Abstract: A porous multi-layer film favorably employable as a separator film for a nonaqueous electric battery comprises at least three united polyolefin layers, in which at least one polyolefin layer is a polyethylene layer and at least one polyolefin layer is a polypropylene layer which is placed in contact with the polyethylene layer. The polyolefin layers are combined to form a united structure with a peel strength of at least 3 g/15 mm and has a pore volume of 30-80%, a maximum pore size of 0.02-2 .mu.m, a shutdown temperature of 135.degree.-140.degree. C., and a thermal durability to maintain the shutdown condition up to at least 180.degree. C.