Abstract: A curable film-forming composition is provided, comprising: (a) a polymeric binder comprising reactive functional groups; (b) a curing agent comprising functional groups that are reactive with the reactive functional groups of (a); and (c) a polysiloxane resin comprising aromatic functional groups and terminal active hydrogen groups. In certain examples of the present invention, the polymeric binder (a) comprises an acrylic polyol prepared from a monomer mixture comprising a hydroxyl functional monomer, and the curable film-forming composition further comprises a rheology modifier comprising: (1) a non-aqueous dispersion of an internally crosslinked organic polymer; (2) a silica dispersion; and/or (3) a reaction product of an amine and an isocyanate. Also provided are coated substrates that include the curable film-forming compositions described above and methods for forming a composite coating on a substrate.

Abstract: A curable composition is provided, comprising: (A) a binder composition; and (B) a polysiloxane resin comprising aromatic functional groups and terminal active hydrogen groups. The composition may be used to prepare articles of manufacture and coated articles, such as footwear components. The composition may additionally be used to mitigate dirt build-up on a substrate.

Abstract: The present invention is directed to compounds that generate nitrogen gas and enhance char formation upon combustion and to intumescent coating compositions containing them. The compounds of the present invention typically comprise a reaction product of: (i) a nitrogen-containing compound; and (ii) a siloxane-containing compound. The nitrogen-containing compound (i) and the siloxane-containing compound (ii) are covalently bonded directly to each other.

Abstract: A curable film-forming composition is provided, comprising: (a) a polymeric binder comprising reactive functional groups; (b) a curing agent comprising functional groups that are reactive with the reactive functional groups of (a); and (c) a polysiloxane resin comprising aromatic functional groups and terminal active hydrogen groups. In certain examples of the present invention, the polymeric binder (a) comprises an acrylic polyol prepared from a monomer mixture comprising a hydroxyl functional monomer, and the curable film-forming composition further comprises a rheology modifier comprising: (1) a non-aqueous dispersion of an internally crosslinked organic polymer; (2) a silica dispersion; and/or (3) a reaction product of an amine and an isocyanate. Also provided are coated substrates that include the curable film-forming compositions described above and methods for forming a composite coating on a substrate.

Abstract: A curable composition is provided, comprising: (A) a binder composition; and (B) a polysiloxane resin comprising aromatic functional groups and terminal active hydrogen groups. The composition may be used to prepare articles of manufacture and coated articles, such as footwear components. The composition may additionally be used to mitigate dirt build-up on a substrate.

Abstract: Rubber replacement articles prepared from curable compositions are provided. The curable compositions comprise: (a) an isocyanate-functional prepolymer; (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250; and (c) an abrasion resistant additive comprising organic particles demonstrating a volume average particle size of at least 5 microns. The isocyanate-functional prepolymer is (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol.

Abstract: Curable compositions are provided comprising: (a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000; (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250; and (c) an abrasion resistant additive comprising organic and inorganic particles. The isocyanate-functional prepolymer is (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol. Upon application of the composition to a substrate as a coating and after curing to form a coated substrate, the coated substrate demonstrates a coating loss of less than 0.33 cm3 after being subjected to 1000 cycles of a TABER Abrasion Test using S-42 sandpaper strips and two 1000 gram weights. Coated substrates and footwear components prepared from the compositions are also disclosed.

Abstract: Curable compositions are provided comprising: (a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000; (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250; and (c) an abrasion resistant additive comprising organic and inorganic particles. The isocyanate-functional prepolymer is (i) a reaction product of a polyisocyanate and a polyamine having primary and/or secondary amino groups; and/or (ii) a reaction product of a polyisocyanate and a polyol. Upon application of the composition to a substrate as a coating and after curing to form a coated substrate, the coated substrate demonstrates a coating loss of less than 0.33 cm3 after being subjected to 1000 cycles of a TABER Abrasion Test using S-42 sandpaper strips and two 1000 gram weights. Coated substrates and footwear components prepared from the compositions are also disclosed.

Abstract: Curable compositions are provided comprising: (a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000; and (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250. The isocyanate-functional prepolymer is a reaction product of a polyisocyanate and either (i) a polyether having primary and/or secondary amino groups or (ii) a mixture of a polyether having primary and/or secondary amino groups and a polyether having hydroxyl groups. Upon curing, the compositions demonstrate a Young's Modulus less than 500 MPa at ?40° C., a percent elongation greater than 200% at ?40° C., and/or a glass transition temperature less than ?20° C., making them ideally suited for use at extreme temperatures.

Abstract: Curable compositions are provided comprising: (a) an isocyanate-functional prepolymer having a weight average molecular weight of 4000 to 15,000; and (b) a curing agent comprising a mixture of polyamines, wherein at least one polyamine has an amine equivalent weight of 125 to 250. The isocyanate-functional prepolymer is a reaction product of a polyisocyanate and either (i) a polyether having primary and/or secondary amino groups or (ii) a mixture of a polyether having primary and/or secondary amino groups and a polyether having hydroxyl groups. Upon curing, the compositions demonstrate a Young's Modulus less than 500 MPa at ?40° C., a percent elongation greater than 200% at ?40° C., and/or a glass transition temperature less than ?20° C., making them ideally suited for use at extreme temperatures.