Patents by Inventor Thomas S. Phillips

Thomas S. Phillips has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5973178
    Abstract: A compound of the formula: ##STR1## wherein: A is hydrogen, a substituted or unsubstituted C.sub.1 to C.sub.4 alkyl, a substituted or unsubstituted C.sub.1 to C.sub.4 alkoxy or a substituted or unsubstituted phenyl;W is a substituted or unsubstituted phenylene or a substituted or unsubstituted naphthylene;Y is--CH.sub.2 --CH.sub.2 --Z wherein Z is selected from --OSO.sub.3 H, --SSO.sub.3 H, --OPO.sub.3 H, --OCOCH.sub.2 --Cll.sub.3, Cl, Br or F; andm is 1 or 2, e is 0 or 1,with the sum of e+m=2.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: October 26, 1999
    Assignee: DyStar L.P.
    Inventors: Thomas S. Phillips, Ronald P. Pedemonte
  • Patent number: 5932708
    Abstract: Fiber-reactive monoazo and disazo dyes, suitable for dyeing cellulose material, such as cotton, and also synthetic or natural polyamide material, such as wool, in high color depth and with good fastness properties, are described which contain a quaternary ammonium group, such as a trialkylammonium group, and contain, as a fiber-reactive group, a group of the vinyl-sulfone series, or a grouping containing a group of the vinyl-sulfone series, or a heterocyclic fiber-reactive group selected from a halogeno-substituted pyrimidine or triazine.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: August 3, 1999
    Assignee: Dystar, L.P.
    Inventors: Thomas S. Phillips, Ralph Svenningsen, Ronald P. Pedemonte
  • Patent number: 5925745
    Abstract: A fiber-reactive dye corresponding to formula (1) ##STR1## in which: Fb is the radical of an azo dye, of a heavy metal complex azo dye, of a formazan dye, of a triphenodioxazine dye or of a phthalocyanine dye;U.sup.(+) is a permanent quaternary ammonium group;A.sup.(-) is a colorless anion, andR.sup.x, R.sub.4, G, Q and n are as defined in the specification, with the proviso that the dye contains at least one group of the vinylsulfone series, such as a group of the formula --SO.sub.2 Y, wherein Y is as defined in the specification, these dyes being capable of dyeing hydroxy- and/or carboxamido-containing fibres, such as cellulosic fibre and wool.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: July 20, 1999
    Assignee: Dystar, L.P.
    Inventors: Thomas S. Phillips, Ralph Svenningsen, Ronald P. Pedemonte
  • Patent number: 5696241
    Abstract: Novel sulfonated quinolone compounds used in the preparation of fiber reactive dyes having the formula: ##STR1## being N-alkyl substituted-4-hydroxy-6-sulfo-2-quinolone. The alkyl group bonded to the nitrogen in the quinolone has from 1 to 4 carbon atoms which may be further substituted by an hydroxy, amino, or sulfo group. The compounds of the invention may be prepared by the sulfonation of an N-alkyl substituted-4-hydroxy-2-quinolones, ##STR2## followed by selective desulfonation to yield the compounds of interest. New monoazo fiber reactive dyes having the formulas: ##STR3## and their metal complexes, may be prepared from these sulfonated compounds by the diazotization of an amine component, selected from an unsubstituted, or a substituted benzene or naphthalene compound, containing a fiber reactive group, and coupling the diazo component to the compounds of the invention.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: December 9, 1997
    Assignee: Dystar, L.P.
    Inventors: Philomen Z. deCroos, Ronald P. Pedemonte, Thomas S. Phillips
  • Patent number: 5641188
    Abstract: An automatic dump bucket has a bail which can rest in an inclined position or a vertical position, the bail of the dump bucket pivotable about pivot pins that are not secured to the side wall of the bucket but which are disposed in a bore in a pivot pin support plate on the side wall of the bucket, in a pivot pin aperture in a side wall of an enclosure bracket and trapped by a pivot pin locking plate. The pivot pin and bail contact area can be lubricated by forcing a lubricant through an opening in the pivot pin locking plate and a passageway formed in the pivot pin. The dump bucket also has fork lift channels and roll-over blocking channels and, when dumped, assumes a position beyond a parallel position with the bail.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: June 24, 1997
    Assignee: Phillips Mine & Mill, Inc.
    Inventor: Thomas S. Phillips
  • Patent number: 5409916
    Abstract: Fiber reactive dyes of the anthraquinone type which provide brilliant violet colors without metal complexing. These dyes may be represented by the formula: ##STR1## wherein W is selected from NR.sub.2 and oxygen;R is independently selected from hydrogen, C.sub.1 -C.sub.6 alkyl;C.sub.1 -C.sub.6 alkoxy, sulfo and carboxy;R.sub.1 is selected from hydrogen, C.sub.1 -C.sub.6 alkyl and phenyl;R.sub.2 is selected from hydrogen and C.sub.1 -C.sub.6 alkyl;R.sub.3 is selected from hydrogen, and C.sub.1 -C.sub.4 alkyl;n is an integer of 1 or 2; andY is CH.dbd.CH.sub.2, or CH.sub.2 CH.sub.2 Z wherein Z is a group capable of being split off by the action of an alkali reagent.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: April 25, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald P. Pedemonte, Thomas S. Phillips
  • Patent number: 5330539
    Abstract: A method for the exhaust dyeing of materials having hydroxy groups and materials containing carbonamide groups using a low salt content dye bath in conjunction with fiber reactive dyes exemplified by a dye of the following formula: ##STR1##
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: July 19, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Thomas S. Phillips, Kevin D. Costa, Werner Russ, Thomas V. Chambers
  • Patent number: 5240807
    Abstract: A water soluble built-on mask layer is provided on a photoresist composition disposed on a substrate. The photoresist comprises an o-quinone diazide and a novolak or paravinyl phenol resin. The built-on mask layer comprises a water soluble, photobleachable diazonium salt, a coupler for the diazonium salt and an acidic, polymeric, film forming resin such as polystyrene sulfonic acid.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: August 31, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Sangya Jain, Salvatore Emmi, Thomas S. Phillips
  • Patent number: 5082963
    Abstract: A process for the preparation of isomerically pure sulfonic acids of 2-aminonaphthalenes having a fiber reactive substituent of the formula --(SO.sub.2 X) wherein X is --CH.sub.2 --CH.sub.2 --Z and Z is a substituent such as thiosulfato, phosphato or sulfato. The process comprises a first step of acylating the amino group of the substituted 2-aminonaphthalene to form a N-acyl derivative of the formula, R--CO--NH--A--SO.sub.2 X wherein A represents a naphthalene nucleus. The N-acyl derivative is then sulfonated to provide an essentially isomerically pure sulfonic acid derivative of the formula R--CO--NH--A(--SO.sub.2 X, --SO.sub.3 H). Depending upon the position of the --SO.sub.2 X group in the starting material, the sulfonation reaction product will have one of the following isomeric ring positions for the sulfonyl and sulfo groups, respectively; 5:7 or 7:5 or 6:8 or 8:6.
    Type: Grant
    Filed: November 24, 1986
    Date of Patent: January 21, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Thomas S. Phillips, Anthony J. Corso
  • Patent number: 4769446
    Abstract: A water-soluble fiber-reactive red dyestuff is disclosed which, in its free acid form, has the formula ##STR1## wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Z wherein Z is --OH, --Cl, --Br, --OSO.sub.3 H, --SSO.sub.3 H, --OPO.sub.3 H.sub.2, --O.sub.2 CCH.sub.3, --O.sub.2 CCH.sub.2 CH.sub.3 or --N(lower alkyl).sub.2. Liquid compositions of said dyestuff are also disclosed. This dyestuff yields brilliant red shades on cellulosic materials having excellent fastness properties and superior color yield and build up.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: September 6, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: Anthony J. Corso, Fritz Meininger, Thomas S. Phillips
  • Patent number: 4746323
    Abstract: This invention is directed to mixtures of water-soluble, fiber reactive yellow dyestuffs which exhibit superior build-up and color properties over those properties obtained with the individual components of the mixtures. The dyestuffs disclosed herein have the following general formula in their free acid form: ##STR1## wherein R is lower alkyl, lower alkoxy or hydrogen and wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Z wherein Z is --OH, --Cl, --Br, --OSO.sub.3 H, --SSO.sub.3 H, OPO.sub.3 H.sub.2 or --N(R.sub.1).sub.2, and wherein R.sub.1 is lower alkyl or hydrogen.
    Type: Grant
    Filed: August 24, 1987
    Date of Patent: May 24, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: Thomas S. Phillips, Anthony J. Corso
  • Patent number: 4699624
    Abstract: This invention is directed to mixtures of water-soluble, fiber reactive yellow dyestuffs which exhibit superior build-up and color properties over those properties obtained with the individual components of the mixtures. The dyestuffs disclosed herein have the following general formula in their free acid form: ##STR1## wherein R is lower alkyl, lower alkoxy or hydrogen and wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Z wherein Z is --OH, --Cl, --Br, --OSO.sub.3 H, --SSO.sub.3 H, OPO.sub.3 H.sub.2 or --N(R.sub.1).sub.2, and wherein R.sub.1 is lower alkyl or hydrogen.
    Type: Grant
    Filed: April 7, 1986
    Date of Patent: October 13, 1987
    Assignee: Hoechst Celanese Corporation
    Inventors: Thomas S. Phillips, Anthony J. Corso
  • Patent number: 4379937
    Abstract: An improved process for selectively N-acylating hydroxy-amino-arylsulfonic acids is disclosed wherein the hydroxy-amino-arylsulfonic acid is dissolved in water by treatment with an alkaline lithium salt, such as lithium hydroxide, and the acylation is conducted while maintaining the pH at about 3-6. The N-acyl-hydroxy-amino-arylsulfonic acids are useful as dyestuff precursors.
    Type: Grant
    Filed: September 23, 1981
    Date of Patent: April 12, 1983
    Assignee: American Hoechst Corporation
    Inventors: Anthony J. Corso, Kathleen M. Colavito, Thomas S. Phillips