Patents by Inventor Thierry Chapus

Thierry Chapus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10190059
    Abstract: A process for the hydrotreatment of a feed obtained from renewable sources in which the total stream of feed F is divided into a number of different part-streams of feed F1 to Fn equal to the number of catalytic zones n, where n is 1 to 10. The mass flow rate of hydrogen sent to the first catalytic zone represents more than 80% by weight of the total mass flow rate of hydrogen used. The effluent from the reactor outlet undergoes at least one separation step. A portion of the liquid fraction is recycled to the catalytic zones in a manner such that the local recycle ratio for each of the beds is 2 or less, and the local dilution ratio over each of the beds is less than 4.
    Type: Grant
    Filed: July 22, 2016
    Date of Patent: January 29, 2019
    Assignee: IFP Energies Nouvelles
    Inventors: Thierry Chapus, Frederic Bazer-Bachi, Elodie Tellier, Yves Scharff, Stephane Fedou, Octavio Carvalho, Sebastien Boucher
  • Publication number: 20170022424
    Abstract: A process for the hydrotreatment of a feed obtained from renewable sources in which the total stream of feed F is divided into a number of different part-streams of feed F1 to Fn equal to the number of catalytic zones n, where n is 1 to 10. The mass flow rate of hydrogen sent to the first catalytic zone represents more than 80% by weight of the total mass flow rate of hydrogen used. The effluent from the reactor outlet undergoes at least one separation step. A portion of the liquid fraction is recycled to the catalytic zones in a manner such that the local recycle ratio for each of the beds is 2 or less, and the local dilution ratio over each of the beds is less than 4.
    Type: Application
    Filed: July 22, 2016
    Publication date: January 26, 2017
    Applicant: IFP Energies Nouvelles
    Inventors: Thierry CHAPUS, Frederic BAZER-BACHI, Elodie TELLIER, Yves SCHARFF, Stephane FEDOU, Octavio CARVALHO, Sebastien BOUCHER
  • Patent number: 9458396
    Abstract: The invention relates to a process for the production of diesel fuel bases comprising a sulfur content that is less than 100 ppm, starting from a feedstock that is obtained from a renewable source, comprising the following stages: a) A stage for bringing the feedstock into contact with a fixed-bed hydrotreatment catalyst for producing an effluent that comprises a gaseous fraction comprising hydrogen and a hydrocarbon-based liquid fraction, d) A stage for bringing into contact at least one portion of the hydrocarbon-based liquid fraction in the presence of a selective hydroisomerization catalyst in a fixed bed, e) A stage for separating the effluent that is obtained from stage d) into a gaseous fraction that comprises hydrogen and at least one diesel-fuel-based fraction.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: October 4, 2016
    Assignee: IFP Energies nouvelles
    Inventors: Wilfried Weiss, Thierry Chapus
  • Patent number: 9447334
    Abstract: The invention concerns a process for the pre-treatment of an unrefined vegetable or animal oil, consisting of passing said oil through a reactor comprising at least one fixed bed of at least one adsorbent comprising a porous refractory oxide which is free of catalytic metals, at a temperature in the range 130° C. to 320° C., at a pressure in the range 0.1 to 7 MPa and with a residence time for said oil on said fixed bed in the range 0.1 to 1 hour. The invention concerns a process for pre-treatment of a semi-refined vegetable or animal oil, integrated upstream of a hydrotreatment step for the production of green gas oil.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: September 20, 2016
    Assignee: IFP Energies nouvelles
    Inventors: Aurelie Dandeu, Vincent Coupard, Thierry Chapus
  • Patent number: 9321970
    Abstract: A process for hydrotreatment of a feed from renewable sources such as vegetable oils for the production of paraffinic hydrocarbons comprising pre-treatment by crystallisation and/or precipitation allowing the elimination of insoluble inorganic impurities under hydrotreatment conditions. The flow of the total feed is divided up into a certain number of different, part flows equal to the number of catalytic zones in the reactor, and the different part flows are injected in the successive catalytic zones in increasing proportions to produce an effluent containing paraffinic hydrocarbons.
    Type: Grant
    Filed: November 8, 2012
    Date of Patent: April 26, 2016
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Nathalie Dupassieux, Thierry Chapus
  • Patent number: 9315737
    Abstract: A process for hydrotreatment of a feed from renewable sources such as vegetable oils for the production of paraffinic hydrocarbons comprising a pre-treatment step by crystallization and/or precipitation and pre-hydrogenation of the feed under hydrogen allowing the elimination of insoluble inorganic impurities under hydrotreatment conditions and improved exothermal management of the reaction. The effluent is separated to a gas fraction and a liquid fraction containing paraffinic hydrocarbons, a portion of said liquid fraction is recycled.
    Type: Grant
    Filed: November 8, 2012
    Date of Patent: April 19, 2016
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Nathalie Dupassieux, Thierry Chapus
  • Patent number: 9260385
    Abstract: A process for the production of surfactant compounds from a feed obtained from renewable sources, comprising hydrotreatment of feed in a fixed bed reactor having a plurality of catalytic zones disposed in series containing a hydrotreatment catalyst. The feed is injected in a staggered manner and injected in increasing proportions in order to produce an effluent containing at least hydrocarbon compounds containing linear paraffins.
    Type: Grant
    Filed: April 18, 2013
    Date of Patent: February 16, 2016
    Assignee: IFP ENERGIES NOUVELLES
    Inventor: Thierry Chapus
  • Patent number: 9109168
    Abstract: A process for hydrotreating a feed originating from renewable sources such as vegetable oils to produce paraffinic hydrocarbons in the presence of hydrogen in excess over the theoretical hydrogen consumption and under hydrotreatment conditions in a fixed bed reactor having a plurality of catalytic zones disposed in series and comprising a hydrotreatment catalyst. The total feed flow is divided into a certain number of different part flows equal to the number of catalytic zones in the reactor; the various part flows are injected into the successive catalytic zones in increasing proportions to produce an effluent comprising paraffinic hydrocarbons. The effluent undergoes a separation step in order to separate a gas fraction and a liquid fraction containing the paraffinic hydrocarbons. At least a portion of said this liquid fraction is recycled to the first catalytic zone so that the weight ratio between said recycle and the part flow introduced into the first catalytic zone is 10 or more.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: August 18, 2015
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Nathalie Dupassieux, Thierry Chapus
  • Publication number: 20150166473
    Abstract: A process for the production of surfactant compounds from a feed obtained from renewable sources, comprising hydrotreatment of feed in a fixed bed reactor having a plurality of catalytic zones disposed in series containing a hydrotreatment catalyst. The feed is injected in a staggered manner and injected in increasing proportions in order to produce an effluent containing at least hydrocarbon compounds containing linear paraffins.
    Type: Application
    Filed: April 18, 2013
    Publication date: June 18, 2015
    Applicant: IFP ENERGIES NOUVELLES
    Inventor: Thierry Chapus
  • Patent number: 9045701
    Abstract: The invention describes a method of treating feeds from renewable sources comprising: a hydrotreatment stage a) comprising at least two catalytic zones in which the entry stream comprising said feed mixed with at least a part of a hydrotreated liquid effluent from stage b) is introduced into the first catalytic zone at a temperature comprised between 150 and 260° C., and the effluent from the first catalytic zone is then introduced, mixed with at least a part of a hydrotreated liquid effluent from stage b) and preheated, into the following catalytic zone or zones at a temperature comprised between 260 and 320° C., a stage b) of separation of the effluent from the hydrotreatment stage a) permitting the separation of a gaseous effluent and of a hydrotreated liquid effluent of which at least a part is recycled upstream from each catalytic zone of stage a).
    Type: Grant
    Filed: October 26, 2010
    Date of Patent: June 2, 2015
    Assignee: IFP Energies Nouvelles
    Inventors: Wilfried Weiss, Laurent Bournay, Thierry Chapus
  • Patent number: 8962905
    Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least one hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: February 24, 2015
    Assignee: IFP Energies Nouvelles
    Inventors: Thierry Chapus, Nathalie Dupassieux, Antoine Daudin
  • Patent number: 8877993
    Abstract: The invention concerns a process for hydrotreatment and/or hydroconversion of a feed of bio-renewable origin containing triglyceride and/or fatty acid structures and wherein the fatty chains contain in the range 8 to 25 carbon atoms, said process comprising the following steps: a) hydrotreatment and/or hydroconversion of said bio-renewable feed in an ebullated bed reactor in the presence of a granular catalyst comprising, on an amorphous support, at least one metal or compound of a metal having a hydrodehydrogenating function, to produce a first effluent; b) sending the effluent produced in step a) to a distillation zone from which a gaseous fraction and at least one distillate cut the end point of which is less than 400° C.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: November 4, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Thierry Chapus, Alain Quignard, Nathalie Dupassieux, Antoine Daudin
  • Publication number: 20140291200
    Abstract: The invention relates to a process for the production of diesel fuel bases comprising a sulfur content that is less than 100 ppm, starting from a feedstock that is obtained from a renewable source, comprising the following stages: a) A stage for bringing the feedstock into contact with a fixed-bed hydrotreatment catalyst for producing an effluent that comprises a gaseous fraction comprising hydrogen and a hydrocarbon-based liquid fraction, d) A stage for bringing into contact at least one portion of the hydrocarbon-based liquid fraction in the presence of a selective hydroisomerization catalyst in a fixed bed, e) A stage for separating the effluent that is obtained from stage d) into a gaseous fraction that comprises hydrogen and at least one diesel-fuel-based fraction.
    Type: Application
    Filed: December 16, 2013
    Publication date: October 2, 2014
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Wilfried WEISS, Thierry CHAPUS
  • Patent number: 8692040
    Abstract: The invention describes a process for treatment of a feedstock that is obtained from a renewable source that comprises a hydrotreatment stage in the presence of at least one fixed-bed catalyst, whereby said catalyst comprises a hydro-dehydrogenating function and an amorphous substrate, at a temperature of between 50 and 450° C., at a pressure of between 1 MPa and 10 MPa, at an hourly volumetric flow rate of between 0.1 h?1 and 10 h?1, and in the presence of a total quantity of hydrogen that is mixed with the feedstock such that the hydrogen/feedstock ratio is between 50 and 1000 Nm3 of hydrogen/m3 of feedstock, followed by a separation from the hydrotreated effluent that is obtained from stage a) of hydrogen, gases, and at least one liquid hydrocarbon effluent that consists of at least 50% linear n-paraffins, and a steam-cracking of at least one portion of the liquid hydrocarbon effluent that is obtained from stage b).
    Type: Grant
    Filed: June 3, 2008
    Date of Patent: April 8, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Quentin Debuisschert, Jean Cosyns, Thierry Chapus, Damien Hudebine
  • Patent number: 8674151
    Abstract: The invention describes a two-step process for hydrotreatment of a feed derived from a renewable source, comprising: a) a first step, termed a mild pre-hydrogenation step, operating in the presence of a first, metallic, catalyst comprising an active hydrodehydrogenating phase constituted by at least one metal from group VIII and/or at least one metal from group VIB and an amorphous mineral support; and b) a second step, termed the second treatment step, operating in the presence of a second, sulphurized, catalyst comprising an active hydrodehydrogenating phase constituted by at least one non-noble metal from group VIII and/or at least one metal from group VIB and an amorphous mineral support.
    Type: Grant
    Filed: June 3, 2008
    Date of Patent: March 18, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Quentin Debuisschert, Jean Cosyns, Thierry Chapus, Damien Hudebine
  • Patent number: 8552235
    Abstract: A process for hydrodeoxygenation of feeds derived from renewable sources with conversion by decarboxylation/decarbonylation limited to at most 10%, using a bulk or supported catalyst comprising an active phase constituted by at least one element from group VIB and at least one element from group VIII, said elements being in the sulphide form, and the atomic ratio of the metal (or metals) from group VIII to the metal (or metals) from group VIB being strictly more than 0 and less than 0.095, said process being carried out at a temperature in the range 120° C. to 450° C., at a pressure in the range 1 MPa to 10 MPa, at an hourly space velocity in the range 0.1 h?1 to 10 h?1, and in the presence of a total quantity of hydrogen mixed with the feed such that the hydrogen/feed ratio is in the range 50 to 3000 Nm3 of hydrogen/m3 of feed.
    Type: Grant
    Filed: March 2, 2010
    Date of Patent: October 8, 2013
    Assignee: Merck Patent GmbH
    Inventors: Antoine Daudin, Laurent Bournay, Thierry Chapus
  • Patent number: 8546626
    Abstract: The invention is concerned with a supported or unsupported catalyst comprising an active phase constituted by a sulfur-containing group VIB element, the group VIB element being molybdenum, and a hydrodeoxygenation process with a yield of hydrodeoxygenation product which is greater than or equal to 90% of charges from renewable sources using a catalyst according to the invention.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: October 1, 2013
    Assignee: IFP Energies Nouvelles
    Inventors: Antoine Daudin, Laurent Bournay, Thierry Chapus
  • Patent number: 8324439
    Abstract: A method of treating feedstocks from renewable sources in order to produce diesel fuel bases of excellent quality. The feedstocks used can be, for example, raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The method includes fixed bed catalytic hydrotreatment, followed by fixed bed hydroisomerization with a catalyst based on monodimensional 10 MR zeolite and at least one metal from group VIII and/or VIB.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: December 4, 2012
    Assignee: IFP Energies Nouvelles
    Inventors: Emmanuelle Guillon, Christophe Bouchy, Nathalie Dupassieux, Antoine Daudin, Thierry Chapus
  • Patent number: 8282815
    Abstract: The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: October 9, 2012
    Assignee: IFP Energies nouvelles
    Inventors: Christophe Bouchy, Antoíne Daudin, Emmanuelle Guillon, Nathalie Dupassieux, Thierry Chapus
  • Publication number: 20120216450
    Abstract: The invention relates to a method of hydrotreatment in co-processing of petroleum feeds, in a mixture with at least one feed obtained from renewable sources, for producing fuel bases (kerosene and/or gas oil) having a sulphur content below 10 ppm, said method comprising the following stages: a) a first hydrotreatment stage in which said feed passes through at least one first fixed-bed catalytic zone comprising at least one bulk or supported catalyst comprising an active phase constituted by at least one group VIB element and at least one group VIII element, said elements being in the form of sulphide and the atomic ratio of the group VIII metal (or metals) to group VIB metal (or metals) being strictly greater than 0 and less than 0.095, b) a second hydrotreatment stage into which the effluent from the first hydrotreatment stage is sent directly, and in which said effluent passes through at least one second fixed-bed catalytic zone comprising at least one hydrotreatment catalyst.
    Type: Application
    Filed: July 27, 2010
    Publication date: August 30, 2012
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Nathalie Dupassieux, Antoine Daudin, Thierry Chapus