Patents by Inventor Thomas S. Ramotowski
Thomas S. Ramotowski has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10608371Abstract: An electrical connector for joining a cable to a cathodically protected body in a marine environment includes a connector body having a terminal connector for joining to the cathodically protected body and a mounting portion for receiving the cable. An elastomeric band is positioned around said connector body mounting portion and exerts radially compressive inward force thereupon. An encapsulant is formed around and bonded to said connector body mounting portion, said elastomeric band and the cable. A method for making the electrical connector is further provided.Type: GrantFiled: June 4, 2018Date of Patent: March 31, 2020Inventor: Thomas S Ramotowski
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Patent number: 10465298Abstract: A method for improving service life in a connector for joining to a cathodically protected platform includes providing a metallic connector for joining to a cable. A non-conductive coating is provided on the connector proximate the cable. A hydroxide ion diffusion distance is determined that will insure dilution of hydroxide ions to a level that will prevent damage to an encapsulant and non-conductive coating bond on the connector. A polymer encapsulant is molded around the non-conductive coating and the cable to seal the assembled cable in the connector such that the encapsulant and non-conductive coating bond is formed at a greater path distance than the determined hydroxide ion diffusion distance from any hydroxide ion source.Type: GrantFiled: September 21, 2018Date of Patent: November 5, 2019Inventor: Thomas S Ramotowski
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Patent number: 8820155Abstract: A method for conducting a peel test of a polymer coated metallic sample includes making a peel test specimen having a polymer joined to a substrate. A free portion of the polymer is left unattached to the substrate. The peel test specimen is positioned in an environment for testing in such a manner that the polymer is allowed to peel downward from the substrate. A weight is joined to the free portion of the polymer and a start time is recorded. The attached portion of the polymer is periodically measured and the elapsed time is recorded. A peel rate is calculated from the measurement and time.Type: GrantFiled: September 30, 2010Date of Patent: September 2, 2014Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Patent number: 8689714Abstract: An electrochemical engine for buoyancy is provided with the engine having a water-tight and gas-tight chamber containing a volume of seawater. The electrochemical buoyancy engine contributes electrons for reduction of hydrogen protons in the seawater using a sufficient voltage applied to an anode and a cathode disposed in the seawater. The generated hydrogen gas is held in the chamber to provide the desired buoyancy and can be vented to adjust the buoyancy.Type: GrantFiled: August 26, 2010Date of Patent: April 8, 2014Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Patent number: 8518495Abstract: A method is provided for applying a superhydrophilic coating to a surface of a sonobuoy and acoustic sensors. A variety of different processed and chemistries can be used to make superhydrophilic coatings including polyethylene glycol, titanium dioxide and nanoporous silica. Application to the surface can be by dipping, painting and spraying. Once applied to the outer surface of the acoustic sensor and specifically the sonobuoy, the sonobuoy can be handled/stored/deployed under existing procedures. Titanium dioxide and nanoporous silica are inorganic materials that would have to be inter-mixed with the coating. The coating allows a surface of the sonobuoy to wet completely upon immersion into a fluid thereby minimizing the formation of air bubbles on the surface whereby the suppression of bubble formation allows the sonobuoy to immediately generate high quality acoustic data.Type: GrantFiled: June 13, 2011Date of Patent: August 27, 2013Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Patent number: 8470921Abstract: This invention is an acoustic device protected by an acoustically transparent low water permeability encapsulant made from an acoustically clear polymer such as polyurethane. High aspect ratio clay nanoparticles are positioned in the substrate in overlapping layers with layers of the substrate interposed. The invention also provides a method for forming an acoustically transparent low permeability encapsulant about an acoustic device. The method includes treating high aspect ration clay nanoparticles to make them organophilic. The treated nanoparticles are then mixed in a polymer resin in such a way as to form an intercalated mixture. A curing agent is added to the mixture, and the mixture is allowed to set. When set the resulting intercalated mixture produces an acoustically clear, low permeability polymer coating.Type: GrantFiled: April 13, 2010Date of Patent: June 25, 2013Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Patent number: 8450434Abstract: An epoxy and rubber microcomposite is formed by adding a carboxy-terminated or amine-terminated rubber component having a glass transition temperature less than zero degrees centigrade to a bisphenol A based epoxy resin component; heating the mixture to 150 degrees centigrade; cooling and curing with a suitable curing agent. A phase segregation occurs between the epoxy resin component and the rubber component to form discrete, spherical rubbery domains with the epoxy compound. Because the glass transition temperature of the rubbery domains is below zero degrees centigrade; the rubbery domains act as acoustic windows within the high-modulus epoxy compound.Type: GrantFiled: September 14, 2012Date of Patent: May 28, 2013Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Publication number: 20130005907Abstract: An epoxy and rubber microcomposite is formed by adding a carboxy-terminated or amine-terminated rubber component having a glass transition temperature less than zero degrees centigrade to a bisphenol A based epoxy resin component; heating the mixture to 150 degrees centigrade; cooling and curing with a suitable curing agent. A phase segregation occurs between the epoxy resin component and the rubber component to form discrete, spherical rubbery domains with the epoxy compound. Because the glass transition temperature of the rubbery domains is below zero degrees centigrade; the rubbery domains act as acoustic windows within the high-modulus epoxy compound.Type: ApplicationFiled: September 14, 2012Publication date: January 3, 2013Inventor: Thomas S. Ramotowski
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Patent number: 8309625Abstract: A method for preventing accumulation of organisms on a surface exposed to a marine environment. Nano-particles are provided in a water soluble polymer. The nano-particles have a thickness of about 2 nanometers and a major surface area of about 3 microns and are treated by a quaternary ammonium salt. The treated nano-particles are mixed into the water soluble polymer material. This mixture can be applied to the exposed surface. Biofouling is prevented by the sharpness of the nano-particles, sloughing of the water soluble material, and biocidal action caused by the quaternary ammonium salt.Type: GrantFiled: June 14, 2011Date of Patent: November 13, 2012Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Patent number: 8299187Abstract: An epoxy and rubber microcomposite is formed by adding a carboxy-terminated or amine-terminated rubber component having a glass transition temperature less than zero degrees centigrade to a bisphenol A based epoxy resin component; heating the mixture to 150 degrees centigrade; cooling and curing with a suitable curing agent. A phase segregation occurs between the epoxy resin component and the rubber component to form discrete, spherical rubbery domains with the epoxy compound. Because the glass transition temperature of the rubbery domains is below zero degrees centigrade; the rubbery domains act as acoustic windows within the high-modulus epoxy compound.Type: GrantFiled: June 11, 2010Date of Patent: October 30, 2012Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Publication number: 20110027518Abstract: This invention is an acoustic device protected by an acoustically transparent low water permeability encapsulant made from an acoustically clear polymer such as polyurethane. High aspect ratio clay nanoparticles are positioned in the substrate in overlapping layers with layers of the substrate interposed. The invention also provides a method for forming an acoustically transparent low permeability encapsulant about an acoustic device. The method includes treating high aspect ration clay nanoparticles to make them organophilic. The treated nanoparticles are then mixed in a polymer resin in such a way as to form an intercalated mixture. A curing agent is added to the mixture, and the mixture is allowed to set. When set the resulting intercalated mixture produces an acoustically clear, low permeability polymer coating.Type: ApplicationFiled: April 13, 2010Publication date: February 3, 2011Inventor: Thomas S. Ramotowski
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Publication number: 20110016961Abstract: A method for conducting an accelerated life test of a polymer coated metallic sample includes placing the sample below the water surface in a test tank containing water and an oxygen containing gas. Cathodic polarization of the metallic portion of the sample is increased. This can be by using a voltage source or a sacrificial anode. Dissolved oxygen in the test tank water is also increased. Dissolved oxygen can be increased by providing oxygen under pressure to the tank or through an aerator under the water surface. Temperature can also be regulated to accelerate the test speed. Delamination of the sample is periodically tested through a peel test or by other means. The invention also provides a reaction model independent method for calculating activation energy.Type: ApplicationFiled: September 30, 2010Publication date: January 27, 2011Inventor: Thomas S. Ramotowski
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Patent number: 7660693Abstract: A method for computing activation energy of diffusion for a material in a liquid is provided. At least two identical samples of the material are submerged in the liquid at different temperatures. The time required for each sample to reach a goal weight percentage is measured. A reaction acceleration factor is computed for the two samples from the resulting times and temperatures. Activation energy of diffusion is computed from the reaction acceleration factor and the temperatures. Additional samples can be used to give an error estimate.Type: GrantFiled: January 30, 2008Date of Patent: February 9, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Publication number: 20090188333Abstract: A method for computing activation energy of diffusion for a material in a liquid is provided. At least two identical samples of the material are submerged in the liquid at different temperatures. The time required for each sample to reach a goal weight percentage is measured. A reaction acceleration factor is computed for the two samples from the resulting times and temperatures. Activation energy of diffusion is computed from the reaction acceleration factor and the temperatures. Additional samples can be used to give an error estimate.Type: ApplicationFiled: January 30, 2008Publication date: July 30, 2009Inventor: Thomas S. Ramotowski
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Patent number: 7528195Abstract: A dampening material is presented with a carboxy-terminated butadiene nitrile (CTBN) as a dampening element. The glass transition temperature of the CTBN is generally at room temperature. The material is a two-component system with micro-scale phase segregation. The CTBN is reacted into an epoxy resin at a high temperature and cooled to allow the epoxy to react with a curing agent. A phase segregation occurs between the epoxy and the CTBN as the epoxy gels/cures. The extent of phase separation in the reaction is controlled by cross-linking and gelling. The rubbery component of CTBN phase segregates and forms discrete, spherical domains. Because the glass transition temperature of the rubbery domains is in the operational temperature range of interest, the composite is capable of absorbing acoustic energy. A high modulus allows a larger amount of acoustic energy to enter the composite where it is absorbed by the rubbery CTBN component.Type: GrantFiled: December 11, 2006Date of Patent: May 5, 2009Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Publication number: 20090026093Abstract: A method for conducting an accelerated life test of a polymer coated metallic sample includes placing the sample below the water surface in a test tank containing water and an oxygen containing gas. Cathodic polarization of the metallic portion of the sample is increased. This can be by using a voltage source or a sacrificial anode. Dissolved oxygen in the test tank water is also increased. Dissolved oxygen can be increased by providing oxygen under pressure to the tank or through an aerator under the water surface. Temperature can also be regulated to accelerate the test speed. Delamination of the sample is periodically tested through a peel test or by other means. The invention also provides a reaction model independent method for calculating activation energy.Type: ApplicationFiled: July 26, 2007Publication date: January 29, 2009Inventor: THOMAS S. RAMOTOWSKI
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Publication number: 20080139747Abstract: A dampening material is presented with a carboxy-terminated butadiene nitrile (CTBN) as a dampening element. The glass transition temperature of the CTBN is generally at room temperature. The material is a two-component system with micro-scale phase segregation. The CTBN is reacted into an epoxy resin at a high temperature and cooled to allow the epoxy to react with a curing agent. A phase segregation occurs between the epoxy and the CTBN as the epoxy gels/cures. The extent of phase separation in the reaction is controlled by cross-linking and gelling. The rubbery component of CTBN phase segregates and forms discrete, spherical domains. Because the glass transition temperature of the rubbery domains is in the operational temperature range of interest, the composite is capable of absorbing acoustic energy. A high modulus allows a larger amount of acoustic energy to enter the composite where it is absorbed by the rubbery CTBN component.Type: ApplicationFiled: December 11, 2006Publication date: June 12, 2008Inventor: Thomas S. Ramotowski
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Patent number: 7141150Abstract: A method and test apparatus for carrying out testing on a variety of samples of polymer bonded to metal wherein the samples are subjected to an accelerated cathodic reaction causing cathodic delamination of the samples. In particular, the method and test apparatus include a closed vessel that is partially filled with synthetic ocean water. An impressed current system is employed to protect the metal component of the samples. The synthetic ocean water is heated with an external band heater raising the temperature of the synthetic ocean water to thermal levels exceeding normal ocean temperatures in order to accelerate the reaction. Pure oxygen is then introduced into the closed vessel at a desired pressure to dissolve the oxygen into the synthetic ocean water to further simulate natural ocean conditions.Type: GrantFiled: July 19, 2004Date of Patent: November 28, 2006Assignee: The United States of America as represented by the Secretary of the NavyInventors: John R. Welch, Thomas S. Ramotowski, Gerald J. Roche
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Patent number: 7078101Abstract: The present invention is a new class of terpolymers for use as high strain electrostrictive polymer films. More particularly, the invention is a class of electrostrictive terpolymers comprising vinylidene fluoride (VDF), trifluoroethylene (TrFE) and at least one monomer having at least one halogen atom side group. The monomer is preferably an ethylene-based monomer and preferably selected to favor gauche-type linkage along the polymer backbone. The halogen atom side group is preferably large enough to move or cause adjacent polymer chains to be farther apart from or away from each other than in the absence of such side group, but not so large that it would inhibit polymer crystallites from forming. The monomer is preferably a chloro-monomer such as chlorofluoroethylene (CFE). The chlorofluoroethylene (CFE) is preferably 1-chloro-2-fluoroethylene or 1-chloro-1-fluoroethylene. The chlorofluoroethylene (CFE) favors gauche-type linkage which favors high electrostrictive strains.Type: GrantFiled: November 21, 2003Date of Patent: July 18, 2006Assignee: The United States of America as represented by the Secretary of the NavyInventors: Thomas S. Ramotowski, George J. Kavarnos, Qiming Zhang
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Patent number: 6982383Abstract: The present invention relates to a cable section assembly for marine applications having a core structure, such as a buoyant cable antenna interim manufacturing step subassembly, and a protective casing formed from a heat shrinkable tubing which together with the interim subassembly forms a complete assembly. For buoyant cable assembly applications the interim subassembly is at least partially formed of polyurethane material having glass microballoons distributed therein, with such material in any event occupying an outer layer portion of the subassembly. The cable section assembly of the present invention is formed by providing a length of heat shrinkable flexible tubing, inflating or expanding the heat shrinkable tubing to its approximate full diameter, inserting the core structure into the length of tubing, and shrinking the tubing around the core structure.Type: GrantFiled: July 30, 2003Date of Patent: January 3, 2006Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles D. Spellman, Edward H. Dzwilewski, Thomas S. Ramotowski