Abstract: A system for characterizing and optimizing refinery feedstock blends according to their corrosivity is provided. Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, mass changes of carbon steel samples, and/or dissociation of sulfur compounds in the feedstocks. The characterization can be carried out via any of impedance, spectroscopic measurements, and continuous measurements of mass changes of carbon steel samples with a crystal microbalance over a range of temperature, e.g., from ambient to 750° F. The system can be employed in any of refinery, terminal, and laboratories, using models and/or hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Abstract: A method for characterizing and optimizing refinery feedstock blends according to their corrosivity is provided. Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, mass changes of carbon steel samples, and/or dissociation of sulfur compounds in the feedstocks. The characterization is performed as a function of temperature via any of electrical resistivity measurement, vibrational spectroscopic analysis, voltammetry, electrochemical impedance spectroscopy, crystal microbalance measurements of weight changes, and combinations thereof. The method employs models and/or hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Abstract: A new technique to measure corrosion rates in naphthenic crudes in a high temperature environment has been designed using a gallium phosphate (GAPO) crystal microbalance. The technique is highly sensitive and can measure instantaneous corrosion rates. Due to the high temperature stability of the GAPO crystals, this technique can be used to measure in the laboratory dynamic naphthenic acid corrosion rates of iron at the high temperatures that are prevalent in various locations in oil and gas production and refining facilities, therefore opening a new and more accurate method to study naphthenic corrosion.

Abstract: A method for characterizing refinery feedstocks according to their corrosivity is provided. The characterization is based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, and/or dissociation of sulfur compounds in the feedstocks. In one embodiment, the characterization is done via vibrational spectroscopic measurements over a range of temperature, e.g., from ambient to 700° F. The method can be practiced in any of refinery, terminal, and laboratories. It can be used in conjunction with models and hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Abstract: Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, and/or dissociation of sulfur compounds in the feedstocks. The characterization is performed as a function of temperature via any of electrical resistivity measurement, vibrational spectroscopic analysis, voltammetry, electrochemical impedance spectroscopy (EIS) and combinations thereof. The method can be practiced in any of refinery, terminal, and laboratories. It can be used in conjunction with models and hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks. In one embodiment, the characterization of refinery feedstocks is via the use of EIS.

Abstract: A system for coating a surface comprising providing a source of iron-based amorphous metal, the iron-based amorphous metal including devitrified ferrite; directing the iron-based amorphous metal toward the surface by a spray for coating the surface; and separating at least a portion of the devitrified ferrite from the spray before the spray reaches the surface. Also an apparatus for coating a surface comprising a source of iron-based amorphous metal, the iron-based amorphous metal including devitrified ferrite; an application system for directing the iron-based amorphous metal toward the surface by a spray for coating the surface, and a system for separating at least a portion of the devitrified ferrite from the spray before the spray reaches the surface.

Abstract: Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, and/or dissociation of sulfur compounds in the feedstocks. The characterization is performed as a function of temperature via any of electrical resistivity measurement, vibrational spectroscopic analysis, voltammetry, electrochemical impedance spectroscopy (EIS) and combinations thereof The method can be practiced in any of refinery, terminal, and laboratories. It can be used in conjunction with models and hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks. In one embodiment, the characterization of refinery feedstocks is via the use of EIS.

Abstract: A method for characterizing and optimizing refinery feedstock blends according to their corrosivity is provided. Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, mass changes of carbon steel samples, and/or dissociation of sulfur compounds in the feedstocks. The characterization is performed as a function of temperature via any of electrical resistivity measurement, vibrational spectroscopic analysis, voltammetry, electrochemical impedance spectroscopy, crystal microbalance measurements of weight changes, and combinations thereof. The method employs models and/or hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Abstract: A method for characterizing refinery feedstocks according to their corrosivity is provided. The characterization is based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, and/or dissociation of sulfur compounds in the feedstocks. In one embodiment, the characterization is done via vibrational spectroscopic measurements over a range of temperature, e.g., from ambient to 700° F. The method can be practiced in any of refinery, terminal, and laboratories. It can be used in conjunction with models and hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Abstract: A system for characterizing and optimizing refinery feedstock blends according to their corrosivity is provided. Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, mass changes of carbon steel samples, and/or dissociation of sulfur compounds in the feedstocks. The characterization can be carried out via any of impedance, spectroscopic measurements, and continuous measurements of mass changes of carbon steel samples with a crystal microbalance over a range of temperature, e.g., from ambient to 750° F. The system can be employed in any of refinery, terminal, and laboratories, using models and/or hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Abstract: A system for coating a surface comprising providing a source of iron-based amorphous metal, the iron-based amorphous metal including devitrified ferrite; directing the iron-based amorphous metal toward the surface by a spray for coating the surface; and separating at least a portion of the devitrified ferrite from the spray before the spray reaches the surface. Also an apparatus for coating a surface comprising a source of iron-based amorphous metal, the iron-based amorphous metal including devitrified ferrite; an application system for directing the iron-based amorphous metal toward the surface by a spray for coating the surface, and a system for separating at least a portion of the devitrified ferrite from the spray before the spray reaches the surface.

Abstract: A method for the diffusion bonding of a graphite member to a metallic surface as part of a composite rotary anode for an X-ray tube is set forth. In the completed structure a carbide-free compound laminate separating and metallurgically bonded to the graphite member and to the metallic surface consists of, in sequence, a layer of interdiffused metals comprising a first metal selected from the group consisting of molybdenum and tungsten and a second metal selected from the group consisting of tantalum, columbium and alloys thereof, a layer consisting essentially of the second metal, a zone of interdiffused metals comprising platinum and the second metal and then a continuous layer comprising platinum or platinum alloy.

Abstract: A method for the diffusion bonding of a graphite member to a metallic surface of molybdenum, molybdenum alloy, tungsten or tungsten alloy as part of a composite rotary anode for an X-ray tube is set forth. In the completed structure a crack-free compound laminate separating and joining the graphite member and the metallic surface comprises a layer of carbide of metal of the metallic surface bonded to a layer of platinum or platinum alloy.

Abstract: A method for the diffusion bonding of a graphite member to a metallic surface as part of a composite rotary anode for an X-ray tube is set forth. In the completed structure a compound laminate separating and metallurgically bonded to the graphite member and to the metallic surface consists of, in sequence, a layer comprising carbide of vanadium and of a metal selected from the group consisting of of molybdenum and tungsten, a layer of metal selected from the group consisting of vanadium and vanadium alloys, a zone of interdiffused metals comprising platinum and vanadium and then a continuous layer comprising platinum or platinum alloy.

Abstract: Methods for the diffusion bonding of a graphite member to a metallic surface as part of a composite rotary anode for an X-ray tube are set forth. The preferred joint for the composite is made by using a layer of palladium in combination with a layer of metal selected from the group consisting of platinum, osmium, rhodium, ruthenium and alloys thereof.

Abstract: A method for the diffusion bonding of a graphite member to a metallic surface of molybdenum, molybdenum alloy, tungsten or tungsten alloy as part of a composite rotary anode for an X-ray tube is set forth. In the completed structure a crack-free compound laminate separating and joining the graphite member and the metallic surface comprises a layer of carbide of metal of the metallic surface bonded to a layer of platinum or platinum alloy.

Abstract: A method for the diffusion bonding of a graphite member to a metallic surface as part of a composite rotary anode for an X-ray tube is set forth. In the completed structure a compound laminate separating and metallurgically bonded to the graphite member and to the metallic surface consists of, in sequence, a layer comprising carbide of vanadium and of a metal selected from the group consisting of molybdenum and tungsten, a layer of metal selected from the group consisting of vanadium and vanadium alloys, a zone of interdiffused metals comprising platinum and vanadium and then a continuous layer comprising platinum or platinum alloy.

Abstract: This invention provides zirconium stabilized corrosion-resistant ferritic stainless steels particularly suitable for long-term use at moderate service temperatures in the as-welded condition or following a high temperature anneal.

Abstract: A graphite disc assembly for a rotating x-ray tube embodying a graphite substrate and an anode target of either tungsten or tungsten rhenium joined thereto by a layer of rhodium, osmium, ruthenium, platinum, platinum-chromium, or palladium. .Iadd.

Abstract: A composite substrate for use in a rotating x-ray anode tube consists of a graphite member joined to another member to which a target anode is affixed.