Abstract: In a patterning method according to this invention, a surface region of a resist layer is solution-retarded by a developer, and, then, the resist layer is patterned. Therefore, a desired shape of a side wall of the resist layer may be obtained by varying a solubility of the resist layer, with the result that a resist pattern with the side wall orthogonal to a surface of the substrate or the overhung side may be formed.

Abstract: A positive resist developer comprising a solution containing a quaternary ammonium hydroxide, a cationic surfactant and a nonionic surfactant.

Abstract: A method of manufacturing a semiconductor device having a submicron pattern. A p-type semiconductor layer is formed on an n-type semiconductor substrate. Insulating films are formed on the p-type semiconductor layer. A first mask layer, such as an aluminum layer having an etching rate different from that of the insulating films, is formed on the insulating films. A second mask layer having an etching rate different from that of the first mask layer, is formed on the first mask layer. The second mask layer is patterned. A coating film having an etching rate different from that of the first insulating film, is formed on the resultant structure. The coating film is etched to be left on a side wall of the patterned second mask layer. The first mask layer is patterned, using the residual coating film and the patterned second mask layer as masks, and a pattern finer than that of the resist is formed in the first mask layer.

Abstract: There is proposed a negative-working photoresist coating composition of an improved resolution, which comprises a cyclized polyisoprene having a weight-average molecular weight of 10,000 to 100,000 and a molecular weight distribution of not more than 1.9, an organic solvent of the cyclized polyisoprene, and a bisazido compound as a crosslinking agent.

Abstract: An improved method of forming a photoresist pattern in the photoengraving process. In the photoengraving process, after forming a photoresist layer, a non-photosensitive organic layer containing cyclized polyisoprene rubber as the major constituent is formed thereover. The organic layer is covered with a mask. The photoresist layer is selectively exposed to light through the organic layer. After developing and removing the organic layer, or together with the organic layer, the photoresist layer is developed.