Patent number: 4952381
Abstract: A catalyst for denitrizing nitrogen oxides contained in waste gas which contains a substantial amount of arsenic compounds therein, which comprises:(a) titanium, and(b) at least one element selected from the group consisting of arsenic and manganese. The catalyst is resistant to deactivation by arsenic compounds and retains high denitrizing activity over a long period of time. The catalyst may further contain at least one base metal selected from the group consisting of V, W, Mo, Cu, Fe, Cr, Co, Ni, Zn and Sn.
Type:
Grant
Filed:
December 12, 1988
Date of Patent:
August 28, 1990
Assignees:
Sakai Chemical Industry Co., Ltd., Mitsubishi Jukogyo Kabushiki Kaisha, Mitsubishi Petrochemical Co., Ltd., Mitsubishi Petrochemical Engineering Co., Ltd., Catalysts & Chemicals Industries Co., Ltd.
Inventors:
Horiaki Rikimaru, Tadao Nakatsuji, Toshikatsu Umaba, Kazuhiko Nagano, Kazuya Mishina, Hiromitsu Shimizu, Shigeru Nojima, Kozo Iida, Yoshiaki Obayashi, Touru Seto, Shigeaki Mitsuoka, Masayuki Hanada, Morio Fukuda, Kiyoshi Nagano, Makoto Imanari, Takeo Koshikawa, Akihiro Yamauchi
Patent number: 4859439
Abstract: A catalyst for denitrizing nitrogen oxides contained in waste gases, which comprises:(a) titanium, and(b) at least one base metal selected from the group consisting of V, W, Mo, Mn, Cu, Fe, Cr, Co, Ni, Zn and Sn, the catalyst containing titanium and the base metals in amounts of at least about 50% by weight in terms of oxides based on the catalyst, and titanium in amounts of about 80-99% by weight in terms of oxides and the base metals in amounts of about 20-1% by weight in terms of oxides, respectively, based on the total weight in terms of oxides of titanium and the base metals, and the catalyst having micropores of about 50-75000 .ANG. in radius in amounts of about 0.25-0.45 ml/g, and micropores of about 50-100 .ANG. in radius in amounts of about 10-40% by volume and micropores of about 500-60000 .ANG. in radius in amounts of not less than about 10% by volume, respectively, based on the total volume of the micropores of about 50-75000 .ANG.
Type:
Grant
Filed:
September 30, 1987
Date of Patent:
August 22, 1989
Assignees:
Sakai Chemical Industry Co., Ltd., Mitsubishi Jukogyo Kabushiki Kaisha, Mitsubishi Petrochemical Co., Ltd., Mitsubishi Petrochemical Engineering Co., Ltd., Catalysts & Chemicals Industries Co., Ltd.
Inventors:
Hiroaki Rikimaru, Tadao Nakatsuji, Toshikatsu Umaba, Kuzuhiko Nagano, Kazuya Mishina, Hiromitsu Shimizu