Patents by Inventor Susumu Higashida

Susumu Higashida has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5629406
    Abstract: Compounds of formula (I): ##STR1## wherein: R.sup.1 is hydrogen, alkyl, aralkyl, --COR.sup.a, --COR.sup.b, --CSR.sup.a, --CSR.sup.b, --SO.sub.2 R.sup.b, --CONHR.sup.b, --CSNHR.sup.b, --CONR.sup.b R.sup.b or --CSNR.sup.b R.sup.b ; R.sup.2 is hydrogen or alkyl; R.sup.3 is hydrogen, alkylidene, substituted alkyl, or R.sup.b ; R.sup.4 is optionally substituted alkyl, cycloalkyl, or aryl; R.sup.5 is R.sup.b O--, R.sup.b R.sup.b N--, R.sup.b HN--, aralkyloxycarbonyloxy or aralkyloxycarbonylamino, or R.sup.5 is --(CH.sub.2).sub.p --D--(CH.sub.2).sub.r --, where D is a single bond, carbonyl, oxygen, sulfur, --NH--, --(CH.sub.2 .dbd.CH.sub.2)-- or --NHCO--; and p and r are each 0 or an integer from 1 to 5; A is --(CH.sub.2).sub.m --B--(CH.sub.2).sub.n -- where B is a single bond, carbonyl, oxygen, sulfur, --NH--, --(CH.sub.2 .dbd.CH.sub.2)-- or --NHCO--; and m and n are each 0 or an integer from 1 to 5; R.sup.a is alkoxy, aralkyloxy, aryloxy or alkoxycarbonyl; R.sup.
    Type: Grant
    Filed: April 14, 1994
    Date of Patent: May 13, 1997
    Assignee: Sankyo Company, Limited
    Inventors: Susumu Higashida, Mitsuya Sakurai, Yuichiro Yabe, Takashi Nishigaki, Tomoaki Komai, Hiroshi Handa
  • Patent number: 4241208
    Abstract: Piperidine derivatives having the formula ##STR1## wherein R' represents an alkyl, an acyl, an alkoxycarbonyl, an amino or nitroso group;X represents oxygen or sulfur;Y represents oxygen, sulfur or a group of the formula .dbd.N--R" in which R" is hydrogen or alkyl;Z represents oxygen or a group of the formula >N--R'" in which R'" is hydrogen or alkyl;n is an integer of 1 to 4; andR represents, when n is 1, alkyl, aryl, cycloalkyl, alkoxycarbonyl, substituted phosphino or substituted phosphinyl, when n is 2, alkylene, alkenylene, arylene, aralkylene; alkylenediphenylene, bis-(alkoxycarbonyl) alkylene, alkylene-bis-(oxycarbonylalkyl), dialkylene ether or diphenylene ether, when n is 3, alkanetriyl,tris-(alkoxycarbonyl)alkanetriyl, alkanetriyl-tris-(oxycarbonylalkyl) or a group of the formula ##STR2## in which p is an integer of 1 through 8 inclusive, and, when n is 4, alkanetetrayl,tetrakis-(alkoxycarbonyl) alkanetetrayl or alkanetetrayl-tetrakis-(oxycarbonylalkyl).
    Type: Grant
    Filed: December 12, 1978
    Date of Patent: December 23, 1980
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Ohsawa
  • Patent number: 4212974
    Abstract: A novel piperidine derivative having a stabilizing effect on a synthetic polymeric material and a composition comprising said piperidine derivative and a synthetic polymeric material.
    Type: Grant
    Filed: July 14, 1978
    Date of Patent: July 15, 1980
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Osawa
  • Patent number: 4125533
    Abstract: A novel piperidine derivative having a stabilizing effect on a synthetic polymeric material and a composition comprising said piperidine derivative and a synthetic polymeric material.
    Type: Grant
    Filed: December 23, 1976
    Date of Patent: November 14, 1978
    Assignee: Sankyo Co. Ltd.
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Osawa
  • Patent number: 4066615
    Abstract: A synthetic polymer composition stabilized against photo- and thermal-deterioration comprising a stabilizing amount of a compound having the formula ##STR1## wherein R' represents an alkyl, an acyl, an alkoxycarbonyl, an amino or nitroso group;X represents oxygen or sulfur;Y represents oxygen, sulfur or a group of the formula = N - R" in which R" is hydrogen or alkyl;Z represents oxygen or a group of the formula >N - R'" in which R'" is hydrogen or alkyl;N is an integer of 1 to 4; andR represents, when n is 1, alkyl, aryl, cycloalkyl, alkoxycarbonyl, substituted phosphino or substituted phosphinyl, when n is 2, alkylene, alkenylene, arylene, aralkylene; alkylenediphenylene, bis-(carboxycarbonyl) alkylene, alkylene-bis-(oxycarbonylalkyl), dialkylene ether or diphenylene ether, when n is 3, alkanetriyl, tris-(alkoxycarbonyl)alkanetriyl, alkanetriyl-tris-(oxycarbonylalkyl) or a group of the formula ##STR2## in which p is an integer of 1 through 8 inclusive, and, when n is 4, alkanetetrayl,tetrakis-(alkoxycarb
    Type: Grant
    Filed: April 11, 1975
    Date of Patent: January 3, 1978
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Ohsawa
  • Patent number: 4016168
    Abstract: A novel piperidine derivative having a stabilizing effect on a synthetic polymeric material and a composition comprising said piperidine derivative and a synthetic polymeric material.
    Type: Grant
    Filed: February 26, 1975
    Date of Patent: April 5, 1977
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Osawa
  • Patent number: 4007158
    Abstract: Novel piperidine derivatives of formula: ##STR1## (wherein 2 or 3 of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent alkyl groups having from 1 to 4 carbon atoms and the remainder of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen atoms, and R.sub.6 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, a substituted alkyl group, an aliphatic acyl group, an alkoxycarbonyl group or an aralkoxycarbonyl group) are useful as stabilizers for synthetic polymers.
    Type: Grant
    Filed: July 3, 1974
    Date of Patent: February 8, 1977
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Osawa
  • Patent number: 4005094
    Abstract: Piperidine-spiro-hydrantoin derivatives having the formula ##STR1## wherein X represents oxygen atom or sulfur atom; n is an integer of 1 to 4 inclusive; andR represents, when n is 1, an alkenyl group which may be substituted with halogen, an alkynyl group which may be substituted with phenyl, an aralkyl group which may be substituted with halogen, alkyl of 1 to 4 carbon atoms or halomethyl, a hydroxyalkyl group, an alkoxyalkyl group, an alkenyloxyalkyl group, an acryloxyalkyl group, an alkylthioalkyl group, an acyloxyalkyl group, an epoxyalkyl group, an N-alkyl-substituted aminoalkyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, an aliphatic acyl group, an alkoxycarbonyl group, a phosphino group which is substituted with phenoxy or alkoxy or a phosphinyl group which is substituted with phenoxy or alkoxy,When n is 2, an alkenylene group of 4 to 18 carbon atoms, a dialkyleneether group, an aralkylene group, a bis(acyloxyalkylene) group or an alkylene-bis(oxycarbonylalkyl) group,When n is
    Type: Grant
    Filed: January 10, 1975
    Date of Patent: January 25, 1977
    Assignee: Sankyo Company Limited
    Inventors: Keisuku Murayama, Syoji Moriyama, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohata, Hisayou Ohsawa
  • Patent number: 3975462
    Abstract: Piperidine-spiro-hydantoin derivatives having the formula ##SPC1##Wherein X represents oxygen atom or sulfur atom; n is an integer of 1 to 4 inclusive, and R represents various aliphatic or aromatic groups depending on the value of n.These compounds (I) are useful as stabilizers against photo and thermal deterioration of various synthetic polymers and can be prepared, for example, by reacting the corresponding 3-unsubstituted piperidine-spiro-hydantoin compound with the halide R-(X.sub.1).sub.n in which R and n are as defined herein and X.sub.1 is a halogen atom.
    Type: Grant
    Filed: October 22, 1974
    Date of Patent: August 17, 1976
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayou Ohsawa
  • Patent number: 3941744
    Abstract: Piperidine derivatives having the formula ##SPC1##WhereinR' represents an alkyl group, a substituted alkyl group, an acyl group, an alkoxycarbonyl group, a substituted alkoxycarbonyl group, an amino group, a substituted amino group, or nitroso group;X represents oxygen atom or sulfur atom;Y represents oxygen atom, sulfur atom or a group of the formula = N -- R" in which R" is hydrogen atom, an alkyl group or a substituted alkyl group;Z represents oxygen atom or a group of the formula >N -- R'" in which R'" is hydrogen atom, an alkyl group or a substituted alkyl group;n is an integer of 1 through 4 inclusive; andR represents, when n is 1, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, a cycloalkyl group, an alkoxycarbonyl group, a substituted alkoxycarbonyl group, a substituted phosphino group or a substituted phosphinyl group, when n is 2, an alkylene group, an alkenylene group, an arylene group, a substituted arylene group, an aralkylene group; an alkylenediphenylene g
    Type: Grant
    Filed: March 12, 1973
    Date of Patent: March 2, 1976
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Syoji Morimura, Takao Yoshioka, Toshimasa Toda, Eiko Mori, Hideo Horiuchi, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohata, Hisayou Ohsawa
  • Patent number: 3933735
    Abstract: 4-Piperidone derivatives having the formulae ##SPC1##Wherein R represents a phenyl or naphthyl group which may be substituted with nitro, lower alkyl, halogen, hydroxyl, lower alkyl hydroxy, hydroxy lower alkyl or formyl or a 5- or 6-membered heterocyclic group having as a hetero atom at least one of oxygen atom, sulfur atom and nitrogen atom and R.sub.1 represents hydrogen atom or an alkyl group of 1 to 4 carbon atoms. They are useful as stabilizers for various synthetic polymers against their photo- and thermal-deteriorations and the 4-piperidone derivatives (II) are prepared from the corresponding 2,2,6,6-tetramethyl-4-oxopiperidine derivatives by reaction with an aldehyde and the 4-piperidone derivatives (I) are prepared from the 4-piperidone derivatives (II) through dehydration.
    Type: Grant
    Filed: May 15, 1974
    Date of Patent: January 20, 1976
    Assignee: Sankyo Company Limited
    Inventors: Keisuke Murayama, Susumu Higashida, Katsuaki Matsui, Tomoyuki Kurumada, Noriyuki Ohta, Hisayu Ohsawa