Abstract: An improved method for heating the aqueous slurries of soils contaminated with tarry/oily organics and volatile compounds. The method includes the steps of heating the slurry (containing inorganic and carbonaceous solids below 1/8 inch) with atmospheric pressure steam in a specially designed slurry heater(s), contacting the hot (95.degree.-99.degree. C.) slurry with the contaminated feed soil (top size 5 inch) in a hydraulic feeder, processing the resultant slurry in a tumbler at temperatures up to 90.degree. C., separating the -1/8 inch solids from the slurry exiting the tumbler and recycling a portion of the -1/8 inch solids in slurry back to slurry heater(s). In order to reach the required temperature in the tumbler, the -1/8 inch slurry has to travel through the tumbler at mass flow rates 1.5-4.0 times higher as compared to those for the soil feed stream.

Abstract: A process is provided for clean-up of soils contaminated with highly viscous coal tar and/or petroleum derived organics. This new invention is based on application of the modified Clean Soil Process integrated with modified thermal desorption technology. This new invention utilizes the unexpected advantages of integration of the Clean Soil Process and conventional thermal desorption which cannot, when applied separately or in sequence (Clean Soil Process followed by Conventional Thermal Desorption), furnish satisfactory clean-up, but when integrated have the capacity to clean the most difficult contaminated soils (including soils contaminated by manufactured gas plants) to about 100 ppm, or less of total soluble organics and less than 3 ppm of PAH's.

Abstract: A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

Abstract: A method is provided for separating an inert solid substantially inorganic fraction comprising sand or soil from a tarry or oily organic matter in a feedstock. The feedstock may be contaminated soil or tarry waste. The feedstock is combined with pulverized coal and water. The ratio (oil or tar to dry weight of coal) of about 1.0:10 to about 4.0:10 at a temperature in the range of 60.degree.-95.degree. C. The mixture is agitated, the coarse particles are removed, and up to about 0.10% by weight (based on weight of coal) of a frothing agent is added. The mixture is then subjected to flotation, and the froth is removed from the mixture.