Abstract: Atomically thin layers including pores, their method of manufacture, and their use are disclosed. In some embodiments, pores may be formed in an atomically thin layer by growing the atomically thin layer on exposed portions of a substrate that includes islands comprising a material that is different than the material of the substrate. In some embodiments, pores and/or defects may be formed in an atomically thin layer by employing growth conditions that promote the formation of defects and/or pores. In certain embodiments, pores and/or defects may be etched to enlarge their size.

Abstract: Two-dimensional material based filters, their method of manufacture, and their use are disclosed. In one embodiment, a membrane may include an active layer including a plurality of defects and a deposited material associated with the plurality of defects may reduce flow therethrough. Additionally, a majority of the active layer may be free from the material. In another embodiment, a membrane may include a porous substrate and an atomic layer deposited material disposed on a surface of the porous substrate. The atomic layer deposited material may be less hydrophilic than the porous substrate and an atomically thin active layer may be disposed on the atomic layer deposited material.

Abstract: Atomically thin layers including pores, their method of manufacture, and their use are disclosed. In some embodiments, pores may be formed in an atomically thin layer by growing the atomically thin layer on exposed portions of a substrate that includes islands comprising a material that is different than the material of the substrate. In some embodiments, pores and/or defects may be formed in an atomically thin layer by employing growth conditions that promote the formation of defects and/or pores. In certain embodiments, pores and/or defects may be etched to enlarge their size.

Abstract: A hybrid membrane, particularly of polyacrylonitrile (PAN)/graphene oxide (GO)/SiO2, separates oil and water even from emulsions. The membrane can be made by one-step electrospinning, adding GO and SiO2 nanofillers in PAN in various concentrations. The nanofillers may be uniformly embedded in the nanofibrous structure of the electrospun hybrid membrane, with GO mainly embedded inside the PAN nanofibers and may cause knots, and/or SiO2 nanoparticles embedded on the nanofiber surface and may form micro-nano fiber surface protrusions. Hierarchical structures formed can have enhanced hydrophilicity due to oxygen-containing groups on both SiO2 and GO, and have >99% oil rejection from oil-water emulsions. Separation flux and phase rejection of gravity separation may be enhanced by incorporation of nanofillers, which may also enhance membrane mechanical properties. Separated water flux may be enhanced from 2600 (pure PAN) to 3151 Lm?2h?1 for the hybrid.

Abstract: A method of deionizing saline water by contacting the saline water with a diffusion barrier to remove at least a portion of divalent ions to form deionized water, in order to desalinate the deionized water without scale formation, and a method of fabricating the diffusion barrier. Various embodiments of the diffusion barrier, the method of fabricating thereof, and the method of deionizing the saline water are provided.

Abstract: Two-dimensional material based filters, their method of manufacture, and their use are disclosed. The filters may include at least one active layer disposed on a porous substrate. The at least one active layer may include intrinsic and/or intentional formed pores. In some embodiments, the flow resistance of the porous substrate may be selected to limit flow through defects and intrinsic pores in the at least one active layer.

Abstract: Conventional sintering processes convert a portion of cBN to hBN which is softer than cBN which negatively affects functional properties of an alumina composite. The invention is directed to method for making an alumina-cubic boron nitride (Al2O3-cBN) composite that contains substantially no hexagonal boron nitride (hBN) by non-conventional spark plasma sintering of cBN with nano-sized alumina particles. The invention is also directed to Al2O3-cBN/Ni composites, which contain substantially no hBN, and which exhibit superior physical and mechanical properties compared to alumina composites containing higher amounts of hBN.

Abstract: Conventional sintering processes convert a portion of cBN to hBN which is softer than cBN which negatively affects functional properties of an alumina composite. The invention is directed to method for making an alumina-cubic boron nitride (Al2O3-cBN) composite that contains substantially no hexagonal boron nitride (hBN) by non-conventional spark plasma sintering of cBN with nano-sized alumina particles. The invention is also directed to Al2O3-cBN/Ni composites, which contain substantially no hBN, and which exhibit superior physical and mechanical properties compared to alumina composites containing higher amounts of hBN.

Abstract: A polyelectrolyte coated fly ash is described with a method of making and a method of using for the adsorption of a contaminant from a solution. The polyelectrolyte coated fly ash may be made by treating the oil fly ash with acid, and then contacting the product with a positive polyelectrolyte to create a first polyelectrolyte layer, and then with a negative polyelectrolyte to create a negative polyelectrolyte layer. The resulting polyelectrolyte coated fly ash quickly adsorbs contaminants from solution, and may be cleaned and reused.

Abstract: Two-dimensional material based filters, their method of manufacture, and their use are disclosed. In one embodiment, a membrane may include an active layer including a plurality of defects and a deposited material associated with the plurality of defects may reduce flow therethrough. Additionally, a majority of the active layer may be free from the material. In another embodiment, a membrane may include a porous substrate and an atomic layer deposited material disposed on a surface of the porous substrate. The atomic layer deposited material may be less hydrophilic than the porous substrate and an atomically thin active layer may be disposed on the atomic layer deposited material.

Abstract: A hybrid membrane, particularly of polyacrylonitrile (PAN)/graphene oxide (GO)/SiO2, separates oil and water even from emulsions. The membrane can be made by one-step electrospinning, adding GO and SiO2 nanofillers in PAN in various concentrations. The nanofillers may be uniformly embedded in the nanofibrous structure of the electrospun hybrid membrane, with GO mainly embedded inside the PAN nanofibers and may cause knots, and/or SiO2 nanoparticles embedded on the nanofiber surface and may form micro-nano fiber surface protrusions. Hierarchical structures formed can have enhanced hydrophilicity due to oxygen-containing groups on both SiO2 and GO, and have >99% oil rejection from oil-water emulsions. Separation flux and phase rejection of gravity separation may be enhanced by incorporation of nanofillers, which may also enhance membrane mechanical properties. Separated water flux may be enhanced from 2600 (pure PAN) to 3151 Lm?2h?1 for the hybrid.

Abstract: Two-dimensional material based filters, their method of manufacture, and their use are disclosed. In one embodiment, a membrane may include an active layer including a plurality of defects and a deposited material associated with the plurality of defects may reduce flow therethrough. Additionally, a majority of the active layer may be free from the material. In another embodiment, a membrane may include a porous substrate and an atomic layer deposited material disposed on a surface of the porous substrate. The atomic layer deposited material may be less hydrophilic than the porous substrate and an atomically thin active layer may be disposed on the atomic layer deposited material.

Abstract: Atomically thin layers including pores, their method of manufacture, and their use are disclosed. In some embodiments, pores may be formed in an atomically thin layer by growing the atomically thin layer on exposed portions of a substrate that includes islands comprising a material that is different than the material of the substrate. In some embodiments, pores and/or defects may be formed in an atomically thin layer by employing growth conditions that promote the formation of defects and/or pores. In certain embodiments, pores and/or defects may be etched to enlarge their size.

Abstract: A method for producing a composite of cubic boron nitride dispersed in a SiAlON ceramic. This method involves mixing silicon nitride nanoparticles, aluminum nitride nanoparticles, silica nanoparticles, calcium oxide nanoparticles, and cubic boron nitride microparticles to produce a mixture. The cubic boron nitride may be coated with nickel. The mixture is sintered to produce the composite, and this sintering may involve spark plasma sintering and/or sintering at a relatively low temperature. The composite may comprise a mixture of Ca-?-SiAlON and ?-SiAlON ceramic reinforced by boron nitride in either or both cubic and hexagonal phases.

Abstract: A method for producing a composite of cubic boron nitride dispersed in a SiAlON ceramic. This method involves mixing silicon nitride nanoparticles, aluminum nitride nanoparticles, silica nanoparticles, calcium oxide nanoparticles, and cubic boron nitride microparticles to produce a mixture. The cubic boron nitride may be coated with nickel. The mixture is sintered to produce the composite, and this sintering may involve spark plasma sintering and/or sintering at a relatively low temperature. The composite may comprise a mixture of Ca-?-SiAlON and ?-SiAlON ceramic reinforced by boron nitride in either or both cubic and hexagonal phases.

Abstract: Durable, porous alumina-carbon nanotube membranes and methods for making them using spark plasma sintering. Methods for removing heavy metals such as cadmium from waste water using alumina-carbon nanotube membranes.

Abstract: A polyelectrolyte coated fly ash is described with a method of making and a method of using for the adsorption of a contaminant from a solution. The polyelectrolyte coated fly ash may be made by treating the oil fly ash with acid, and then contacting the product with a positive polyelectrolyte to create a first polyelectrolyte layer, and then with a negative polyelectrolyte to create a negative polyelectrolyte layer. The resulting polyelectrolyte coated fly ash quickly adsorbs contaminants from solution, and may be cleaned and reused.

Abstract: Conventional sintering processes convert a portion of cBN to hBN which is softer than cBN which negatively affects functional properties of an alumina composite. The invention is directed to method for making an alumina-cubic boron nitride (Al2O3-cBN) composite that contains substantially no hexagonal boron nitride (hBN) by non-conventional spark plasma sintering of cBN with nano-sized alumina particles. The invention is also directed to Al2O3-cBN/Ni composites, which contain substantially no hBN, and which exhibit superior physical and mechanical properties compared to alumina composites containing higher amounts of hBN.

Abstract: Conventional sintering processes convert a portion of cBN to hBN which is softer than cBN which negatively affects functional properties of an alumina composite. The invention is directed to method for making an alumina-cubic boron nitride (Al2O3-cBN) composite that contains substantially no hexagonal boron nitride (hBN) by non-conventional spark plasma sintering of cBN with nano-sized alumina particles. The invention is also directed to Al2O3-cBN/Ni composites, which contain substantially no hBN, and which exhibit superior physical and mechanical properties compared to alumina composites containing higher amounts of hBN.

Abstract: A method of deionizing saline water by contacting the saline water with a diffusion barrier to remove at least a portion of divalent ions to form deionized water, in order to desalinate the deionized water without scale formation, and a method of fabricating the diffusion barrier. Various embodiments of the diffusion barrier, the method of fabricating thereof, and the method of deionizing the saline water are provided.