Patents by Inventor Thomas Martini

Thomas Martini has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4791205
    Abstract: Compounds of the general formula ##STR1## in which n denotes 1 or 2,X denotes an OMe group,Me denotes a proton, an alkali metal cation or an optionally substituted ammonium cation,R denotes hydrogen, a lower alkyl group or halogen, and, in the event thatn is 1,X also denotes an --NR.sup.1 R.sup.2 group in which R.sup.1 and R.sup.2 represent hydrogen or a lower alkyl group,a process for their preparation and their use as optical brighteners, especially for polyamide fibers and wool.
    Type: Grant
    Filed: May 21, 1987
    Date of Patent: December 13, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erich Schinzel, Hans Frischkorn, Thomas Martini
  • Patent number: 4595756
    Abstract: Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion, process for their manufacture and their use.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: June 17, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Norbert Schonberger, Erich Schinzel, Thomas Martini, Gunter Rosch
  • Patent number: 4508900
    Abstract: Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion,process for their manufacture and their use.
    Type: Grant
    Filed: September 13, 1982
    Date of Patent: April 2, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Norbert Schonberger, Erich Schinzel, Thomas Martini, Gunter Rosch
  • Patent number: 4447350
    Abstract: Mixtures of optical brighteners consisting of 1 to 60% by weight of a brightener from the bisbenzoxazolylnaphthalene series and 99 to 40% by weight of one or more brighteners of the formulae 2 to 10 listed in the description.
    Type: Grant
    Filed: September 15, 1983
    Date of Patent: May 8, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Erich Schinzel, Hans Frischkorn, Herbert Friedrich, Heinz Probst
  • Patent number: 4416795
    Abstract: Mixtures of optical brighteners composed of(a) 1 to 99% by weight of one or more compounds of the formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 can be identical or different and denote hydrogen, chlorine, C.sub.1 -C.sub.4 carbalkoxy, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and(b) 99 to 1% by weight of one or more compounds of the formulae ##STR2## in which n denotes 0 or 1, R.sub.7 and R.sub.8 denote identical or different radicals from the group comprising hydrogen, fluorine, chlorine, phenyl, trifluoromethyl, C.sub.1 -C.sub.4 -alkyl, alkoxy, cyano, carboxyl, carboalkoxy, carboxamide or alkyl sulfonates, and two adjacent radicals R.sub.7 and R.sub.8 together can also represent a benzene ring, a lower alkylene group or a 1,3-dioxapropylene group, and B denotes a cyano group, a carboxylate group or a carboxamide group or a 1,2,4-oxadiazol-3-yl group, a 1,3,5-oxadiazol-2-yl group, a phenyl group or a 1,3,4-oxadiazol-2-yl group.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: November 22, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Hans Frischkorn, Erich Schinzel, Heinz Probst
  • Patent number: 4400294
    Abstract: Mixtures of optical brighteners consisting of(a) 1 to 99 weight % of one or several compounds of the formula 1 ##STR1## (b) 99 to 1 weight % of one or several compounds of the formula 2 ##STR2## wherein n is 0 or 1,X is oxygen or sulfur,B is a group of the formulae ##STR3## and the other substituents are defined a specified in the description.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: August 23, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Gunter Rosch
  • Patent number: 4336155
    Abstract: Mixtures of optical brighteners consisting of 5 to 95% by weight of a compound of the formula ##STR1## in which A denotes a o- or p-cyanophenyl group, and 95 to 5% by weight of one or more further optical brighteners.
    Type: Grant
    Filed: July 16, 1980
    Date of Patent: June 22, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Rudiger Erckel, Horst Fruhbeis, Gunter Rosch, Heinz Probst
  • Patent number: 4330427
    Abstract: Mixtures of optical brighteners consisting of 5 to 95 parts by weight of a mixture consisting of 0 to 80% by weight of the compound of the formula 1 ##STR1## 20 to 100% by weight of the compound of the formula 2 ##STR2## and 0 to 80% by weight of the compound of the formula 3 ##STR3## and 95 to 5% by weight of one or more other optical brighteners.
    Type: Grant
    Filed: July 16, 1980
    Date of Patent: May 18, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Rudiger Erckel, Horst Fruhbeis, Gunter Rosch, Heinz Probst
  • Patent number: 4323675
    Abstract: Triazolyl stilbene compounds of the formula ##STR1## wherein A is a benzene or naphthalene ring optionally substituted by non-chromophoric substituents and B is a substituted 1,2,4-oxdiazole (3) or 1,3,5-oxdiazole (2) group, as well as a procedure for their manufacture and their use as optical brighteners.
    Type: Grant
    Filed: June 25, 1980
    Date of Patent: April 6, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Eckes, Rudiger Erckel, Thomas Martini, Gunter Rosch
  • Patent number: 4321052
    Abstract: A process for the bleaching of cellulose in an alkaline peroxide bleaching bath in the presence of a compound of the formula ##STR1## wherein R is C.sub.6 -C.sub.22 -alkyl, C.sub.6 -C.sub.22 -alkenyl or C.sub.6 -C.sub.22 -alkylaryl, n is a number of from 5 to 50, and X is ethylene or propylene; the ether chain (X-O).sub.n consisting entirely of ethoxy units or contains n/5 isopropoxy units at most.
    Type: Grant
    Filed: April 17, 1981
    Date of Patent: March 23, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Otto Smerz, Thomas Martini, Siegfried Billenstein, Klaus Adrian
  • Patent number: 4309551
    Abstract: Compounds of the general formula (1) ##STR1## wherein R.sub.1 denotes hydrogen, halogen, alkyl, alkoxy or, conjointly with R.sub.2, a fused benzo ring, R.sub.2 denotes hydrogen, alkyl, alkoxy, halogen, phenyl, cyano, carboalkoxy, carboxyl, carbonamido, monoalkylcarbonamido, dialkylcarbonamido, sulfo, alkylsulfonyl, alkyloxysulfonyl, sulfonamido, monoalkylsulfonamido or dialkylsulfonamido or, conjointly with R.sub.3, a fused benzo ring, R.sub.3 has the same meaning as R.sub.2, R.sub.4 denotes hydrogen, alkyl, alkoxy, halogen or, conjointly with R.sub.3, a fused benzo ring, R.sub.5 denotes alkyl, hydroxyalkyl, alkoxyalkyl, optionally substituted aralkyl, cyanoethyl, cycloalkyl or a group of the formulae --CH.sub.2 CN, --CH.sub.2 CONH.sub.2 or --CH.sub.2 COO--alkyl, A denotes a group of the formulae ##STR2## or--(CH.sub.2).sub.4 --R.sub.6 denotes hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, aralkyl or optionally substituted phenyl, n denotes 1, 2 or 3 and X.sup.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: January 5, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Norbert Schonberger, Erich Schinzel, Thomas Martini, Gunter Rosch
  • Patent number: 4304569
    Abstract: The formulation for brightening synthetic fibers or mixtures of synthetic fibers and natural fibers, which is an aqueous dispersion comprising at least one finely divided optical brightener and a dispersing agent, wherein the improvement comprises the dispersing agent being a water-soluble or water-dispersible polyester containing at least one phosphonic acid ester moiety.
    Type: Grant
    Filed: November 26, 1980
    Date of Patent: December 8, 1981
    Assignee: Cassella AG.
    Inventors: Friedrich Engelhardt, Karl Hintermeier, Herbert Friedrich, Thomas Martini
  • Patent number: 4271036
    Abstract: Colorless formulations of optical brighteners from the 4,4'-bis-triazinylamino-stilbene-disulfonic acid series, which are obtained by heating the brightener together with an oxyalkylate.
    Type: Grant
    Filed: January 23, 1980
    Date of Patent: June 2, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Uhl, Hans Frischkorn, Thomas Martini
  • Patent number: 4263176
    Abstract: Brighteners for detergents consisting of a mixture of 4,4'-bis-(2-morpholino-4-anilino-1,3,5-triazinylamino)-stilbene-2,2'-disul fonic acid-di-Na salt and from 5 to 50% by weight, calculated on said brightener, of another brightener of the formula ##STR1## in the above formula, M is an alkali metal cation, preferably sodium, X is a group of the formula --COR.sub.2 or --SO.sub.2 R.sub.3, R.sub.2 being C.sub.1 -C.sub.8 -alkyl and R.sub.3 being C.sub.1 -C.sub.5 -alkyl, C.sub.4 -C.sub.8 -cycloalkyl, phenyl or toluyl, Y is hydrogen or C.sub.1 -C.sub.5 -alkyl, A is C.sub.3 -C.sub.6 -alkylene, R.sub.1 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.4 -C.sub.8 -cycloalkyl, or a group of the formula ##STR2## and Z is an anilino group, a chloroanilino group or a morpholino group. Said brightener mixtures are color-stable and do not show any green discoloration even after a prolonged storage in a moist atmosphere.
    Type: Grant
    Filed: November 16, 1979
    Date of Patent: April 21, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Helmut Mengler, Gunter Rosch, Gunter Hohlfeld
  • Patent number: 4246403
    Abstract: Novel 1,3,4-oxadiazolone-(2) compounds of the formula ##STR1## wherein Y denotes carboxy optionally functionally modified or optionally substituted phenyl or a five-membered heterocycle optionally substituted and selected from the group consisting of: furan, thiophen, oxazole, imidazole, oxadiazole, oxadiazolone, triazole, benzofuran, thionaphthalene, benzoxazole, benzimidazole, and benzotriazole, R denotes hydrogen, alkyl or optionally substituted phenyl, n denotes 0 and 1 and the rings A and B carry optionally further non-chromophoric substituents. These compounds may be used as optical brighteners.
    Type: Grant
    Filed: July 25, 1979
    Date of Patent: January 20, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Prossel, Erich Schinzel, Norbert Schonberger, Thomas Martini, Gunter Rosch
  • Patent number: 4140699
    Abstract: Perfluorinated vinyl ethers are prepared by reacting a fluorinated carboxylic acid fluoride with hexafluoropropylene epoxide in the presence of a catalyst and thereafter pyrolyzing the carboxylic acid fluoride containing ether linkages, optionally after having converted it into a salt of a monovalent metal.
    Type: Grant
    Filed: November 22, 1976
    Date of Patent: February 20, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Thomas Martini
  • Patent number: 4136121
    Abstract: Perfluorocarboxylic acid salts of a monovalent metal are reacted with perfluorocarboxylic acid fluorides in aprotic polar solvents. Perfluoroketones are obtained.The salt of the perfluorocarboxylic acid can be replaced by alkali metal salts of formic acid, oxalic acid or of oxygen-containing mineral acids, the central atom of which is an element of the groups IIIA to VIIA of the periodic table and which mineral acid is weaker than trifluoroacetic acid. The same result is obtained if the anhydride of the perfluorocarboxylic acid is contacted with an alkali metal fluoride. The synthesized perfluoroketones are liquids of high chemical and thermal stability.
    Type: Grant
    Filed: October 20, 1977
    Date of Patent: January 23, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Martini, Friedhelm Kluge
  • Patent number: 4118421
    Abstract: Perfluoro-alkoxy propionic acid fluorides may be obtained by reacting hexafluoro-propene epoxide with a perfluoro-carboxylic fluoride in an aprotic polar solvent in the presence of a N,N,N', N'-tetrasubstituted diaminodifluoromethane as catalyst.The compounds obtained may be used as starting products for valuable perfluoro ethers which are highly inert towards heat or aggressive chemicals, such as fluorine.
    Type: Grant
    Filed: June 21, 1977
    Date of Patent: October 3, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Thomas Martini
  • Patent number: 4118399
    Abstract: By reacting an N-formylated secondary amine with hexafluoro epoxide in the presence of trisdimethyl amino difluorophosphorane or hexamethyl phosphoric acid triamide mixture can be obtained consisting of perfluoro-.alpha.-(3,6-dimethyl-1,4-dioxanyl-2-oxy)-propionic acid fluoride and perfluoro-2-oxo-3,6-dimethyl-1,4-dioxane.
    Type: Grant
    Filed: May 19, 1977
    Date of Patent: October 3, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Thomas Martini
  • Patent number: 4118398
    Abstract: Perfluorinated ethers obtainable exposing perfluorocarbonyl compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 mean identical or different perfluoroalkyl radicals optionally containing one or several ether-like bound oxygen atoms to light rays having a wave length of from 100 to 600 m .mu., in a liquid phase.
    Type: Grant
    Filed: April 28, 1977
    Date of Patent: October 3, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Thomas Martini