Patents by Inventor Takaho Shibata
Takaho Shibata has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230341790Abstract: A toner includes a toner particle containing a binder resin containing a crystalline polyester. In differential scanning calorimetry (DSC), the toner is heated to 180° C. at a rate of 10° C./min, then cooled to 25° C. at a rate of 10° C./min and successively from 25° C. to 15° C. at a rate of 3° C./min, and heated again to 180° C. at a rate of 10° C./min. As a result, an exothermic amount P1 when the toner is cooled from 80° C. to 40° C. is 1.00 J/g or less, an exothermic amount P2 when the toner is cooled from 25° C. to 15° C. is 0.10 J/g or more, and when a sum of endothermic amounts P3 (J/g) when the toner is heated again from 40° C. to 180° C. and a sum of exothermic amounts P4 (J/g) when the toner is cooled from 180° C. to 40° C. satisfies 2.0 ? P3-P4 ? 10.0.Type: ApplicationFiled: March 13, 2023Publication date: October 26, 2023Inventors: KENTA MITSUIKI, HISASUKE KAJIHARA, MAKI IMURA, NOBUHIRO YOSHIDA, KOHEI YOSHIYAMA, KENTARO KAMAE, YUU NISHIMURA, KAZUNARI OOYAMA, NOBUYOSHI SUGAHARA, YUYA CHIMOTO, TAKAHO SHIBATA
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Publication number: 20230314973Abstract: The toner comprises a toner particle that contains a binder resin, a polymer C, and a pigment, wherein at least a portion of the polymer C is bonded with at least a portion of the pigment; in solid-state NMR measurement at 60° C. using as a sample, a solid fraction collected according to a prescribed procedure in which the toner is dissolved in chloroform, transverse relaxation time T2 of a peak observed at 1.5 ppm to 2.5 ppm is 1.0 ms to 50.0 ms; and using a SPA (J/cm3)0.5 for a SP value of the binder resin and a SPB (J/cm3)0.5 for a SP value of the polymer C, the SPA and the SPB satisfy a following formula (1). 1.0?SPA?SPB?2.Type: ApplicationFiled: March 14, 2023Publication date: October 5, 2023Inventors: HISASUKE KAJIHARA, MAKI IMURA, KENTARO KAMAE, YUU NISHIMURA, TAKAHO SHIBATA
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Publication number: 20230305415Abstract: The present invention provides a toner including a toner particle containing a binder resin and a release agent. The binder resin contains an amorphous resin and a crystalline resin, and a content of the crystalline resin is 1.0% to 20.0% by mass based on a mass of the binder resin. In a cross-section of the toner particle observed by scanning transmission electron microscopy, (i) there exist a matrix A of the amorphous resin and domains A of the release agent dispersed in the matrix A, (ii) the domains A each include a matrix B of the release agent and domains B of the crystalline resin dispersed in the matrix B, and (iii) the domains A are each covered with the crystalline resin and an average coverage of the domains A by the crystalline resin is 70% or more.Type: ApplicationFiled: March 9, 2023Publication date: September 28, 2023Inventors: NOBUHIRO YOSHIDA, KOHEI YOSHIYAMA, MAKI IMURA, KENTA MITSUIKI, KENTARO KAMAE, YUU NISHIMURA, KAZUNARI OOYAMA, NOBUYOSHI SUGAHARA, HISASUKE KAJIHARA, YUYA CHIMOTO, TAKAHO SHIBATA
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Publication number: 20230305416Abstract: A toner including a toner particle containing a binder resin containing an amorphous polyester A and a crystalline polyester C, and a wax, and a silica fine particle, wherein the content of the crystalline polyester C is within a specific range, the softening point of the amorphous polyester A satisfies a specific relationship, and in an X-ray diffraction spectrum under a specific temperature condition for the toner, there is a peak corresponding to the crystalline polyester C, a wax index AW1 and a crystalline polyester index AC1 of the toner satisfy a specific relationship, the silica fine particle contains a silica fine particle A having a maximum diameter of primary particle in a specific range, and the average coverages of the surface of the toner before and after the toner is treated with hexane with the silica fine particle A satisfy a specific relationship.Type: ApplicationFiled: March 17, 2023Publication date: September 28, 2023Inventors: KENTARO KAMAE, YUU NISHIMURA, HISASUKE KAJIHARA, TAKAHO SHIBATA, MAKI IMURA
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Publication number: 20230305414Abstract: A toner comprising a toner particle comprising a binder resin, wherein the binder resin comprises an amorphous polyester A and a crystalline polyester C; the amorphous polyester A has an amorphous polyester segment a1 and a2; the amorphous polyester segment a2 has a monomer unit of a specific alcohol a0; the crystalline polyester C is a polymer having a crystalline polyester segment c2 and a crystalline segment c1 bonded to the end of the crystalline polyester segment c2; the crystalline polyester segment c2 has a monomer unit of a specific alcohol b0; an absolute value of a difference between a carbon number of the linear aliphatic polyhydric alcohol a0 and a carbon number of the linear aliphatic polyhydric alcohol b0 is 4 or less; and SP values of the polyester segment a1 and a2, and the crystalline segment c1 and the crystalline polyester segment c2 satisfy specific relationships.Type: ApplicationFiled: March 8, 2023Publication date: September 28, 2023Inventors: MAKI IMURA, HISASUKE KAJIHARA, KENTARO KAMAE, YUU NISHIMURA, TAKAHO SHIBATA
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Patent number: 11762307Abstract: A toner having a toner particle containing a binder resin and a styrene-acrylic resin, the toner being characterized in that the styrene-acrylic resin is a graft polymer having an aliphatic hydrocarbon compound segment and a styrene-acrylic segment, the styrene-acrylic segment has a specific monomer unit, the melting point of the styrene-acrylic segment is from 30° C. to 80° C., and when the toner is measured using a FT-IR ATR method, the intensity assigned to the styrene-acrylic resin and the intensity assigned to the binder resin satisfy a specific relationship.Type: GrantFiled: August 7, 2020Date of Patent: September 19, 2023Assignee: CANON KABUSHIKI KAISHAInventors: Junichi Tamura, Takaho Shibata, Ryuji Murayama, Kenta Mitsuiki, Megumi Shino, Hironori Minagawa
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Patent number: 11720036Abstract: A toner comprising a toner particle comprising a binder resin including a polyester resin, and a polyolefin resin having a sulfonic acid group, wherein the polyolefin resin having a sulfonic acid group is a polymer in which a vinyl polymer is bonded to a polyolefin, a content ratio of a monomer unit containing a sulfonic acid group in the vinyl polymer is from 1.0 mass % to 20.0 mass %, in a FT-IR spectrum obtained through measurement of a large particle size toner and a small particle size toner resulting from dividing, on a number basis, the toner into two substantially equal parts, a ratio of an intensity of a maximum absorption peak in a range from 1130 cm?1 to 1170 cm?1 with respect to an intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.Type: GrantFiled: June 10, 2021Date of Patent: August 8, 2023Assignee: CANON KABUSHIKI KAISHAInventors: Takakuni Kobori, Kenta Mitsuiki, Hitoshi Sano, Wakiko Katsumata, Daisuke Yamashita, Yosuke Iwasaki, Takeshi Ohtsu, Takaho Shibata, Masaharu Miura, Koh Ishigami, Yuichi Mizo
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Patent number: 11630162Abstract: Connection normality check of a pair of electric wires is simplified. A circuit check device 1 that checks connection normality of a pair of electric wires L1 and L2 includes, when the pair of electric wires is connected to an exchange 2, a voltmeter 11 that measures a first inter-wire potential difference between one end of an electric wire portion p1 of the electric wire L1 and one end of an electric wire portion p2 of the electric wire L2, a voltmeter 12 that measures a second inter-wire potential difference between the other end of the electric wire portion p1 of the electric wire L1 and the other end of the electric wire portion p2 of the electric wire L2, and a determiner 13 that determines whether the measured first inter-wire potential difference agrees with the measured second inter-wire potential difference.Type: GrantFiled: July 5, 2019Date of Patent: April 18, 2023Assignee: Nippon Telegraph and Telephone CorporationInventors: Noriyuki Sato, Takaho Shibata, Tsuyoshi Nagai
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Publication number: 20220373919Abstract: A toner, comprising a toner particle comprising a binder resin and a water-soluble polyvalent metal salt, wherein a main component of the binder resin is a polyester resin having specific acid value, the water-soluble polyvalent metal salt is a chloride, nitrate or sulfate of the specific metal, the water-soluble polyvalent metal salt has a solubility in water at 25° C. of 30 to 200 g/100 mL, in a cross-sectional observation of the toner particle, a proportion of the area of domains having a concrete surface area, relative to the total area of domains derived from the water-soluble polyvalent metal salt, is 80 to 100 area %, the expression below is satisfied, where At (area %) denotes the proportion of the total area of domains and Fm (atomic %) denotes the proportion of the polyvalent metal atom relative to the atoms in the toner as detected by X-ray fluorescence analysis. 0.02?At/Fm?0.Type: ApplicationFiled: April 28, 2022Publication date: November 24, 2022Inventors: Maki Imura, Tomoyo Miyakai, Kentaro Kamae, Yuu Nishimura, Shin Kitamura, Takaho Shibata
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Publication number: 20220373911Abstract: A toner, comprising a toner particle comprising a binder resin, wherein the binder resin comprises an amorphous polyester and a crystalline polyester; (i) a weight-average molecular weight of a soluble matter of the crystalline polyester in o-dichlorobenzene at 100° C. is 1500 to 4900; (ii) the crystalline polyester comprises a modified crystalline polyester having at least one terminal-modified structure selected from among a structure in which a hydroxy group at a main chain terminal of the crystalline polyester is terminal-modified with a C16 to C31 aliphatic monocarboxylic acid, and a structure in which a carboxy group at a main chain terminal of the crystalline polyester is terminal-modified with a C15 to C30 aliphatic monoalcohol; and (iii) a content ratio of the terminal-modified structure in the crystalline polyester is 80.0 mol % or higher.Type: ApplicationFiled: April 28, 2022Publication date: November 24, 2022Inventors: Kentaro Kamae, Tomoyo Miyakai, Maki Imura, Yuu Nishimura, Shin Kitamura, Takaho Shibata
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Patent number: 11429032Abstract: A toner containing a toner particle that contains a binder resin including a polyester resin, and a polyolefin resin having —COOM that is a neutralized carboxy group with a monovalent metal ion M, wherein the polyolefin resin having —COOM is a polymer in which a vinyl polymer is bonded to a polyolefin, a content of a monomer unit containing —COOM in the polyolefin resin having —COOM is 1 to 20 mass %, and in a FT-IR spectrum obtained through measurement of a large particle size-side particle group and a small particle size-side particle group obtained by dividing the toner into two substantially equal parts, on a number basis, a ratio of the intensity of a maximum absorption peak in a range from 1545 cm?1 to 1555 cm?1 with respect to the intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.Type: GrantFiled: August 26, 2020Date of Patent: August 30, 2022Assignee: CANON KABUSHIKI KAISHAInventors: Takaho Shibata, Yuichi Mizo, Koh Ishigami, Takakuni Kobori, Masaharu Miura, Takeshi Ohtsu, Yosuke Iwasaki, Daisuke Yamashita, Ryo Nakajima, Wakiko Katsumata, Hitoshi Sano, Kenta Mitsuiki, Rei Hijikawa
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Publication number: 20220050398Abstract: A toner includes toner particles containing a binder resin, a colorant, and inorganic fine particles, in which in a depth profile of an element distribution in a depth region from the outermost surface of a particle to a depth of 500 nm the depth profile being obtained by an element analysis performed by X-ray photoelectron spectroscopy using the toner as a sample, two or more minimum points of a concentration of a carbon element in the depth region exist, a concentration of an inorganic element becomes a maximum value at a depth position corresponding to each of the minimum points, and the inorganic element is an element derived from the inorganic fine particle.Type: ApplicationFiled: July 22, 2021Publication date: February 17, 2022Inventors: Kazunari Ooyama, Yuu Nishimura, Nobuyoshi Sugahara, Hitoshi Sano, Toru Takahashi, Kazuki Murata, Daisuke Tsujimoto, Koh Ishigami, Shin Kitamura, Takaho Shibata, Ryo Nakajima
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Publication number: 20210397106Abstract: A toner comprising a toner particle comprising a binder resin including a polyester resin, and a polyolefin resin having a sulfonic acid group, wherein the polyolefin resin having a sulfonic acid group is a polymer in which a vinyl polymer is bonded to a polyolefin, a content ratio of a monomer unit containing a sulfonic acid group in the vinyl polymer is from 1.0 mass % to 20.0 mass %, in a FT-IR spectrum obtained through measurement of a large particle size toner and a small particle size toner resulting from dividing, on a number basis, the toner into two substantially equal parts, a ratio of an intensity of a maximum absorption peak in a range from 1130 cm?1 to 1170 cm?1 with respect to an intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.Type: ApplicationFiled: June 10, 2021Publication date: December 23, 2021Inventors: Takakuni Kobori, Kenta Mitsuiki, Hitoshi Sano, Wakiko Katsumata, Daisuke Yamashita, Yosuke Iwasaki, Takeshi Ohtsu, Takaho Shibata, Masaharu Miura, Koh Ishigami, Yuichi Mizo
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Publication number: 20210389688Abstract: A negative-charging toner comprising a toner particle comprising a binder resin and an organic-inorganic composite fine particle comprising resin fine particles and inorganic fine particles A, wherein the organic-inorganic composite fine particle is negative charging, the organic-inorganic composite fine particle has a structure in which at least a part of the inorganic fine particle A is embedded in the resin fine particle, a number average particle diameter Db of the organic-inorganic composite fine particle is 50 to 350 nm, and a plurality of convex portions derived from the inorganic fine particles A are present on the surface of the organic-inorganic composite fine particle.Type: ApplicationFiled: June 2, 2021Publication date: December 16, 2021Inventors: Takaho Shibata, Ryuji Murayama, Ryuichiro Matsuo, Yuto Onozaki, Kenta Mitsuiki, Megumi Shino, Hironori Minagawa
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Publication number: 20210318390Abstract: Connection normality check of a pair of electric wires is simplified. A circuit check device 1 that checks connection normality of a pair of electric wires L1 and L2 includes, when the pair of electric wires is connected to an exchange 2, a voltmeter 11 that measures a first inter-wire potential difference between one end of an electric wire portion p1 of the electric wire L1 and one end of an electric wire portion p2 of the electric wire L2, a voltmeter 12 that measures a second inter-wire potential difference between the other end of the electric wire portion p1 of the electric wire L1 and the other end of the electric wire portion p2 of the electric wire L2, and a determiner 13 that determines whether the measured first inter-wire potential difference agrees with the measured second inter-wire potential difference.Type: ApplicationFiled: July 5, 2019Publication date: October 14, 2021Inventors: Noriyuki Sato, Takaho Shibata, Tsuyoshi Nagai
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Publication number: 20210302853Abstract: A toner comprising a toner particle containing a binder resin and a polymer A, wherein the binder resin contains a polyester resin having a specific structure, the polymer A has a first monomer unit derived from a specific (meth)acrylic acid ester and a second monomer unit different from the first monomer unit, a content ratio of the first monomer unit in the polymer A is 5.0 mol % to 60.0 mol % while a content ratio of the second monomer unit in the polymer A is 20.0 mol % to 95.0 mol %, and the SP value of the first monomer unit, the SP value of the second monomer unit, and the SP value of a silicone segment contained in the specific structure satisfy a specific relationship.Type: ApplicationFiled: March 24, 2021Publication date: September 30, 2021Inventors: Kazuki Murata, Koh Ishigami, Shin Kitamura, Nobuyoshi Sugahara, Takaho Shibata, Toru Takahashi, Kazunari Ooyama, Yuu Nishimura, Daisuke Tsujimoto, Ryo Nakajima, Hitoshi Sano
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Publication number: 20210302854Abstract: A toner comprising a toner particle containing a binder resin containing at least 50 mass % of a polyester resin, wherein the polyester resin contains a polyester resin A having a silicone segment, and in XPS analysis, when X is a ratio of the number of silicon atoms attributable to silicone segments relative to a total number of measured atoms, X1 is a value of the X on the toner particle surface, X2 is a value of the X at a depth of 30 nm from the surface, Z is a ratio of the number of carbon atoms attributable to ester bonds relative to a total number of measured atoms, Z1 is a value of the Z on the toner particle surface and Z2 is a value of the Z at a depth of 30 nm from the toner particle surface, X1, Z1, X2 and Z2 satisfy a specific relationship.Type: ApplicationFiled: March 24, 2021Publication date: September 30, 2021Inventors: Shin Kitamura, Nobuyoshi Sugahara, Daisuke Tsujimoto, Kazunari Ooyama, Yuu Nishimura, Kazuki Murata, Toru Takahashi, Ryo Nakajima, Hitoshi Sano, Koh lshigami, Takaho Shibata
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Patent number: 11131938Abstract: A toner comprises a toner particle including a binder resin, and inorganic fine particles A and silica particles B, wherein the inorganic fine particle A has a rectangular parallelepiped shape; an amount of the inorganic fine particles A is 0.3 to 3.0 mass parts per 100 mass parts of the toner particles; a number average particle diameter of the silica particles B is 80 to 200 nm; a fixing ratio of the inorganic fine particle A is 25% to 70%; where a separation amount of the inorganic fine particles A is denoted by YA (mg), and a separation amount of the silica particles is denoted by YB (mg), YA is 3.00 to 18.0, YA and YB satisfy the following formula, YA/YB>0.75, and a surface potential difference C in a rubbing test using the inorganic fine particle A and the binder resin is ?70 V to +70 V.Type: GrantFiled: August 13, 2019Date of Patent: September 28, 2021Assignee: CANON KABUSHIKI KAISHAInventors: Ryuji Murayama, Takaho Shibata, Junichi Tamura, Kenta Mitsuiki, Megumi Shino, Hironori Minagawa
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Publication number: 20210286282Abstract: The present invention provides a white toner which has high charge uniformity and enables stable print-out of high-quality images irrespective of its usage environment. The above object can be solved by a white toner including a white toner particle containing a binder resin, a white pigment and an inorganic fine particle, in which the white pigment has a work function of 5.80 eV or more and 6.10 eV or less, the content of the white pigment is 15.0 parts by mass or more and 60.0 parts by mass or less relative to 100 parts by mass of the binder resin, and the inorganic fine particle has a work function of 6.15 eV or more.Type: ApplicationFiled: May 28, 2021Publication date: September 16, 2021Inventors: Takakuni Kobori, Kenta Mitsuiki, Hitoshi Sano, Wakiko Katsumata, Daisuke Yamashita, Yosuke Iwasaki, Takeshi Ohtsu, Takaho Shibata, Masaharu Miura, Koh lshigami, Yuichi Mizo
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Publication number: 20210063903Abstract: A toner containing a toner particle that contains a binder resin including a polyester resin, and a polyolefin resin having —COOM that is a neutralized carboxy group with a monovalent metal ion M, wherein the polyolefin resin having —COOM is a polymer in which a vinyl polymer is bonded to a polyolefin, a content of a monomer unit containing —COOM in the polyolefin resin having —COOM is 1 to 20 mass %, and in a FT-IR spectrum obtained through measurement of a large particle size-side particle group and a small particle size-side particle group obtained by dividing the toner into two substantially equal parts, on a number basis, a ratio of the intensity of a maximum absorption peak in a range from 1545 cm?1 to 1555 cm?1 with respect to the intensity of a maximum absorption peak in a range from 1713 cm?1 to 1723 cm?1 exhibits a specific relationship.Type: ApplicationFiled: August 26, 2020Publication date: March 4, 2021Inventors: Takaho Shibata, Yuichi Mizo, Koh Ishigami, Takakuni Kobori, Masaharu Miura, Takeshi Ohtsu, Yosuke Iwasaki, Daisuke Yamashita, Ryo Nakajima, Wakiko Katsumata, Hitoshi Sano, Kenta Mitsuiki, Rei Hijikawa