane, a crosslinking agent and the three-component stabilizer package. Antioxidants utilized for the three-component stabilizer package include tetrakis[methylene(3,5-di-tert-butyl-4-hydroxyhydrocinnamate)]methane, pentaerythritol tetrakis(betalaurylthiopropionate) and thiodiethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate).